NH4Cl水溶液的微观结构和宏观物性研究

通过拉曼光谱、同步辐射X射线散射和密度泛函理论(DFT)模拟,研究了质量分数为1.0 %-28.0 %的NH₄Cl水溶液的微观结构变化。同时在室温下测量了粘度、接触角和电导率。由拉曼光谱和密度泛函理论模拟结果可知,当溶质浓度升高至10.0 %时,在2900 cm_-1^和3100 cm_-1^{附近出现了明显的}N-H作用峰,且随着质量分数的升高,NH₄Cl水溶液中的氢键类型发生了转变。X射线散射结果表明,当NH₄Cl水溶液质量分数升高至10.0 %时,差值对分布函数G(r)在2.98 ?附近出现明显双峰,表明在该浓度下溶液中NH₄₊^-Cl_-^{接触离子对开始成为主要微观作用形式。对}NH₄Cl水溶液的宏观物性研究表明,粘度、接触角和电导率均随着NH₄Cl水溶液质量分数的增加而增大。作者推断,NH₄Cl水溶液中氢键类型的转变、O-H...N键占比增多以及逐渐增加的NH₄₊^-Cl_-^{接触离子对},是粘度和接触角随溶质浓度增加而增加的微观本质因素;电导率的增加与溶液中有效导电离子数量增加有关。     

Chaotic scattering in the restricted three-body problem I. The Copenhagen problem

We consider the scattering motion of the planar restricted three-body problem with two equal masses on a circular orbit. Using the methods of chaotic scattering we present results on the structure of scattering functions. Their connection with primitive periodic orbits and the underlying chaotic saddle are studied. Numerical evidence is presented which suggests that in some intervals of the Jacobi integral the system is hyperbolic. The Smale horseshoe found there is built from a countable infinite number of primitive periodic orbits, where the parabolic orbits play a fundamental role.     

Characterization of the mesospheric sodium layer at La Palma

We present the results of a mesospheric sodium monitoring programme at La Palma carried out through five campaigns of one week each, from 1999 September to 2000 August. The yearly averaged parameters of the layer (the sodium column density and the width) are given. We show that the short time-scale dynamics of the layer are governed by the sporadic layers with an average frequency of one event per night. The influence of the short time-scale dynamics of the layer on an adaptive optics system working on the William Herschel Telescope is quantified. It appears that it is a small effect in terms of defocus error. Finally, we present data obtained during the Perseid meteor shower and show that the dynamics of the sodium layer undergoes a transition with the meteoric activity.     

Intrinsic intraday variability in the gravitational lens system B0218+357

Radio monitoring of the gravitational lens system B0218+357 reveals it to be a highly variable source with variations on time-scales of a few days correlated in both images. This shows that the variability is intrinsic to the background lensed source and suggests that similar variations in other intraday variable sources can also be intrinsic in origin.     

SCATTERING PHASE MATRICES OF ICE CRYSTALS WITH HEXAGONAL PRISM AND TRIANGULAR PYRAMID FORM—A VECTOR RAY TRACING METHOD

The work presented previously by the authors(Cai and Liou,1982)has been extended in this paper.By making use of our improved model the calculations on scattering phase matrices of hexagonal prismice crystals(HPIC)have been conducted for monodisperse and polydisperse systems.Compared with themodel of Cai and Liou,the required computational quantity is decreased by about two orders of magni-tude and the errors of results are less for the new model.Meanwhile,the scattering phase matrices of triangularpyramid ice crystals(TPIC)are also computed in the paper,and the comparison between the scatterings of thetwo forms of ice crystals is performed.     

双基地激光测风雷达回波信号仿真研究

本文针对传统的体散射模型并未考虑大气不均匀性对信号传输的影响等问题,通过引入垂直非均匀的大气参数改进了模型,并利用其建立了体目标的双基地激光测风雷达方程,仿真了侧向散射回波信号,并与单基地雷达进行了对比分析。研究表明:水平方向上,双基地激光测风雷达的回波信号分布特征与单基地雷达差异较大,其回波信号等值线在近地面为卵形线,随着探测高度的增加,回波信号等值线逐渐变为以主、被动雷达为焦点的椭圆形,并最终趋近于圆形;垂直方向上,双基地激光测风雷达的回波信号随高度衰减剧烈,近地面的回波能量约为10^-10 J,4 km高度的回波能量约为10^-15J,在中低层大气(0~10 km),回波信号中气溶胶散射占比大,在高层大气(10 km以上),分子散射占比大。     

Scattering of elastic wave by a partially sealed cylindrical shell embedded in poroelastic medium

Scattering of an elastic wave by a cylindrical shell embedded in poroelastic medium is investigated theoretically with the assumption that the shell material is also a porous elastic medium. The porous medium is modellized via Biot's theory and the scattering by cylindrical shell is expressed by the definition of scattering matrix. The normal mode expansion technique is employed for analysing the scattering field, and the asymptotic solutions of displacements, stresses and pore pressure are derived. Two limiting cases‐scattering by a poroelastic cylinder in Biot medium and a elastic cylindrical shell in elastic medium are obtained from the general solutions. The dispersion curves of displacement amplitude at the interface of shell and medium is compared with the case of elastic shell. The scattering amplitude associated with the fast, slow and transverse waves are identified by numerical simulation. Furthermore, the influence of the poroelastic property of shell material on scattering amplitude is analysed. Copyright © 2005 John Wiley & Sons, Ltd.     

Space–VLBI observations of the OH maser OH 34.26+0.15: low interstellar scattering

We report on the first space–VLBI observations of the OH 34.26+0.15 maser in two main-line OH transitions at 1665 and 1667 MHz. The observations involved the space radio telescope on board the Japanese satellite HALCA and an array of ground radio telescopes. The map of the maser region and images of individual maser spots were produced with an angular resolution of 1 mas, which is several times higher than the angular resolution available on the ground. The maser spots were only partly resolved and a lower limit to the brightness temperature     was obtained. The maser seems to be located in the direction of low interstellar scattering, an order of magnitude lower than the scattering of a nearby extragalactic source and pulsar.     

ESTIMATION OF SOUNDING ABILITY OF A BRILLOUIN LIDAR IN THE EAST CHINA SEA

Vertical profiles of sound speed in the sea can be measured by using laser excited Brillouin scattering. In this paper the dependence of the accuracy of sound speed measurement on the accuracy of the Brillouin shift measurement is analyzed. We calculated the maximum detecting depths of sound speed to an accuracy of 1 m/s by lidar with different laser pulse energy, platform altitude, telescope aperture and lidar effective attenuation coefficient. The estimation of sounding ability in the East China Sea is made in some stations. These data can be used in the design of Brillouin Lidar for the China Sea.