激光剥蚀电感耦合等离子体质谱元素微区分析标准物质研究进展

激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)是目前地球科学分析领域的重要技术手段,元素微区分析标准物质研制是该分析技术发展的重要方向。本文对当前LA-ICP-MS元素微区分析标准物质的种类、元素分布以及应用上的优缺点和标准物质的制备方法进行了评述。现有的有证标准物质数量不多、种类不齐全,部分元素浓度较低,定值不确定度较大,应用上受到较大的局限性;研制标准也不成熟,均匀性检验方面尚未有统一的方法。本文参照岩石粉末标准物质均匀性检验方法提出了两步均匀性检验法,同时指出在标准物质种类方面,铂族元素及Au元素浓度适当、Pb-S等不同硫化物基体标准物质,以及化学成分不同的碳酸岩和磷酸岩基体标准物质是当前的迫切需求;在标准物质研制技术方面,纳米岩石粉末压片技术的研发、原位微区分析标准物质(固体)均匀性检验判别标准研究是亟待解决的问题。     

电感耦合等离子体质谱-原子荧光光谱法研究上海口岸进口印度尼西亚煤炭微量元素的赋存形态特征

印度尼西亚是我国最大的煤炭进口国,本文应用电感耦合等离子体质谱、原子荧光光谱、直接测汞仪等技术分析了上海口岸31批进口印度尼西亚煤炭中的12种微量元素,结合数理统计方法研究该类煤炭中微量元素的赋存形态。结果表明,进口印尼煤炭中含有高汞煤、三级含砷煤,As、Hg的平均富集系数大于1,其迁移风险值得关注;Be、Cu、Mo、Cd、Sn、Pb含量均低于中国煤和世界煤炭的平均水平,体现出印尼煤炭低灰分的品质特征。12种微量元素和相关项目(灰分和全硫)可划分为3类:第一类归纳为黏土矿物吸附类,包括As、Be、Cr、Co、Ni、Cu、Mo、Cd、Sn、Pb、灰分;第二类归纳为硫铁矿类,包括Hg、全硫;第三类归纳为碳酸盐矿物类,包括Ba。本文研究结果对于指导进口煤炭开发、利用过程中的环境评价和洁净化处理具有一定的参考价值。     

戊基磷酸二戊酯萃取色层分离-电感耦合等离子体质谱法测定铀产品中9种杂质元素

铀产品中杂质元素的含量测定在核法证学溯源分析或燃料元件厂质量检验中具有重要应用价值,保证测量的准确度主要在于控制流程空白、提高杂质元素的回收率。本文建立了戊基磷酸二戊酯(UTEVA)树脂快速分离铀与杂质元素、电感耦合等离子体质谱法(ICP-MS)测定杂质元素含量的系统流程。结果表明,UTEVA树脂对铀的吸附能力强,铀样品取样量为16.43 mg时,全流程对铀的去污因子大于3×105,9种杂质元素(锰钼镍铜铬铝钛钒镉)的回收率为95.1%~105.1%,国家标准物质GBW04205中杂质元素的分析结果与参考值在不确定度(k=2)范围内一致。本工作建立的分离流程对铀的去污效果好,特别适用于样品量少的情况下铀中杂质元素的分析,为核法证分析最终的归因溯源或燃料质量检验提供了技术支持。     

中国地球气候系统模式的发展及其模拟和预估

地球气候系统模式是开展多学科、多圈层集成研究的重要平台,其发展是国际地学领域特别是全球变化领域竞争的前沿。中国的地球气候系统模式研发工作始于20世纪80年代,最近10年得到快速发展。研发格局上已经形成中国科学院、有关部委和高校三足鼎立的局面。文中在简要回顾中国地球气候系统模式早期发展历史的基础上,总结了中国参加第6次耦合模式比较计划的9个地球气候系统模式的技术特点,初步评估了中国4个模式对全球和东亚气候模拟的基本性能,分析了其在4种共享社会经济路径情景下对全球降水与温度的预估变化及其与平衡态气候敏感度的联系。最后,结合国际态势,从发展的角度提出未来中国气候模式研发工作需要加强的8个方向。      

Thermal expansion of gehlenite, Ca2Al[AlSiO7], and the related aluminates LnCaAl[Al2O7] with Ln=Tb, Sm

The thermal expansion of gehlenite, Ca₂Al[AlSiO₇], (up to T=830 K), TbCaAl[Al₂O₇] (up to T=1,100 K) and SmCaAl[Al₂O₇] (up to T=1,024 K) has been determined. All compounds are of the melilite structure type with space group Thermal expansion data was obtained from in situ X-ray powder diffraction experiments in-house and at HASYLAB at the Deutsches Elektronen Synchrotron (DESY) in Hamburg (Germany). The thermal expansion coefficients for gehlenite were found to be: α₁=7.2(4)×10⁻⁶ K⁻¹+3.6(7)×10⁻⁹ΔT K⁻² and α₃=15.0(1)×10⁻⁶ K⁻¹. For TbCaAl[Al₂O₇] the respective values are: α₁=7.0(2)×10⁻⁶ K⁻¹+2.0(2)×10⁻⁹ΔT K⁻² and α₃=8.5(2)×10⁻⁶ K⁻¹+2.0(3)×10⁻⁹ΔT K⁻², and the thermal expansion coefficients for SmCaAl[Al₂O₇] are: α₁=6.9(2)× 10⁻⁶ K⁻¹+1.7(2)×10⁻⁹ΔT K⁻² and α₃=9.344(5)×10⁻⁶ K⁻¹. The expansion-mechanisms of the three compounds are explained in terms of structural trends obtained from Rietveld refinements of the crystal structures of the compounds against the powder diffraction patterns. No structural phase transitions have been observed. While gehlenite behaves like a ’proper’ layer structure, the aluminates show increased framework structure behaviour. This is most probably explained by stronger coulombic interactions between the tetrahedral conformation and the layer-bridging cations due to the coupled substitution (Ca²⁺+Si⁴⁺)-(Ln ³⁺+Al³⁺) in the melilite-type structure. Electronic Supplementary Material Supplementary material is available for this article at     

Simulation of Precipitation in Monsoon Regions of China by CMIP3 Models

The output of 25 models used in the Coupled Model Intercomparison Project phase 3 （CMIP3） were evaluated, with a focus on summer precipitation in eastern China for the last 40 years of the 20th century. Most models failed to reproduce rainfall associated with the East Asian summer monsoon （EASM）, and hence the seasonal cycle in eastern China, but provided reasonable results in Southwest （SW） and Northeast China （NE）. The simulations produced reasonable results for the Yangtze-Huai （YH） Basin area, although the Meiyu phenomenon was underestimated in general. One typical regional phenomenon, a seasonal northward shift in the rain belt from early to late summer, was completely missed by most models. The long-term climate trends in rainfall over eastern China were largely underestimated, and the observed geographical pattern of rainfall changes was not reproduced by most models. Precipitation extremes were evaluated via parameters of fitted GEV （Generalized Ex- treme Values） distributions. The annual extremes were grossly underestimated in the monsoon-dominated YH and SW regions, but reasonable values were calculated for the North China （NC） and NE regions. These results suggest a general failure to capture the dynamics of the EASM in current coupled climate models. Nonetheless, models with higher resolution tend to reproduce larger decadal trends and annual extremes of precipitation in the regions studied.     

GLDAS和CMIP5产品的中国土壤湿度-降水耦合分析及变化趋势

利用GLDAS同化产品和12个CMIP5模式的输出结果,从土壤湿度对降水影响的两个中间环节出发,通过分析陆面耦合指数ILH、潜热通量—抬升凝结高度耦合指数ILCL以及抬升凝结高度ZLCL间接研究中国区域土壤湿度与降水间耦合特征,并对1958~2013年及RCP4.5辐射强迫情景下50年(2006~2055年)的4个代表性区域夏季耦合强度的年代际变化特征进行分析。研究发现:1958~2013年期间,内蒙古阴山山脉附近、新疆和青海的部分地区为夏季中国土壤湿度与降水耦合的最强区域;陆面耦合指数ILH变化幅度从高到低依次出现在华北、华南、内蒙古中部和西北地区,并在20世纪70年代中到80年代中发生转折。2006~2055年的平均而言,预估内蒙古阴山山脉附近仍为耦合最强区;与历史时期(1958~2005年)比较,新疆中部和内蒙古阴山山脉附近的耦合指数ILH增大,而广西和广东地区的则减小;对于耦合指数ILH的年代际变化(2006~2055年),2026~2035年间华北最大而华南最小,西北地区变化不大,而内蒙古中部地区的耦合强度逐渐增大。     

An analytical approach to small amplitude solutions of the extended nearly circular Sitnikov problem

The model of extended Sitnikov Problem contains two equally heavy bodies of mass m moving on two symmetrical orbits w.r.t the centre of gravity. A third body of equal mass m moves along a line z perpendicular to the primaries plane, intersecting it at the centre of gravity. For sufficiently small distance from the primaries plane the third body describes an oscillatory motion around it. The motion of the three bodies is described by a coupled system of second order differential equations for the radial distance of the primaries r and the third mass oscillation z. This problem which is dealt with for zero initial eccentricity of the primaries motion, is generally non integrable and therefore represents an interesting dynamical system for advanced perturbative methods. In the present paper we use an original method of rewriting the coupled system of equations as a function iteration in such a way as to decouple the two equations at any iteration step. The decoupled equations are then solved by classical perturbation methods. A prove of local convergence of the function iteration method is given and the iterations are carried out to order 1 in r and to order 2 in z. For small values of the initial oscillation amplitude of the third mass we obtain results in very good agreement to numerically obtained solutions.     

Dynamic soil–structure interaction analysis via coupled finite-element–boundary-element method

In this paper, a study on the transient response of an elastic structure embedded in a homogeneous, isotropic and linearly elastic half-plane is presented. Transient dynamic and seismic forces are considered in the analysis. The numerical method employed is the coupled Finite-Element–Boundary-Element technique (FE–BE). The finite element method (FEM) is used for discretization of the near field and the boundary element method (BEM) is employed to model the semi-infinite far field. These two methods are coupled through equilibrium and compatibility conditions at the soil–structure interface. Effects of non-zero initial conditions due to the pre-dynamic loads and/or self-weight of the structure are included in the transient boundary element formulation. Hence, it is possible to analyse practical cases (such as dam–foundation systems) involving initial conditions due to the pre-seismic loads such as water pressure and self-weight of the dam. As an application of the proposed formulation, a gravity dam has been analysed and the results for different foundation stiffness are presented. The results of the analysis indicate the importance of including the foundation stiffness and thus the dam–foundation interaction.     

Peak discharge increase in hyperconcentrated floods

The peak of river floods usually decreases in the downstream direction unless it is compensated by freshwater inflow from tributaries. In the Yellow River (China) the opposite is regularly observed, where the peak discharge of river floods increases in the downstream direction (at a rate far exceeding the contribution from tributaries). This flood peak discharge increase is probably related to rapid morphological changes, to a modified bed friction, or to a combination of both. Yet the relative role of these processes is still poorly understood. This paper aims to analyze the relative contribution of bed erosion and friction change to the peak discharge increase, based on available data and a recently developed numerical model. Using this high-resolution, fully coupled morphodynamic model of non-capacity sediment transport, two hyperconcentrated floods characterized by downstream peak discharge increase are numerically reproduced and analyzed in detail. The results reveal that although erosion effects may contribute to the downstream discharge increase (especially in case of extreme erosion), for most cases the increase must be mainly due to a reduction in bed friction during peak discharge conditions. Additionally, based on the concept of channel storage reduction, the effects of decreasing bed friction and (very strong) bed erosion can be integrated in explaining the peak discharge increase.