西南极乔治王岛长城站区晚第四纪燕窝湖岩芯元素地球化学特征

本文阐述了乔治王岛长城站区燕窝湖沉积物中微量元素及某些常量元素的含量、分布、富集系数和相关系数的变化规律 ,探讨了该湖岩芯物质来源及气候环境的阶段性变迁 ,认为一方面燕窝湖周围碎屑沉积岩 (包括火山沉积岩 )是进入沉积体系的主要物源 ;另一方面 ,地幔物质也是其物源之一 ;同时 ,并不排除南极大陆冰进期搬运来的陆源物质进入沉积体系。     

地层综合柱状图自动绘制的技术研究

介绍的软件及绘制技术成功地处理了地层综合柱状图中的化石、火成岩及相变等的绘制技术问题；其自动化程度高，具有很大的灵活性，以适应不同格式图件的要求。通过自编的接口软件由原始数据最终形成ＡｕｔｏＣＡＤ环境下的二进制图形交换文件。     

Evaluating the transport and removal of chromate using pyrite and biotite columns

To remove chromate from a wastewater, a porous permeable reactive barrier system (PRBS), using pyrite and biotite, was adapted. This study included bench‐scale column experiments to evaluate the efficiency of the PRBS and investigate the reaction process. The total chromium concentration of the effluent from the biotite and pyrite columns reached the influent concentration of 0·10 mM after passing through more than 150 pore volumes (PVs) and 27 PVs respectively, and remained constant thereafter. The Cr^VI concentration in the effluent from the biotite column became constant at about 0·08 mM , accounting for approximately 80% of the influent concentration, after passing through 200 PVs. Moreover, in the pyrite column, the Cr^VI concentration remained at about 0·01 mM , 10% of the input level, after passing through 116 PVs. This shows that both columns maintained their levels of chromate reduction once the Cr^VI breakthrough curves (BTCs) had reached the steady state, though the steady‐state output concentration of total chromium had reached the influent level. The variances of the iron concentration closely followed those of the chromium. The observed data for both columns were fitted to the predicted BTCs calculated by CXTFIT, a program for estimating the solute transport parameters from experimental data. The degradation coefficient µ of the total chromium BTCs for both columns was zero, suggesting the mechanisms for the removal of chromate limit the µ of the Cr^VI BTCs. The Cr^VI degradation of the pyrite column (6·60) was much greater than that of the biotite column (0·27). In addition, the Cr^VI retardation coefficient R of the pyrite column (253) was also larger than that of the biotite column (125). The R values for the total chromium BTCs from both columns were smaller than those of the Cr^VI BTC. Whereas the total chromium BTC for the pyrite column showed little retardation (1·5), the biotite column showed considerable retardation (80). The results for the 900 °C heat‐treated biotite column were analogous to those of the control column (quartz sand). This suggests that the heat‐treated biotite played no role in the retardation and removal of hexavalent chromium. The parameters of the heat‐treated biotite were calculated to an R of 1·2 and µ of 0·01, and these values confirmed quantitatively that the heated biotite had little effect on the transport of Cr^VI. These solute transport parameters, calculated by CXTFIT from the data obtained from the column tests, can provide quantitative information for the evaluation of bench‐ or field‐scale columns as a removal technology for Cr^VI in wastewater or contaminated groundwater. Copyright © 2006 John Wiley & Sons, Ltd.     

华北煤矿奥灰突水特点及防治对策研究

奥陶系灰岩含水层是华北地区各矿区煤层开采的重要水害,通过对奥灰突水及相关的案例分析,认为奥灰突水多发生在区域降水量大于700mm的矿区;导水断层和陷落柱是造成突水的主要通道;奥灰水也可以通过补给薄层灰岩而进入矿井;不同层段的奥灰岩,其富水性不同,奥灰岩顶界具有一定的隔水作用。针对华北地区煤矿奥灰突水特点,提出其防范对策应是加强不同层位的水文地质探查,重点防范集中导水通道突水,并进行中间层的改造。     

不同龄期垃圾渗滤液对浅层地下水污染的实验研究

为了深入了解垃圾渗滤液对浅层地下水污染的机理,揭示不同龄期垃圾渗滤液在浅层地下水中多组分运移规律,文章以阜新市垃圾填埋场为研究对象,通过室内土柱对比实验,研究了不同龄期垃圾渗滤液在浅层地下水中多组分运移的机理和规律。结果表明不同龄期垃圾渗滤液在入渗过程中都会引起地下水不同程度的污染,且新鲜垃圾渗滤液较老龄垃圾渗滤液更易污染地下水,其污染机理主要为吸附、解析、溶解、沉淀和离子交换等水岩作用。研究结果为今后垃圾填埋场的治理和地下水的修复提供理论依据。     

内蒙古天和永新生代玄武岩成因及其地质意义

天和永玄武岩为碧玄岩,至少可以划分出3种矿物共生组合类型。天和永玄武岩总体具有贫硅(w(SiO2)=43.97%～45.68%)、富碱(w(K2O+Na2O)=5.91%～7.65%)、富钾(w(K2O)=2.04%～2.89%)、高钛(w(TiO2)=2.18%～2.37%)、高Mg值(Mg#=68～76)的特征;稀土元素含量高(∑REE=(246.62～329.82)×10-6),稀土配分曲线呈右倾平滑直线,强烈富集轻稀土,轻重稀土强烈分馏((La/Yb)N>30),无明显的Eu(δEu=0.90～1.02)和Ce异常(δCe=0.96～1.00);强烈富集不相容元素,其中高场强元素(HFSE)Nb、Ta和Th出现峰值,具有近似OIB配分型式的特征;玄武岩富含相容元素Co((39.1～48.9)×10-6)、Ni((130～257)×10-6)、Cr((138～320)×10-6)。上述所有特征以及岩石结晶程度低、富含橄榄岩包体和少量捕虏晶、元素变异关系等均表明,天和永玄武岩是原生玄武岩质岩浆固结的产物。微量元素比值Ba/Rb(12～35)和碱金属的变化暗示源区可能遭受过流体的交代作用,源岩可能是富集的二辉橄榄岩。岩石成因模拟表明,形成天和永玄武岩的原生岩浆是在变压、部分熔融的条件下富集地幔源区岩石非实比熔融的产物,变压熔融柱穿切了Sp/Gt二辉橄榄岩相边界。岩浆形成于源区岩石的低度(约<5%)部分熔融,其中石榴石二辉橄榄岩部分熔融约为1%,尖晶石二辉橄榄岩部分熔融2%～5%。综合分析显示,源区部分熔融的触发机制是边际驱动的地幔对流,因而其形成深度大于东部的集宁玄武岩和汉诺坝玄武岩。     

天津市新建的具有独特风格的桥梁

天津市近几年来新建了多座具有独特风格和景观效果的新型桥梁,本文主要介绍其中的三座斜拉桥、三座拱桥、一座自锚式悬索桥和一座集交通、观光、游览为一体的巨型摩天轮桥梁,以及三座经装修改建、使旧桥换新颜的实例。     

国庄矿北大巷突水通道分析

通过对突水水源、突水量特点、固体突出物的总量、突出物的成分组合、突出物的形状以及松散物的主要成分等分析,认为肥城煤田国庄矿北大巷突水通道为岩溶陷落柱。      

东海沉积物中磷的存在形态及其环境意义

By means of SEDEX, ASPILA and XRF, depth-dependent changes of different phosphorus forms in sediment cores from specific areas of the offshore Changjiang Estuary (Yangtze Estuary) in 1998 were analyzed. Results show that contents of total phosphorus (TP), organic-phosphorus (OP) and iron-phosphorus (Fe-P) decreased down-core, while those of absorbed-phosphorus (Ad-P) andcalcium-phosphorus (Ca-P) increased. The distribution tendency of detritus-phosphorus (De-P) is not obvious. Results also show that TP, Fe-P and OP contents at Meso station of the Changjiang Estuary and Hangzhou Bay are higher than that of the other stations. This suggests that the pollutants carried by the Changjiang and the Qiantang rivers from inland have affected the natural environment inoffshore area. TP, Fe-P and OP contents of each station become higher from bottom to top, indicating the amount of the terrestrial pollutants carried by the two rivers has been enhanced since the last 30-50 years. Ad-P, Ca-P, Fe-P and OP are all active phosphorus in sediments, and their re-cycling in sediment is closely related to each other.