贵州梵净山地区震旦系微量元素特征及沉积环境

为了详细研究梵净山地区震旦系沉积地球化学特征及沉积环境演化,笔者对该处永义剖面自下而上进行系统采样.样品分析结果表明该处剖面稀土元素呈轻稀土(LREE)富集,重稀土(HREE)亏损,铈总体上表现为亏损,垂向上逐渐变小,铕异常发生3次波动,表明该处震旦系沉积时总体上为氧化环境,局部沉积环境发生变化.而且陡山沱组底部"碳酸盐帽"稀土元素标准化分配模式不同于冷泉碳酸盐岩分配模式,表明两者处于不同的沉积环境,成因上无关.V/Cr、Ni/Co、U/Th及V/V Ni等微量元素比值均表明震旦系沉积时为总体上氧化环境,但垂向上仍有沉积环境及水体分层性的变化.     

南海北部C4站柱状沉积中的孢粉组合及其古环境意义

对南海北部C4站柱状沉积剖面进行了高分辨率孢粉、藻类成分的分析和研究,同时测定了部分样品的AMS14C年代,划分了该站柱状沉积物地层时代,相应恢复了南海北部9 800 a B P以来植被、气候、环境的3个演替阶段.南海北部C4站从下至上可划分成3个孢粉组合带,依次为:1带(258～194 cm):以Pinus-Quercus(常绿)-Polypodiaceae-Pterdium-Pteris-Dicranopteris-Adiantum为主孢粉带;2带(194～94 cm):以Pinus-Quercus(常绿)-Pteridium-Polypodiaceae-Microlepia-Dicranopteris为主孢粉带;3带(94～4 cm):以Pinus-Pteridium-Polypodiaceae-Quercus(常绿)-Microlepia-Dicranopteris为主孢粉带.与3个孢粉带相对应的古植被阶段依次为:伴有针叶树的常绿阔叶、落叶阔叶混交林,热带半常绿季雨林,热带常绿阔叶、落叶阔叶混交林,与周边地区的植被演替相一致.由此可见,研究区经历了全新世早期气候转暖,中期气候炎热、干湿季明显、海平面上升以及晚期气候暖热、湿润3个古环境演变阶段.     

ZDR柱识别方法在海南地区的应用

基于双偏振天气雷达的相关研究大部分集中在雷达如何识别粒子相态、精细化探测云系垂直结构方面,专门针对差分反射率因子ZDR柱的识别研究相对较少。通过对海南地区对流云系特征进行分析研究,提出一套基于双偏振雷达探测数据（2020—2021年）的ZDR柱识别方法,结合多源资料对发生在海南地区的2次对流天气过程展开分析,〖JP2〗验证ZDR柱识别效果。结果表明：①ZDR柱通常在对流云系前中期较为深厚,最大可达0 ℃层以上3～5 km,〖JP〗在空间分布上ZDR柱与雷达径向速度的辐合有密切关系,其正负径向速度对的差值与ZDR柱的强弱变化规律呈正相关,并且深厚的ZDR柱较大概率出现在对流云系运动方向的前缘位置,与对流云团雷达反射率因子较大区域（≥50 dBz）有明显的对应关系;②ZDR柱最大深度的变化趋势同雷达回波顶高和垂直累计液态水含量有弱相关性,雷达回波顶高和垂直累计液态水含量的变化通常滞后于ZDR柱深度的变化（约12～15 min）。该方法具备识别海南岛地区ZDR柱现象的能力,可以在分析强对流天气过程、人工影响天气指挥和短临灾害天气预警等方面发挥应用效益。     

概括平差模型的解法探讨

分析了概括平差模型系数矩阵可能出现非列满秩情况的原因,研究了如何使系数矩阵为列满秩矩阵,避免了系数矩阵为非列满秩时的复杂解算过程。     

单柱离子色谱测定二氧化锰产品中无机阴离子杂质

采用了单柱离子色谱法测ＭｎＯ２产品中无机离子杂质；提出了消除干扰的可行途径，将Ｌａ（ＯＨ）３加入后能同时消除进样峰的干扰和溶剂峰的出现。选用１．７５ｍｍｏｌ／Ｌ邻苯二甲酸１．７５ｍｍｏｌ／Ｌ三羟甲基氨基甲烷为混合淋洗剂测定Ｆ＾－，Ｃｌ＾－，ＮＯ３＾和ＳＯ＾２－４，其标准加入回收率为９５％－１０５％；ＲＳＤ（ｎ＝７）为２．４７％－８．０８％。     

Identification and occurrence of novel C36–C54 3,4-dialkylthiophenes with an unusual carbon skeleton in immature sediments

A series of novel long-chain 3,4-dialkylthiophenes (C₃₆–C₅₄) was identified in a number of sediments ranging from Pleistocene to Cretaceous. The identifications were based on mass spectral characterisation, desulphurisation and mass spectral data of synthesised model compounds. These organic sulphur compounds are probably formed by sulphur incorporation into mid-chain dimethylalkadienes with two methylenic double bonds. These putative precursor lipids are unprecedented and may be considered rather unusual. The distribution of 3,4-dialkylthiophenes in sediments varies considerably with the depositional palaeoenvironment, indicating that these compounds have a potential as molecular markers reflecting changes in palaeoenvironment.     

Time effects on dynamic soil properties under random excitation conditions

Two types of clayey soils, a kaolinite and a bentonite, were tested using a resonant column apparatus under random excitation conditions. The concept of root mean square (rms) strain was utilized for the purpose of strain calculations during random loading. The conventional estimator of the transfer function was used for random vibration analysis. The effect of confinement duration (at a constant pressure) on dynamic soil properties, namely damping and shear modulus, was evaluated. The results indicate that for both cohesive soils, the effect of time was less pronounced during random vibration than sinusoidal loading at the same rms strain. This effect is however more pronounced when the peak shearing strain of sinusoidal loading is considered. Furthermore, time effects were more pronounced at low strain levels than at high strain levels.     

耗能-隔震柔性底层钢管混凝土-钢筋混凝土组合框架的实验研究

本文用钢管混凝土柱作为结构底层耗能柱、用承重墙和隔震器控制结构底层倒塌破坏,从而提出了一种新的耗能-隔震柔性底层结构体系。通过本文12根钢管混凝土柱和文献[7]中7根钢管混凝土柱的低周疲劳实验,初步确定了钢管混凝土柱地震损伤模型的参数;通过两个钢管混凝土-钢筋混凝土三层框架模型和一个纯钢筋混凝土三层框架模型的拟动力实验,研究和比较了两类结构体系的地震损伤。     

青藏高原崇测冰芯氯离子、硫酸根离子记录

通过对青藏高原崇测冰帽一支18．70m冰芯中Cl^-、SO4^2-离子含量变化的分析表明，20世纪90年来Cl^-、SO4^2-离子含量在波动中呈下降趋势，两种离子的周期性波动变化相似，20世纪晚期比早期和中期的波动幅度小，总体上离子含量逐渐减少与温度在波动中上升相一致，但每一次温度的升高与离子含量的下降并非一一对应。陆源物质和青藏高原上的盐湖是冰芯中Cl^-、SO4^2-离子的主要贡献者。揭示了研究地区大气成分和环境变化与气候变化的关系及亚洲粉尘在全球环境变化中的源区地位。     

REMOTE SENSING OF THE SEASONAL VARIATION IN COLUMN ABUNDANCE OF ATMOSPHERIC CH4*

Infrared solar spectra on clear days were measured automatically by an infrared solar spectrometer(ISS) with 0.4 cm^-1 resolution developed by us.A line-by line(LBL) computation method was used to calculate theoretical atmospheric absorption.In the wavelength range of 3.410-3.438 μm.the absorption is mainly due to atmospheric methane and water vapor.Columnatmospheric methane was retrieved from the recorded infrared solar spectra.The seasonal variation of column atmospheric methane in Hefei has been obtained from the measuremental data of nearly 18 months since the April of 1997.and found that it is similar to that of background data.The instruments.principles of measurement and some of results were introduced,and the results are also discussed briefly in the paper.