Raman spectroscopic study of K-lingunite at various pressures and temperatures

K-lingunite is a high-pressure modification of K-feldspar that possesses the tetragonal hollandite structure. Variations of the Raman spectra of K-lingunite were studied up to ~31.5 GPa at room temperature, and in the range 79–823 K at atmospheric pressure. The Raman frequencies of all bands were observed to increase with increasing pressure, and decrease with increasing temperature for K-lingunite. This behavior is in line with those observed for most of other materials. New sharp Raman bands appear at pressures greater than 13–15 GPa, suggesting a phase transition in K-lingunite with increasing pressure. The transition is reversible when pressure was released. The appearance of these new Raman bands may correspond to the phase transition revealed earlier at around 20 GPa by X-ray diffraction studies. Instead of transforming back to its stable minerals, such as orthoclase, microcline or sanidine, K-lingunite became amorphous in the temperature range 803–823 K at atmospheric pressure.     

土压力问题的变分解答

用变分学方法导出了与朗肯土压力公式和库伦土压力公式完全一致的土压力计算公式，并且一般情况下的极值曲线线不同一条直线，而是比较复杂的曲线，在 倾斜边坡情况下的伦公式仅仅是一个特解。     

Design of drainage blankets for leachate recirculation in bioreactor landfills using two-phase flow modeling

Drainage blankets (DB) are used for leachate recirculation in bioreactor landfills and consist of highly permeable material placed over a large area of the landfill with the leachate injection pipe embedded in the material at specified locations. DBs are generally installed at different depth levels during the waste filling operations. Very limited information is reported on performance of DBs, and that which exists is based on a small number of field monitoring and modeling studies. A rational method for the design of landfills using DBs has not been developed. This study performs a parametric analysis based on a validated two-phase flow model and presents design charts to guide the design of DBs for given hydraulic properties of MSW, the leachate injection rate and the dimensions and locations of the DB as measured from the leachate collection and recirculation system (LCRS) located at the bottom of the landfill cell. Numerical simulations were performed for the two established MSW conditions: homogeneous–isotropic and heterogeneous–anisotropic waste. The optimal levels of leachate saturation, wetted width, wetted area and developed pore water and pore gas pressures were determined, and design charts using the normalized parameters were developed. An example is presented on the use of design charts for typical field application.     

Low-pressure evolution of arc magmas in thickened crust: The San Pedro–Linzor volcanic chain,Central Andes,Northern Chile

Magmatism at Andean Central Volcanic Zone (CVZ), or Central Andes, is strongly influenced by differentiation and assimilation at high pressures that occurred at lower levels of the thick continental crust. This is typically shown by high light to heavy rare earth element ratios (LREE/HREE) of the erupted lavas at this volcanic zone. Increase of these ratios with time is interpreted as a change to magma evolution in the presence of garnet during evolution of Central Andes. Such geochemical signals could be introduced into the magmas be high-pressure fractionation with garnet on the liquidus and/or assimilation from crustal rocks with a garnet-bearing residue. However, lavas erupted at San Pedro–Linzor volcanic chain show no evidence of garnet fractionation in their trace element patterns. This volcanic chain is located in the active volcanic arc, between 22°00^′S and 22°30^′S, over a continental crust ∼70 km thick. Sampled lavas show Sr/Y and Sm/Yb ratios <40 and <4.0, respectively, which is significantly lower than for most other lavas of recent volcanoes in the Central Andes. In addition, ⁸⁷Sr/⁸⁶Sr ratios from San Pedro–Linzor lava flows vary between 0.7063 and 0.7094. This is at the upper range, and even higher than those observed at other recent Central Andean volcanic rocks (<0.708). The area in which the San Pedro–Linzor volcanic chain is located is constituted by a felsic, Proterozoic upper crust, and a thin mafic lower crustal section (<25 km). Also, the NW–SE orientation of the volcanic chain is distinctive with respect to the N–S orientation of Central Andean volcanic front in northern Chile. We relate our geochemical observations to shallow crustal evolution of primitive magmas involving a high degree of assimilation of upper continental crust. We emphasize that low pressure AFC- (Assimilation Fractional Crystallization) type evolution of the San Pedro–Linzor volcanic chain reflects storage, fractionation, and contamination of mantle-derived magmas at the upper felsic crust (<40 km depth). The ascent of mantle-derived magmas to mid-crustal levels is related with the extensional regime that has existed in this zone of arc-front offset since Late-Miocene age, and the relatively thin portion of mafic lower crust observed below the volcanic chain.     

Pseudo-dynamic methods for seismic passive earth pressure behind a cantilever retaining wall with inclined backfill

The designing of retaining walls requires the complete knowledge of earth pressure distribution. Under earthquake conditions the design needs special attention to reduce the devastating effect, but under seismic conditions, the available literature mostly uses the pseudo-static analytical solution as an approximate to the real dynamic nature of the complex problem. This paper shows a detailed study on the seismic passive earth thrust behind a cantilever retaining wall with inclined backfill surface by pseudo-dynamic analysis. A planar failure surface has been considered. The effect of variation of parameters such as soil friction angle, wall friction angle and back fill inclination have been explored. A complete analysis shows that the time dependent non-linear behaviour of the pressure distribution obtained in the present method results in more realistic design values of earth pressures under earthquake conditions. Results are provided in tabular and graphical non-dimensional form and compared thoroughly with the existing values in the literature.     

低温高压微地质体中微米纳米级矿物相研究——以大冶葡萄石中绿纤石和多硅白云母为例

低温高压地质体因与地壳碰撞、俯冲等构造活动密切相关,长期以来一直是国内外地学界关注的研究对象。但由于受研究手段、分辨能力所限,对于呈微米纳米级微粒形式存在于低温高压微地质体（即矿物）中的成分、物相及其成因等问题的研究,至今仍是地学研究中的薄弱环节。随...     

开采沉陷土体变形与孔隙水压相互作用研究进展

本文通过实验、实测和理论分析研究了开采沉陷土体变形与孔隙水压力之间的相互作用,结果表明,随着开采的进行,土体的应力变形发生变化造成了超静孔隙水压力的产生和消散,反映在土体变形上出现随开采时间延续而发展的附加压缩和膨胀变形,这种压缩或膨胀在土体的不同部位相互叠加,有时还叠加了底部含水层水位下降引起的地面下沉。这些结果揭示了厚松散含水层地区开采沉陷特殊性的机理,对开采沉陷预测及水体下采煤具有重要意义。     

固结不排水剪总应力强度指标的几点讨论

建立了偏离室内常规三轴压缩试验应力条件下的总应力强度指标和有效固结压力强度指标的理论公式;讨论了这两种强度指标的变化规律及其与室内常规CU试验指标的差异;简要地分析了直接将室内常规CU试验指标用于压缩与伸长土单元的强度计算、用于有效固结压力法确定抗剪强度和用于土压力与地基极限承载力计算时的偏差情况。     

西华山脉钨矿床的形成压力及有关花岗岩的侵位深度

文章阐述了西华山黑钨矿-石英脉与普通热液石英脉的不同之处;分析了前人所获压力值较低(30~70MPa)的主要原因;利用黑钨矿-石英脉绿柱石中两相气液包裹体和不混溶硅酸盐熔融包裹体的有关资料及相关相图,求得西华山脉钨矿床的形成压力为200MPa。根据西华山脉钨矿床产出的地质特征以及岩石学、矿物学、稳定同位素和流体包裹体地球化学等证据论证了这一压力的合理性。     

葡萄石的热膨胀性与压缩性及其地质意义

利用同步辐射X射线衍射及拉曼光谱技术对葡萄石分别进行了原位高温及原位高压实验。原位高温实验结果表明葡萄石的热膨胀系数为K=1. 77(3)×10~(-5)K~(-1),轴向热膨胀系数具有各向异性(α_aα_bα_c),葡萄石在1073K时开始发生脱水反应,分解为钙长石及硅灰石。原位高压X射线衍射实验结果表明,在大于12. 4GPa时,葡萄石的晶胞参数发生不连续变化,可能发生了相变;在24. 0GPa左右,葡萄石发生不可逆的非晶化转变。原位高压拉曼光谱表明,葡萄石在12. 6GPa左右发生相变,这一相变很可能与其[(Si,Al)O_4]四面体中的Si发生有序排列有关。结合葡萄石的热膨胀性及压缩性,我们确定了葡萄石在高温高压下的稳定范围,这一结果对认识上地幔中含水矿物的状态以及地幔中水的来源有重要意义。