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Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn2+-ions from sewage and rinsing water. 相似文献
23.
Current states of stress in the northern Andes as indicated by focal mechanisms of earthquakes 总被引:1,自引:3,他引:1
Systematic inversion of double couple focal mechanisms of shallow earthquakes in the northern Andes reveals relatively homogeneous patterns of crustal stress in three main regions. The first region, presently under the influence of the Caribbean plate, includes the northern segment of the Eastern Cordillera of Colombia and the western flank of the Central Cordillera (north of 4°N). It is characterized by WNW–ESE compression of dominantly reverse type that deflects to NW–SE in the Merida Andes of Venezuela, where it becomes mainly strike–slip in type. A major bend of the Eastern thrust front of the Eastern Cordillera, near its junction with the Merida Andes, coincides with a local deflection of the stress regime (SW–NE compression), suggesting local accommodation of the thrust belt to a rigid indenter in this area. The second region includes the SW Pacific coast of Colombia and Ecuador, currently under the influence of the Nazca plate. In this area, approximately E–W compression is mainly reverse in type. It deflects to WSW–ENE in the northern Andes south of 4°N, where it is accommodated by right-lateral displacement of the Romeral fault complex and the Eastern front of the northern Andes. The third, and most complex, region is the area of the triple junction between the South American, Nazca and Caribbean plates. It reveals two major stress regimes, both mainly strike–slip in type. The first regime involves SW–NE compression related to the interaction between the Nazca and Caribbean plates and the Panama micro-plate, typically accommodated in an E–W left-lateral shear zone. The second regime involves NW–SE compression, mainly related to the interaction between the Caribbean plate and the North Andes block which induces left-lateral displacement on the Uramita and Romeral faults north of 4°N.Deep seismicity (about 150–170 km) concentrates in the Bucaramanga nest and Cauca Valley areas. The inversion reveals a rather homogeneous attitude of the minimum stress axis, which dips towards the E. This extension is consistent with the present plunge of the Nazca and Caribbean slabs, suggesting that a broken slab may be torn under gravitational stresses in the Bucaramanga nest. This model is compatible with current blocking of the subduction in the western northern Andes, inhibiting the eastward displacement of slabs, which are forced to break and sink in to the asthenosphere under their own weight. 相似文献
24.
The Okavango giant mafic dyke swarm (NE Botswana): its structural significance within the Karoo Large Igneous Province 总被引:1,自引:0,他引:1
Bernard Le Gall Gomotsang Tshoso Jrme Dyment Ali Basira Kampunzu Fred Jourdan Gilbert Fraud Herv Bertrand Charly Aubourg William Vtel 《Journal of Structural Geology》2005,27(12):783
The structural organization of a giant mafic dyke swarm, the Okavango complex, in the northern Karoo Large Igneous Province (LIP) of NE Botswana is detailed. This N110°E-oriented dyke swarm extends for 1500 km with a maximum width of 100 km through Archaean basement terranes and Permo-Jurassic sedimentary sequences. The cornerstone of the study is the quantitative analysis of N>170 (exposed) and N>420 (detected by ground magnetics) dykes evidenced on a ca. 80-km-long section lying in crystalline host-rocks, at high-angle to the densest zone of the swarm (Shashe area). Individual dykes are generally sub-vertical and parallel to the entire swarm. Statistical analysis of width data indicates anomalous dyke frequency (few data <5.0 m) and mean dyke thickness (high value of 17 m) with respect to values classically obtained from other giant swarms. Variations of mean dyke thicknesses from 17 (N110°E swarm) to 27 m (adjoining and coeval N70°E giant swarm) are assigned to the conditions hosting fracture networks dilated as either shear or pure extensional structures, respectively, in response to an inferred NNW–SSE extension. Both fracture patterns are regarded as inherited brittle basement fabrics associated with a previous (Proterozoic) dyking event. The Okavango N110°E dyke swarm is thus a polyphase intrusive system in which total dilation caused by Karoo dykes (estimated frequency of 87%) is 12.2% (6315 m of cumulative dyke width) throughout the 52-km-long projected Shashe section. Assuming that Karoo mafic dyke swarms in NE Botswana follow inherited Proterozoic fractures, as similarly applied for most of the nearly synchronous giant dyke complexes converging towards the Nuanetsi area, leads us to consider that the resulting triple junction-like dyke/fracture pattern is not a definitive proof for a deep mantle plume in the Karoo LIP. 相似文献
25.
微食物环是海洋生态系统中重要的物质和能量过程,是传统食物链的有效补充。微食物环研究是当前海洋生态学研究的热点之一,但对其结构的系统研究较少,海洋微食物网结构在2000年才被Garrison提出。尽管微食物网各个类群的丰度在不同海洋环境中有相对变化,但是这些变化都处于一定的范围之内,其丰度结构约为纤毛虫10 cell ml-1、鞭毛虫103 cell ml-1、微微型真核浮游生物104 cell ml-1、蓝细菌104-5 cell ml-1、异养细菌106 cell ml-1、病毒107 particle ml-1。海洋浮游食物链中捕食者和饵料生物粒径的最佳比值为10:1,实际研究中该比值会略低,例如纤毛虫与其饵料的粒径比值为8:1,鞭毛虫为3:1。Pico和Nano浮游植物的丰度比(Pico:Nano)是研究微食物网结构的指数之一,该指数具有不受研究尺度影响的优点,可用于研究区域性和全球性微食物网结构。近年来,学者们从多角度对海洋微食物网的结构开展了研究,不同海区微食物网各类群丰度、生物量的时间和空间变化研究有很多报道,微食物网的结构可受空间、季节、摄食、营养盐等多种因素影响。在对不同空间微食物网的研究中,学者往往研究不同物理性质的水团中各类群生物丰度的不同,以此来表征微食物网结构的不同;同一海区微食物网结构的季节变化也是使用各个类群丰度和生物量的变化来表示,该变化主要受水文环境因素影响。摄食者对微食物网各类生物的影响通过三种途径:1. 中型浮游动物摄食;2. 中型浮游动物摄食微型浮游动物,通过营养级级联效应影响低营养级生物;3. 中型浮游动物通过释放溶解有机物、营养盐影响细菌和低营养级生物。浮游植物通过产生化感物质和溶解有机物影响微食物网结构,而营养盐的浓度及变化则可以对微食物网产生直接或间接影响。 相似文献
26.
拟建中的虎跳峡水电站水库蓄水后距虎跳峡上游20 km处的龙蟠右岸变形体是否会突然失稳崩滑为许多人关注.本文在折射波勘探方法获得龙蟠变形体底界形态、埋深、规模的基础上,进一步利用折射波勘探已经采集的炮集记录识别的反射波、面波、折射波等来研究变形体的内部结构和弹性及非弹性参数,获得变形体内部存在纵向横向结构的依据以及面波和折射波衰减系数,进而估算了变形体介质横波和纵波的非弹性性质参数与弹性性质参数的比值分别为0000184和0000144.由此判断水库蓄水后因变形体介质大量孔隙充水,造成孔隙压增加和剪切强度降低,进而导致变形体可能发生稳定非弹性变形或滑动,但稳定变形或滑动是否会演化成突然的非稳定滑动尚缺乏资料的支持. 相似文献
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新冠肺炎疫情对经济全球化的影响分析 总被引:7,自引:6,他引:1
新冠肺炎疫情是第二次世界大战以来世界面临的最大危机,给世界带来巨大的冲击,包括人们的心理和生活、经济增长与就业、国家治理及世界治理等。这些影响使很多学者、评论家、大众、企业家乃至政府官员产生了非常悲观的情绪,舆论中不乏经济全球化将终结、全球供应链将大规模调整、世界治理格局将彻底改变等言论。本文通过建立“全球化的三角结构”剖析了经济全球化的动力机制,并结合疫情对世界的主要影响,试图揭示后疫情时代经济全球化的走势。我们认为,资本的“空间出路”、技术的“时空压缩”和国家的开放程度是驱动经济全球化的三个基本力量,这三者的变化及其相互作用结果影响着全球化进程。从动力机制看,全球化是一个没有终点且不断变化的历史过程,它不会倒退,而是波动。过去半个世纪以来,世界各国已经被全球化紧密地联系在一起,相互脱钩的代价极其昂贵,没有国家会选择完全脱钩。所谓的逆全球化现象,是全球化发展过程中世界格局变化及各国应对策略调整的结果。新冠肺炎疫情并不能影响全球化的资本和技术驱动力,但是可能影响国家的开放程度。如果疫情持续时间不是很长,经济全球化将很快会回归原有的发展轨迹,继续进行调整。各国也将继续围绕经济全球化进行斗争、妥协、再斗争,直至形成一个相对稳定的状态。因此,经济全球化可能因为应对疫情而踩下急刹车,甚至暂退半步,但很快将继续前行,向着“包容性全球化”的方向发展。 相似文献
29.
Martina Anelli Tommaso Julitta Luca Fallati Paolo Galli Micol Rossini Roberto Colombo 《国际地球制图》2019,34(5):459-472
Photogrammetry represents a non-destructive, cost-effective tool for coral reef monitoring, able to integrate traditional remote sensing techniques and support researchers’ work. However, its application to submerged habitats is still in early stage. We present new ways to employ Structure from Motion techniques to infer properties of reef habitats. In particular, we propose the use of Digital Surface Models and Digital Terrain Models for assessing coral colonies extension and height and discriminating between seabed and coral cover. Such information can be coupled with digital rugosity estimates to improve habitat characterization. DTM, DSM and orthophotos were derived and used to compute a series of metrics like coral morphologies, reef topography, coral cover and structural complexity. We show the potentialities offered by underwater photogrammetry and derived products to provide useful basic information for marine habitat mapping, opening the possibility to extend these methods for large-scale assessment and monitoring of coral reefs. 相似文献
30.
The structure of the Dalradian rocks of the Banffshire coast has been re-examined. It is shown that D1 structures face upwards along the entire section and the major Boyndie Syncline (Sutton and Watson 1956) must also be of D1, age and not D3 as proposed by Johnson (1962). D2 structures are developed in the west, most strongly in the Portsoy Group and Cowhythe Gneiss where they may be related to the Portsoy Thrust (Elles 1931). East of the Cowhythe Gneiss D2 structures are not developed but D3 structures are of local importance. Porphyroblast growth is considered to be post-D1, pre-D3 related to the ‘active’ D2 deformation in the west (Barrovian) and to the ‘static’ D2 interval in the east (Buchan). The wider implications of these conclusions for Dalradian structure are briefly considered. 相似文献