广西金牙金矿床石英的标型特征及其意义

本文通过对金牙金矿床石英的化学成分、包裹体、物理性质及稳定同位素等万面的矿物学特征研究,取得了有价值的成因信息和找矿标志。认为该矿床属浅成中低温地下热(卤)水渗滤型金矿床,成矿物质来源于地层围岩。还指出石英颗粒极细小,多为隐晶至微晶,自形程度低,呈白色或无色、透明;比重低,晶胞棱长a_o大而Co小、单位晶胞体积增大(与标准石英比);红外光谱有1个宽峰、4个吸收峰和2个强的特征峰的波段,具单峰或双峰发热光曲线(在50～350℃范围内);具结构铝,含Ca、Fe、Mn、Au、Ag、Co、Ni、Se、Te与∑REE等杂质元素,其中Au与Al成正相关,而Au与∑REE呈负相关;包裹体呈无色透明、个体细小且少,以液相为主.气液比低,且出现沸腾包体群,其含盐度低,无子矿物,Na、Ca较高,为富含CO_2,CH_4的Ca~(-2)-Na_a-HCO_3~1-Cl型地下热(卤-水(温度305～190℃、压力25669～16945kpa.深度小于1km);δ~(18)O、δ~(18)O_(H_2O)、δD值具大气降水特征,δ~(13)C值类似油田碳等特征,是找“金牙型”金矿的重要找矿标志。     

利用X射线粉晶衍射和电感耦合等离子体质谱法研究江西西华山钨矿床中黑钨矿的矿物学特征及指示意义

目前针对江西大型黑钨矿石英脉型钨矿床西华山的黑钨矿矿物学特征及指示意义研究较少。本文利用X射线粉晶衍射分析和电感耦合等离子体质谱分析技术对黑钨矿晶体结构、化学成分特征及空间变化规律开展研究。获得黑钨矿晶胞参数为a0=0.477 nm,b0=0.573 nm,c0=0.498 nm,β=90°21',属于锰钨铁矿,与前人得出的黑钨矿晶胞参数略有不同,代表不同元素对铁锰的类质同象替代。主要化学成分WO3、Fe O、Mn O的含量在空间上具有一定的变化规律,反映了成矿物质的运移特征。微量元素Sc、Y、Nb、Ta在垂向含量变化大,说明矿液运移具有复杂性。稀土总量ΣREEs较高(397.16×10-6~1071.11×10-6),具有强烈的Eu负异常,具重稀土富集左倾的"躺椅式"球粒陨石标准化配分模式。将西华山、盘古山、淘锡坑、大吉山4个典型矿床的黑钨矿稀土元素特征进行对比,反映产在花岗岩内接触带的黑钨矿的稀土总量(ΣREEs)相对最高,分馏最明显;产在花岗岩内及其外接触带的黑钨矿的稀土总量(ΣREEs)相对较低,分馏程度最不明显;而产在花岗岩外接触带的黑钨矿的稀土总量(ΣREEs)有高有低,分馏程度有强有弱。因此,黑钨矿的化学成分变化特征,可以有效地指示成矿物质空间运移特征、物质来源和矿床成因。     

雅鲁藏布缝合带巴尔蛇绿岩边部石英菱镁岩成因

石英(滑石)菱镁岩是基性岩、超基性岩与富CO2流体反应形成的一套硅化-碳酸盐化蚀变岩,常伴生金、汞、菱镁矿、碱金属矿化而在国外备受关注,但国内相关研究较薄弱。巴尔蛇绿岩位于西藏阿里地区,石英菱镁岩主要出露在蛇绿岩体东北边界,出露厚度约20 m,近北西西向延伸数千米。本文系统研究了雅鲁藏布缝合带西段巴尔蛇绿岩边部石英菱镁岩矿物学及地球化学特征。根据尖晶石镜下特征,划分为两个阶段:一阶段石英菱镁岩中尖晶石稳定存在,二阶段石英菱镁岩中尖晶石几乎全部蚀变(代表更强程度蚀变作用)。石英菱镁岩主要地球化学组成为Si O2、Mg O及CO2,8件样品主量元素含量变化较大,Si O2/Mg O比值波动较大,反映石英菱镁岩形成为非等化学过程。蛇纹石化橄榄岩与石英菱镁岩有着相似微量元素分布规律,表明同源性,但两者仍有较明显差异:两阶段石英菱镁岩LREE都较地幔橄榄岩略富集,从地幔橄榄岩到两阶段石英菱镁岩,HREE先亏损再略富集。微量元素标准化图解中,Sr在橄榄岩与石英菱镁岩中都为正异常,其含量随蚀变强度增强而增加。此外,两阶段石英菱镁岩均无Au、Hg矿化。     

Origin of Listwanite in the Luobusa Ophiolite, Tibet, Implications for Chromite Stability in Hydrothermal Systems

Listwanite from the Luobusa ophiolite,Tibet,forms a narrow,discontinuous band along the eastern part of the southern boundary fault. We undertook a detailed petrographic and geochemical study to understand the mineral transformation processes and the behaviour of major and trace elements during listwanite formation. Three alteration zones characterized by distinct mineral components and texture are recognized and,in order of increasing degree of alteration,these are: zoneIII is rich in serpentine minerals; zoneII is rich in talc and carbonates; and zoneI is mainly composed of carbonates and quartz. Geochemical data for the three alteration zones show significant modification of some major and trace elements in the protolith,although some oxides show linear correlations with Mg O. Gold mineralization is recognized in the Luobusa listwanite and may signify an important target for future mineral exploration. Gold enrichment occurs in both zoneI and zoneIIand is up to 0.91 g/t in one sample from zoneI. We show that CO2-rich hydrothermal fluids can modify both the occurrence and composition of chromite grains,indicating some degree of chromite mobility. Low-Cr anhedral grains are more easily altered than high-Cr varieties. The compositions of chromite and olivine grains in the listwanite suggest a dunite protolith.     

华北陆块南缘郁山铝土矿矿物组成研究

郁山铝土矿床是2006年河南省地质调查院在豫西新安县发现的一个大型隐伏铝土矿矿床。文章通过利用显微镜、X衍射、扫描电镜、电子探针、红外光谱、热重等手段分析发现,郁山铝土矿中的矿物组成有:铝矿物,黏土矿物,铁矿物,钛矿物,非晶质,其它微量矿物(锆石、电气石、硫磷铝锶矿、明矾石、斜长石、钾长石、石英、方解石)六大类。非晶质组分的存在是华北陆块南缘铝土矿研究中物质组分方面的一个突破,为华北陆块南缘铝土矿的物质来源,成矿过程以及物质成分变化研究提供了线索和证据。     

晚中新世-上新世黄土高原佳县红粘土剖面碳同位素记录与C4植被演化

新生代C4植被开始扩张的年代、过程和驱动机制是全球古气候变化研究的焦点问题.中国黄土高原的黄土-红粘土剖面保存了连续的古生态演化记录,是研究这一关键科学问题的理想载体.本文选择黄土高原北部佳县厚达64m的红粘土剖面(8.2～2.7Ma),对190个层位的次生方解石矿物进行了无机碳同位素测试,由此分析了晚中新世-上新世末的C4植被扩张和演化过程.C4植被持续增长与全球冰盖的扩张基本一致,表明气候变冷很可能导致了黄土高原区域气候的干旱化与降雨季节性的增强.C4植被的扩张存在明显的3个阶段,分别以6.6Ma和3.6Ma为界限,每一次扩张增加10％左右,暗示了全球性的构造事件对黄土高原植被演化的控制.此外,佳县红粘土剖面呈现10次持续时间为10 ～ 20万年的碳同位素正漂移事件,平均每40万年发生一次,说明40万年轨道周期也控制着C4植被的演化.     

Evidence of multi-stage faulting by clay mineral analysis: Example in a normal fault zone affecting arkosic sandstones (Annot sandstones)

Fault affecting silicoclastic sediments are commonly enriched in clay minerals. Clays are sensitive to fluid–rock interactions and deformation mechanisms; in this paper, they are used as proxy for fault activity and behavior. The present study focuses on clay mineral assemblages from the Point Vert normal fault zone located in the Annot sandstones, a Priabonian-Rupelian turbidite succession of the Alpine foredeep in SE France. In this area, the Annot sandstones were buried around 6–8 km below the front of Alpine nappes soon after their deposition and exhumed during the middle-late Miocene. The fault affects arkosic sandstone beds alternating with pelitic layers, and displays throw of about thirty meters. The fault core zone comprises intensely foliated sandstones bounding a corridor of gouge about 20 cm thick. The foliated sandstones display clay concentration along S–C structures characterized by dissolution of K-feldspar and their replacement by mica, associated with quartz pressure solution, intense microfracturation and quartz vein precipitation. The gouge is formed by a clayey matrix containing fragments of foliated sandstones and pelites. However, a detailed petrographical investigation suggests complex polyphase deformation processes. Optical and SEM observations show that the clay minerals fraction of all studied rocks (pelites and sandstones from the damage and core zones of the fault) is dominated by white micas and chlorite. These minerals have two different origins: detrital and newly-formed. Detrital micas are identified by their larger shape and their chemical composition with a lower Fe–Mg content than the newly-formed white micas. In the foliated sandstones, newly-formed white micas are concentrated along S–C structures or replace K-feldspar. Both types of newly formed micas display the same chemical composition confirmed microstructural observations suggesting that they formed in the same conditions. They have the following structural formulas: Na_0.05 K_0.86 (Al _1.77 Fe_0.08 Mg_0.15) (Si_3.22 Al_0.78) O₁₀ (OH)_2. They are enriched in Fe and Mg compared to the detrital micas. Newly-formed chlorites are associated with micas along the shear planes. According to microprobe analyses, they present the following structural formula: (Al_1,48 Fe_2,50 Mg_1,84) (Si_2,82 Al_1,18) O₁₀ (OH)₈. All these data suggest that these clay minerals are synkinematic and registered the fault activity. In the gouge samples, illite and chlorite are the major clay minerals; smectite is locally present in some samples.In the foliated sandstones, Kubler Index (KI) ((001) XRD peak width at half height) data and thermodynamic calculations from synkinematic chlorite chemistry suggest that the main fault deformation occurred under temperatures around 220 °C (diagenesis to anchizone boundary). KI measured on pelites and sandstones from the hanging and footwall, display similar values coherent with the maximal burial temperature of the Annot sandstones in this area. The gouge samples have a higher KI index, which could be explained by a reactivation of the fault at lower temperatures during the exhumation of the Annot sandstones formation.     

欧亚黄土沉积环境对比研究

本文对采自中国、法国、比利时等国43块黄土样品进行实验室处理后,分析对比了它们在碳酸盐含量、粒度组成、重矿物组成及粘土矿物成分方面的共同特性及差异性。结果表明,中国黄土碳酸盐含量稳定,西欧不同类型的黄土碳酸盐含量差别很大。在粒度组成上,欧亚黄土并没有本质的差别,但西欧不同层位的黄土粒度组成呈有规律变化。对西欧重矿物的分析可以追溯黄土的物质来源,粘土矿物含量在欧亚不同黄土中也有差别。比较结果说明,欧洲的黄土堆积受第四纪冰期、间冰期的气候波动影响较大,中国黄土在堆积期间始终处在干旱、半干旱的气候条件下。     

Changes in grain-size and sedimentation rate of the Neogene Red Clay deposits along the Chinese Loess Plateau and implications for the palaeowind system

In recent years, the Red Clay deposits underlying Quaternary loess on the Chinese Loess Plateau (north China) have attracted more attention because they show a direct and continuous record of past atmos- pheric circulation and palaeoclimatic change. Investiga- tions on Red Clay deposits through multidisciplinary methods have demonstrated an aeolian origin for the Red Clay, like the overlying Quaternary loess. The Red Clay formed during the Miocene and Pliocene[1―13]. However, the type o…