藻体海水培养液中铜的化学存在形式

采用金属络合物通式模型,在IBM-PC计算机上计算了不同pH(7.5～9.5)、碱度(2.3～2.5mmol dm~(-3))和加入不同浓度的铜离子(1.0×10~(-4)～1.0mg dm~(-3))条件下,海水培养液中铜的主要化学存在形式分配的百分数。还给出了计算机程序框图和主要化学存在形式含量的百分数随pH、碱度和铜浓度变化图。     

张宣地区大白阳金矿床包裹体特征及矿床剥蚀保存

华北克拉通破坏及其成矿事件已引起地学界的广泛关注,其中张宣地区是华北克拉通的重要金矿集中区之一,通过对张宣地区大白阳金矿成矿类型、成矿深度及剥蚀保存的探讨,为区内深部找矿提供了重要的参考依据。文章通过流体包裹体研究对大白阳金矿成矿温度及成矿深度进行计算,利用矿物压力计对矿区周边岩体侵位深度进行估算。流体包裹体研究结果显示大白阳金矿成矿温度160~220℃、盐度w（NaCl_eq）=9%~15%,密度0.78~0.97 g/cm³、压力46.3~104.6 MPa,成矿流体主要属于NaCl-H₂O体系,成矿过程中流体温度和盐度都呈现明显的降低趋势。采用黑云母压力计,针对大白阳金矿周边谷嘴子、杨家营以及前坝口花岗质岩体的侵位深度进行估算,并对大白阳金矿自形成以来的剥蚀保存情况进行了探讨,估算结果显示,谷嘴子岩体（236.0 Ma）成岩深度7.02 km、杨家营岩体（138.6 Ma）成岩深度2.66 km、前坝口岩体（140.2 Ma）成岩深度3.13 km。结合前人的裂变径迹结果,认为张宣地区自中生代以来剥蚀速率为0.022~0.029 km/Ma,剥蚀量为3 km。按照前述成矿压力46.3~104.6 MPa换算,大白阳金矿成矿深度6.93 km,剥蚀量小于矿床成矿深度,说明该矿深部仍具有良好的找矿前景。     

利用古温标恢复四川盆地主要构造运动时期的剥蚀量

地层剥蚀量是沉积盆地埋藏史和热史重建中一个关键的参数.本文利用石油钻井的系统古温标(Ro)资料,并结合多种恢复方法,得出四川盆地主要构造运动时期的剥蚀量.研究表明:加里东期,川东南剥蚀量较大,达2000m.东吴运动时期,川西南、川东南等距二叠纪玄武岩喷发区较近地区的剥蚀量较大,分别在260～450 m和800～900m:印支早期盆地整体遭受了抬升剥蚀作用,剥蚀厚度为100～500 m.印支中、晚期龙门山地区褶皱剥蚀,H1、Y1等钻井该时期的地层剥蚀量超过2000 m.燕山期周缘山系的继续隆升造成山前大范围地区的剥蚀:喜山期盆地周缘钻井的剥蚀量较大,在2000 m左右,而早期古隆起上的钻井如GJ、J13、Z12等钻井的地层剥蚀量则较小,在1000 m左右.可见,四川盆地不同地质时期及不同构造区位的剥蚀厚度都不尽相同,这一时空差异反映了构造运动对该区的差异影响.这一研究也表明,以系统的古温标资料(R_o)为基础,针对不同地质情况选用适当的反演方法并结合多种反演方法.能有效地恢复钻井在不同时期的剥蚀量.上述四川盆地各时期剥蚀地层厚度的恢复,对研究该区的构造、沉积和油气演化提供了基础数据.     

The role of iron and sulfur in the visual appearance of lake sediment varves

Easily discernible sediment varves (annual laminations) may be formed in temperate zone lakes, and reflect seasonal changes in the composition of the accumulating material derived from the lake and its catchment (minerogenic and organic material). The appearance of varves may also be influenced by chemical processes. We assessed the role of iron (Fe) and sulfur (S) in the appearance of varves in sediments from Lake Nylandssjön in northern Sweden. We surveyed Fe in the lake water and established whether there is internal transport of Fe within the sediment. We used a unique collection of seven stored freeze cores of varved sediment from the lake, collected from 1979 to 2004. This suite of cores made it possible to follow long-term changes in Fe and S in the sediment caused by processes that occur in the lake bottom when the sediment is ageing. We compared Fe and S concentrations using X-ray fluorescence spectroscopy (XRF) in specific years in the different cores. No diagenetic front was found in the sediment and the data do not suggest that there is substantial vertical transport of Fe and S in the sediment. We also modeled Fe and S based on thermodynamic, limnological, and sediment data from the lake. The model was limited to the five components H⁺, e^?, Fe³⁺, SO₄ ^2?, H₂CO₃ and included the formation of solid phases such as Fe(OH)₃ (amorphous), FeOOH (aged, microcrystalline), FeS and FeCO₃. Modeling showed that there are pe (redox) ranges within which either FeS or Fe(OH)₃/FeOOH is the only solid phase present and there are pe ranges within which the two solid phases co-exist, which supports the hypothesis that blackish and grey-brownish layers that occur in the varves were formed at the time of deposition. This creates new possibilities for deciphering high-temporal-resolution environmental information from varves.     

The world''s large lake basins as denudation-accumulation systems and implications for their lifetimes

The mechanical denudation rates of 81 large lake basins (lake area > 500 km²) were determined from long-term river loads and erosion maps. Using the drainage area/lake area ratios the mean sedimentation rates of the lakes were calculated for a porosity of 0.3. The mean sedimentation rates of different lake types vary between 0.1 mm/a (glacial lakes, lowland) and 5.4 mm/a (mostly sag basin lakes). The calculated lifetimes of the lakes are based on the lake volumes and mean sedimentation rates, assuming steady-state conditions and solely clastic material. On average, glacial lakes in highlands and fault-related lakes show the shortest lifetimes (c. 70 ka), glacial lakes in lowlands and rift lakes have the longest lifetimes (c. 1 Ma). Some lakes remain unfilled for very long time spans due to rapid subsidence of their basin floors. The calculated lifetimes are compared with those derived from sediment core studies. Most core studies indicate lower mechanical sedimentation rates than the calculated ones because a major part of the incoming sediment is trapped in deltas. However, a number of lakes (e.g., the Great Lakes of North America) show the opposite tendency which is largely caused by extensive shoreline erosion and resuspension. The lifetimes of large glacial lakes often exceed the duration of interglacials. Hence, their lifetimes are restricted by glaciation and not by sediment infill. Rift lakes persist for long time periods which exceed the calculated lifetimes in some cases. Time-dependent subsidence, basin extension, as well as the impact of climate change are briefly described.     

THERIA_G: a software program to numerically model prograde garnet growth

We present the software program THERIA_G, which allows for numerical simulation of garnet growth in a given volume of rock along any pressure–temperature–time (P–T–t) path. THERIA_G assumes thermodynamic equilibrium between the garnet rim and the rock matrix during growth and accounts for component fractionation associated with garnet formation as well as for intracrystalline diffusion within garnet. In addition, THERIA_G keeps track of changes in the equilibrium phase relations, which occur during garnet growth along the specified P–T–t trajectory. This is accomplished by the combination of two major modules: a Gibbs free energy minimization routine is used to calculate equilibrium phase relations including the volume and composition of successive garnet growth increments as P and T and the effective bulk rock composition change. With the second module intragranular multi-component diffusion is modelled for spherical garnet geometry. THERIA_G allows to simulate the formation of an entire garnet population, the nucleation and growth history of which is specified via the garnet crystal size frequency distribution. Garnet growth simulations with THERIA_G produce compositional profiles for the garnet porphyroblasts of each size class of a population and full information on equilibrium phase assemblages for any point along the specified P–T–t trajectory. The results of garnet growth simulation can be used to infer the P–T–t path of metamorphism from the chemical zoning of garnet porphyroblasts. With a hypothetical example of garnet growth in a pelitic rock we demonstrate that it is essential for the interpretation of the chemical zoning of garnet to account for the combined effects of the thermodynamic conditions of garnet growth, the nucleation history and intracrystalline diffusion. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.

鄂西黄陵穹隆新生代隆升特征及其环境效应

位于湖北省西缘的黄陵穹隆具有基底加盖层双层结构,其暴露的基底主要以黄陵花岗岩为代表。该穹隆对长江三峡的形成演化、四川－江汉盆地一带构造格局的形成,以及三峡大坝的安全性等方面均具有重要控制和影响作用。本文通过对黄陵花岗岩的裂变径迹特征分析,结合野外实测阶地地貌数据,获得了黄陵穹隆65Ma以来的隆升速率、隆升高度和剥蚀速率等方面的数据：1)65-7Ma,隆升速率为24.6-7.4m/Ma,隆升高度为1426.8-429.2m;2)7Ma至今,平均隆升速率为204.1m/Ma,隆升高度为1428.7m。而0.73-0.01Ma以来隆升速率由0.058m/Ka增加为1.033m/Ka,平均隆升速率为0.134m/Ka,显示出早期隆升较慢,后期加快的趋势。65Ma以来,至少总的剥蚀厚度为2455.5m-1457.9m,其中7Ma以来剥蚀的厚度为1028.7m,剥蚀速率为0.147mm/a。研究结果约束了长江三峡的形成时间和过程,证实了三峡是一年轻的河谷。     

关于“内蒙地轴解体”

近年来引起我国地质界广泛注意的内蒙地轴解体论所建立的基础是清河镇群蛇绿岩和清河镇小壳动物群。解体论者认为这些广泛分布在中朝陆台北缘近２００００ｋｍ的东西延伸带上的不同岩层都是和温都尔庙群相似的蛇绿岩，并且其中都产有早寒武世小壳动物化石。最新研究已证实清河镇动物群不是生物化石，而是用酸处理岩石样品过程中的化学沉淀物和少量现代植物碎屑混入物的组合。大量地质资料也证明这个带上主要分布早前寒武纪变质杂岩和稍晚的裂谷堆积，所谓的清河镇群蛇绿岩是错误的地质观察和岩石鉴定造成的。     

水-岩化学作用对岩体变形破坏力学效应研究进展

水—岩化学作用对岩体变形破坏力学效应的研究涉及力学和化学两方面,也即为地球化学与岩体力学两个研究领域的交叉。针对水化学作用对岩体力学性质的影响机理,较系统地总结了该研究领域中的现状和研究新进展,分析了其研究方法,指出了今后的研究方向和主要研究内容,并认为此方面的研究将在工程地质学中占重要地位。     

第四纪洞庭盆地安乡凹陷及西缘构造-沉积特征与环境演化

通过地表观察和钻孔资料,对洞庭盆地安乡凹陷及其西缘第四纪构造沉积特征和环境演化进行了研究,为江汉—洞庭盆地第四纪地质研究补充了新的资料。凹陷总体呈南北向,周边为正断裂。凹陷内第四系厚一般为100-220 m,最厚达300 m,自下而上依次为早更新世华田组、汨罗组,中更新世洞庭湖组,晚更新世坡头组和全新世湖冲积。第四系以砾石层、砂层为主,次为（含）粉砂质黏土、黏土,岩性、岩相横向变化大。安乡凹陷西缘（即太阳山隆起东缘）,呈自西向东缓倾的丘岗地貌。区内主要发育中更新世白沙井组,其中南部下部以砂、砾石层为主,上部为黏土;北部以粉砂质黏土沉积为主,下部可发育砂层。根据地貌、沉积及控凹断裂特征,重塑安乡凹陷及其西缘第四纪构造活动与环境演化过程：早更新世—中更新世早期,凹陷西边的北北东向周家店断裂伸展活动,安乡凹陷不均匀沉降,总体具河流和过流性湖泊环境并接受沅水沉积;同期凹陷西缘构造抬升,处于剥蚀的山地环境。中更新世中期断陷活动向西扩展,凹陷区为过流性湖泊环境;凹陷西缘地区转为河流（南部）和湖泊（北部）环境并接受沉积。中更新世晚期安乡凹陷及其西缘整体抬升并遭受剥蚀,凹陷西缘同时具有自西向东的掀斜。晚更新世安乡凹陷拗陷沉降,具河流和湖泊环境;同期凹陷西缘遭受剥蚀。晚更新世末受区域海平面下降影响,安乡凹陷遭受剥蚀。全新世安乡凹陷拗陷沉降,具泛滥平原之河流、湖泊环境。