榴辉岩的化学分类

以山东荣成地区的榴辉岩为例,把榴辉岩分为镁一榴辉岩、铁一榴辉岩和钙一榴辉岩三类。三类榴辉岩的岩石化学,主要造岩矿物成分都有明显差别,石榴石分别是镁铝榴石、铁铝榴石和钙铝榴石。绿辉石的硬玉分子也有不同。三类榴辉岩的化学成分限制是Mg-榴辉岩MgO>10%,石榴石以镁铝榴分子占优势,Fe-榴辉岩的MgO<10,石榴石以铁铝榴石分子占优势。Ca-榴辉岩CaO>19%,石榴石以钙铝榴石分子优势。     

黑龙江省砂金指纹（化学成分）特征

对黑龙江省８４个砂金，７个岩金样品的化学成分进行了研究。通过Ｒ型聚类分析、探讨了不同元素之间相关性及其地质意义。通过Ｑ型聚类分析将所有样品进行分类，探讨了砂金样品与已知岩金样品之间的成因联系，并对砂金的可能原生金源的剥蚀程度进行了估计。     

Tortoises and hares: dissolution,erosion and isostasy in landscape evolution

Denudation mechanisms differ fundamentally between limestone and silicate rock types, which are subject to very different rate thresholds and enhancers/inhibitors. Silicates are removed largely by erosion, the mechanical entrainment and transport of particles. This is a relatively high energy, and highly episodic, process which occurs only when a minimum threshold ?ow velocity is exceeded; it is inhibited by vegetation cover and favoured by strongly seasonal runoff. Limestone is removed largely by chemical dissolution at a rate directly proportional to runoff. Dissolution is a relatively low energy process that can occur at any ?ow velocity or in static water; in general it is enhanced by vegetation cover and non‐seasonality of runoff. These contrasting factors in the denudation of silicates versus limestone can produce strikingly uneven rates of surface lowering across a landscape, sometimes akin to the well known ‘tortoise and hare race’, where the slow and steady denudation of limestones may in the long term exceed the sometimes rapid, but often localized and episodic, erosion of silicates. Prolonged exposure of limestone to a humid temperate climate in a tectonically stable environment produces low‐relief corrosion plains in which limestone uplands are anomalous and, in most instances, due to recent unroo?ng from beneath a siliciclastic cover. In a highly seasonal or semi‐arid climate almost the exact inverse may develop, with ‘?ashy’ runoff and sparse vegetation favouring erosion rather than dissolution. Even under a constant humid climate progressive unroo?ng of a thick limestone unit within folded siliciclastics may lead to a topographic inversion over time, with the limestone outcrop always forming a topographic low ?anked by siliciclastic uplands. Valleys will be initiated on anticlinal crests, where the limestone is ?rst unroofed, but progressive lowering of the limestone causes these valleys to migrate to their ?nal position in the synclinal troughs. In humid climates isostatic compensation in response to slow, but continuous, denudation of extensive limestone outcrops may be a signi?cant factor in the development of relief on adjacent, more slowly eroding, silicate outcrops. Copyright © 2004 John Wiley & Sons, Ltd.     

Whole-rock chemistry of the Gameleira I uranium deposit,Lagoa Real,Brazil

The Lagoa Real uranium (U) province, referred to as Lagoa Real, is located in the state of Bahia, north-eastern Brazil. Lagoa Real has ∼112,000 metric tonnes and average grade of 2700 ppm of U₃O₈, being one of the largest U deposits in the world and the largest in Brazil. Despite its economic and strategic importance, there are gaps in the geological knowledge of the Lagoa Real U deposits. One of them is the lack of extensive whole-rock chemical data sets. Here, we present whole-rock chemical analyses for major and trace elements, including the rare-earth elements (REE), from barren country rocks to uraniferous ore shoot, systematically sampled from an exploratory drill hole. The chemical data indicate that albitite rocks, with and without uraniferous mineralisation, cannot result from sodic syenitic magmatism, as proposed by recent studies. Petrographical and geochemical evidence supports the previously suggested concept that the Lagoa Real albitite rocks resulted from sodic metasomatism of the granitic country rock, known as the São Timóteo granite. Their ore-mineral assemblages and geochemical characteristics are similar to albitite-hosted U deposits worldwide.     

ESTIMATING RATES OF DENUDATION USING COSMOGENIC ISOTOPE ABUNDANCES IN SEDIMENT

We propose, as a testable hypothesis, a basin-scale approach for interpreting the abundance of in situ produced cosmogenic isotopes, an approach which considers explicitly both the isotope and sediment flux through a drainage basin. Unlike most existing models, which are appropriate for evaluating in situproduced cosmogenic isotope abundance at discrete points on Earth's surface, our model is designed for interpreting isotope abundance in sediment. Because sediment is a mixture of materials, in favourable cases derived from throughout a drainage basin, we suggest that measured isotope abundances may reflect spatially averaged rates of erosion. We investigate the assumptions and behaviour of our model and conclude that it could provide geomorphologists with a relatively simple means by which to constrain the rate of landscape evolution if a basin is in isotopic steady state and if sampled sediments are well mixed.     

印支运动对济阳坳陷构造形态形成演化的影响

三叠纪中期至侏罗纪早期的印支运动动力来源于华北板块与扬子板块的聚敛,聚敛作用形成巨大的NE-SW向挤压力首先导致济阳坳陷北西向压性构造的形成,产生了一系列NW向褶皱隆起带及其伴生的宽缓向斜,其次在对济阳盆地产生多处NW向挤压逆冲构造,伴之以褶皱构造。印支运动还造成本区地势起伏不平,剥蚀程度差异还导致相对隆起区与相对低洼区相间排列,上古生界保留较完整。     

Formation and stability of mixed Mg/Ca/phytate species in synthetic seawater media: Consequences on ligand speciation

The results of a potentiometric investigation (by ISE-H⁺, glass electrode) on the speciation of phytate ion (Phy¹²⁻) in an ionic medium simulating the major components (Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻ and SO₄²⁻) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca²⁺–Mg²⁺–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH₃Phy⁵⁻, MgCaH₄Phy⁴⁻, Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X₁₁₃ = 2.67 and log X₁₁₄ = 1.37 for MgCaH₃Phy⁵⁻ and MgCaH₄Phy⁴⁻ (statistical value is log X_stat = 0.60), and log X₂₁₃ = 6.11 and log X₂₁₄ = 2.15 for Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ (log X_stat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand).     

Kinetic and equilibrium studies of copper-dissolved organic matter complexation in water column of the stratified Krka River estuary (Croatia)

An interaction of dissolved natural organic matter (DNOM) with copper ions in the water column of the stratified Krka River estuary (Croatia) was studied. The experimental methodology was based on the differential pulse anodic stripping voltammetric (DPASV) determination of labile copper species by titrating the sample using increments of copper additions uniformly distributed on the logarithmic scale. A classical at-equilibrium approach (determination of copper complexing capacity, CuCC) and a kinetic approach (tracing of equilibrium reconstitution) of copper complexation were considered and compared. A model of discrete distribution of organic ligands forming inert copper complexes was applied. For both approaches, a home-written fitting program was used for the determination of apparent stability constants (K_i^equ), total ligands concentration (L_iT) and association/dissociation rate constants (k_i¹,k_i^- 1).A non-conservative behaviour of dissolved organic matter (DOC) and total copper concentration in a water column was registered. An enhanced biological activity at the freshwater–seawater interface (FSI) triggered an increase of total copper concentration and total ligand concentration in this water layer. The copper complexation in fresh water of Krka River was characterised by one type of binding ligands, while in most of the estuarine and marine samples two classes of ligands were identified. The distribution of apparent stability constants (log K₁^equ: 11.2–13.0, log K₂^equ:8.8–10.0) showed increasing trend towards higher salinities, indicating stronger copper complexation by autochthonous seawater organic matter.Copper complexation parameters (ligand concentrations and apparent stability constants) obtained by at-equilibrium model are in very good accordance with those of kinetic model. Calculated association rate constants (k₁¹:6.1–20 × 10³ (M s)^− 1, k₂¹: 1.3–6.3 × 10³ (M s)^− 1) indicate that copper complexation by DNOM takes place relatively slowly. The time needed to achieve a new pseudo-equilibrium induced by an increase of copper concentration (which is common for Krka River estuary during summer period due to the nautical traffic), is estimated to be from 2 to 4 h.It is found that in such oligotrophic environment (dissolved organic carbon content under 83 µM_C, i.e. 1 mg_CL^− 1) an increase of the total copper concentration above 12 nM could enhance a free copper concentration exceeding the level considered as potentially toxic for microorganisms (10 pM).     

珠江口及附近海域夏季氮的化学形式分布研究

根据1998年夏季对珠江河口及附近海域的水质调查，研究了氮的各种化学形式的空间分布特征、相关系数和环境条件的影响。结果表明：珠江河口中，无机氮含量很高，占总氮的85％；而硝酸氮占无机氮的95％，NO2^--N和NH4^ -N含量很低。在外海，则以有机氮为主，占总氮的80％。NH4^ -N和NO2^--N在伶仃洋河口中部出现最大值，在外海的值最小；其它形式的氮从伶仃洋内河口到外海，其浓度都逐渐降低。NO3^--N是各种形式氮中的主要因素，它与各形式氮之间具有良好的相关性；NH4^ -N和NO2^--N与其它形式氮之间的相关性都很差，而其余各种形式氮之间都有较好的相关性。涨潮时不利于污染物的扩散；与小潮相比，大潮时伶仃洋河口中部表层氮的浓度偏高。