连云港地区水泥土搅拌桩适用性问题探讨

水泥土搅拌桩地基处理在连云港地区应用广泛。通过工程实例,对于法及湿法的加固效果,从桩身强度及单桩抗压承载力两方面进行分析比较,探讨其适用性,认为,在连云港地区,干法较湿法的加固效果有显著改善,可为类似工程提供参考。     

枣庄桃花山水泥用灰岩矿地质特征及矿床成因

桃花山水泥用灰岩矿矿床位于枣庄市峄城城区,赋存于寒武纪九龙群张夏组地层中,呈层状产出,共分2个矿层,含5个夹石层。矿区分东、西2个矿段,西矿段矿石质量较好,无夹层;东矿段局部存在高镁、高碱夹石层。矿床平均有益、有害组分为Ca O 52.75%,Mg O 1.70%,R2O 0.269%,矿床属海相沉积矿床。     

Special speleothems in cement-grouting tunnels and their implications of the atmospheric CO2 sink

 Based on the analyses and comparisons of water chemistry, stable carbon isotopes and deposition rates of speleothems, the authors found that there are two kinds of speleothems in the tunnels at the Wujiangdu Dam site, Guizhou, China, namely the CO₂-outgassing type and the CO₂-absorbing type. The former is natural, as observed in general karst caves, and the product of karst processes under natural conditions. The latter, however, is special, resulting from the carbonation of a cement-grouting curtain and concrete. Due to the quick absorption of CO₂ from the surrounding atmosphere, evidenced by the low CO₂ content in the air and the high deposition rate of speleothems (as high as 10 cm/a) in the tunnels, the contribution of the carbonation process to the sink of CO₂ in the atmosphere is important (in the order of magnitude of 10⁸ tons c/a) and should be taken into consideration in the study of the global carbon cycle because of the use of cement on a worldwide scale. Received: 21 July 1997 · Accepted: 13 January 1997     

Alteration processes of cement induced by CO2-saturated water and its effect on physical properties: Experimental and geochemical modeling study

The objective of this study is to understand cement alteration processes with the evolution of porosity and hardness under geologic CO₂ storage conditions. For this study, the cylindrical cement cores (class G) were reacted with CO₂–saturated water in a vessel (40 °C and 8 MPa) for 10 and 100 days. After the experiment, the CO₂ concentration and Vickers hardness were measured in the hydrated cement core to estimate the carbonation depth and to identify the change in hardness, respectively. Diffusive-reactive transport modeling was also performed to trace the alteration processes and subsequent porosity changes. The results show that cement alteration mainly results from carbonation. With alteration processes, four different reaction zones are developed: degradation zone, carbonation zone, portlandite depletion zone, and unreacted zone. In the degradation zone, the re-dissolution of calcite formed in the carbonation zone leads to the increase of porosity. In contrast, the carbonation zone is characterized by calcite formation resulting mainly from the dissolution of portlandite. The carbonation zone acts as a barrier to CO₂ intrusion by consuming dissolved CO₂. Especially in this zone, although the porosity decreases, the Vickers hardness increases. Our results show that cement alteration processes can affect the physical and hydrological properties of the hydrated cement under CO₂-saturated conditions. Further long-term observation is required to confirm our results under in-situ fluid chemistry of a CO₂ storage reservoir. Nonetheless, this study would be helpful to understand alteration processes of wellbore cements under CO₂ storage conditions.     

Fluid flow in cataclastic thrust fault zones in sandstones, Sub-Andean Zone, southern Bolivia

The Bolivian Sub-Andean Zone (SAZ) corresponds to a Neogene thrust system that affects an about 10-km thick Palaeozoic to Neogene siliciclastic succession. The analysis of macro and microstructures and cement distribution in thrust fault zones shows that they are sealed by quartz at depths >3 km, due to local silica transfer by pressure-solution/precipitation activated at temperatures >70–90 °C. At shallower depths, faults have remained open and could be preferential drains for lateral flow of carbonate-bearing fluids, as shown by the occurrence of carbonate cements in fractures and their host-sandstone. Due to decreasing burial, resulting from foothill erosion during fault activity, critically buried fault segments can be affected by non-quartz-sealed structures that post-date initial quartz-sealed structures. The integration of textural, fluid inclusion and isotopic data shows that carbonates precipitated at shallow depth (<3 km), low temperature (<80 °C) and relatively late during the thrusting history. Isotopic data also show that precipitation occurred from the mixing of gravity-driven meteoric water with deeper formation water bearing carbonate carbon derived from the maturation of hydrocarbon source rocks (Silurian and Devonian shales). The combined microstructural and isotopic analyses indicate that: (i) fluid flow in fault zones often occurred with successive pulses derived from different or evolving sources and probably related to episodic fault activity, and (ii) at a large-scale, the faults have a low transverse permeability and they separate thrust sheets with different fluid histories.     

On the compression behavior of remolded cement-admixed soft clay

Although extensive research has been performed on the mechanical properties of cement-stabilized clays, quite a few attempts have been made on the compression behavior of remolded cement-admixed clays. The results from oedometer tests have been discussed to investigate the compressibility of remolded cement-admixed clays, taking into consideration cement amount and curing time. The findings show that the difference in shape and position of compression curves is attributed to cement amount and curing time. Most compression index (C_c) values of remolded cement-admixed clays are greater than those of untreated clay due to the presence of remolded yield stress σ′_yr that is closely related to initial water content and clay fabric. Based on the obtained test data, the relationships of C_c vs. e₀, C_c vs. w₀, C_c vs. e₁, C_c vs. e_yr, and σ′_yr vs. e_yr are preliminarily discussed and quantitatively established. Especially, an important divergence of void index I_v at effective stress σ′_v less than remolded yield stress σ′_yr can be observed at different cement amounts and curing durations. Being independent on cement amount, curing time, and initial state of soil, an excellent convergence occurs at stress σ′_v greater than yield stress σ′_yr. The normalized compression curves of I_v vs. σ′_v at σ′_v?>?σ′_y can be expressed by a unique line that agrees well with intrinsic compression line (ICL) and extended ICL.     

Consolidation behavior of a soft mud treated with small cement content

Soft mud can be found in many large size reclaimed lands. Such soils present extremely high settlement potential that needs to be alleviated by means of effective ground improvement techniques. Current knowledge on applying small cement content to reduce settlement potential of soft mud is limited. This study concerns the consolidation behavior and settlement potential of soft mud treated with small cement content. Based on the pH values of soft mud–cement mixtures, oedometer specimens with cement content of 6% were prepared for consolidation tests. The test results show that preconsolidation pressure is rapidly developed and secondary compression is reduced. The ratio of secondary compression index to compression index is also reduced, indicating a change in grain size characteristics. The coefficient of consolidation is increased for consolidation pressures smaller than the preconsolidation pressure. This indicates that treating the soft mud with a small cement content can be very effective for reducing settlements in cases where new loads are small to medium and the time for ground improvement is limited.     

水泥熟料生产企业CO2直接排放核算模型的建立

为快速掌握区域内全部水泥企业的碳排放情况,在部分企业实际生产数据未知时,也能建立其生产碳排放清单,文中基于熟料生产特征,构建了可根据设备设计产能和运行时长两种参数来核算企业CO2排放的数值模型.以京津冀地区59条典型水泥熟料生产线的生产数据作为统计样本,借助Eviews对生产线的实际产能、熟料烧成煤耗与设计产能间的关系...     

生石灰和水泥混合处理吹填土的试验研究

随着中国东南沿海地区经济的迅速发展,土地资源不足的问题显得日益突出,人工吹填造地技术为解决这一问题提供了新的思路。吹填造地关键问题之一是要缩短吹填泥浆的固结的时间,为此在室内进行了沉降柱模拟试验,试图寻找一种在吹填的同时进行加固的方法。在沉降柱试验中发现,用水泥作为添加剂对吹填泥浆进行加固处理,其加固效果不如用水泥和石灰混合材料添加剂的加固效果。通过对两种添加方式的土样进行工程地质性质对比和结构性分析及其他一些物理化学试验结果分析,初步找出了加固效果差异的原因。     

Sorption and diffusion studies with low molecular weight organic compounds in cementitious systems

The uptake of methanol, ethanol, formaldehyde, acetaldehyde, formic acid and acetic acid by cement paste was determined in hydrating cement after 1 h, 28 d and 390 d hydration. The sorption values determined for formate and acetate were critically assessed by investigating through- and out-diffusion of these compounds in fully hydrated cement paste and their uptake by individual cement phases. Diffusion studies included inverse modelling of four data sets for each compound and an uncertainty analysis based on a Latin hypercube sampling procedure. Solid–liquid distribution ratios determined from the hydration experiments are on the order of 10⁻⁴ m³ kg⁻¹ in the case of alcohols and aldehydes indicating non-specific (very weak) bonding onto the surface of the cement phases, e.g. through hydrogen bonding. Hydration and diffusion studies reveal slightly higher distribution ratios and reversible uptake by cement paste and cement phases in the case of acetate indicating specific adsorption (electrostatic interaction) onto partially positively charged surface sites of the cement phases. Selective binding of a small fraction of formate is evidenced from both sorption and out-diffusion experiments suggesting the presence of sorption sites capable of strongly bonding the anion, presumably by SO₄²⁻/HCOO⁻ replacement in the ettringite structure.