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271.
利用静态箱-气相色谱法对泥河水库春季水-气界面二氧化碳通量值进行连续24h观测,对其变化趋势及影响因素加以分析。结果表明:泥河水库24h均为大气CO2的源,其碳通量均值为26.50mg/(m2·h),全天源的极大值出现在1∶00为32.38mg/(m2·h),源的极小值出现在13∶00为20.15mg/(m2·h)。在春季影响泥河水库水-气界面CO2通量变化的主要因素是气温、叶绿素和风速,相关系数分别为0.671、0.625、0.253。结论:水库水-气界面CO2通量的变化是多种因素共同作用的结果,春季水库是大气CO2主要碳源之一。 相似文献
272.
闽江河口咸草湿地冬季甲烷和二氧化碳通量及影响因子分析 总被引:2,自引:0,他引:2
闽江河口是我国东南沿海典型的开放式感潮河口,咸草Cyperus malaccensis var.brevifolius为闽江河口区最大的鳝鱼滩沼泽湿地的主要土著种。采用静态暗箱-气相色谱法,测定了2008年冬季(11月、12月和次年1月)咸草湿地涨潮前、涨落潮过程中和落潮后3个阶段排向大气环境的甲烷(CH4)和二氧化碳(CO2)通量特征。结果表明,涨落潮过程中咸草湿地排向大气环境的甲烷通量小于涨潮前和落潮后,在时间上表现为冬季3个月甲烷排放通量持续下降;咸草湿地二氧化碳通量同样表现为涨落潮过程中小于涨潮前和落潮后,在时间上也呈递减趋势;氧化还原电位(Eh)以及pH值对咸草湿地甲烷和二氧化碳排放通量具有不同程度的影响。 相似文献
273.
湖泊自生碳酸盐碳同位素组成(δ13Cc)在区域气候与环境变化方面的应用研究近年来进展迅速,成果显著,保存在各类湖泊沉积物柱芯中的δ13Cc记录揭示了湖表水体与大气CO2的交换程度、暖季降水量的多少、流域C3和C4植被变化情况、水生生物光合作用或呼吸作用强弱、湖泊生产力大小、湖泊水体化学特征、湖水不同深度层的有机质变化过程等重要的气候和环境信息;对此进行归纳和述评。 相似文献
274.
The production and use of nanomaterials will inevitably lead to their disposal in the natural environment. To assess the risk that these materials pose to human and ecosystem health an understanding of their mobility and ultimate fate is essential. To date, however, relatively little research has been conducted on the fate of nanoparticles in subsurface systems. In this study the subsurface mobility of two carbon nanoparticles: nano-fullerenes (nC60) and multi-walled carbon nanotubes (MWCNTs) is assessed. A two-dimensional finite element model was used to simulate the movement of these nanoparticles under a range of hydrologic and geological conditions, including a heterogeneous permeability field. The numerical model is based on colloid filtration theory (CFT) with a maximum retention capacity term. For the conditions evaluated the carbon nanotubes are much more mobile than nC60 due to the smaller collector efficiency associated with carbon nanotubes. However, the mobility of nC60 increased significantly when a maximum retention capacity term was included in the model. Model results also demonstrate that, for the systems examined, nanoparticles were predicted to be less mobile in heterogeneous systems compared to the homogeneous systems with the same average hydraulic properties. 相似文献
275.
Understanding of the Common Land Model performance for water and energy fluxes in a farmland during the growing season in Korea 总被引:1,自引:0,他引:1
The Common Land Model (CLM) is one of the most widely used land surface models (LSMs) due to the practicality of its simple parameterization scheme and its versatility in embracing a variety of field datasets. The improved assessment of land surface water and energy fluxes using CLM can be an alternative approach for understanding the complex land–atmosphere interactions in data‐limited regions. The understanding of water and energy cycles in a farmland is crucial because it is a dominant land feature in Korea and Asia. However, the applications of CLM to farmland in Korea are in paucity. The simulations of water and energy fluxes by CLM were conducted against those from the tower‐based measurements during the growing season of 2006 at the Haenam site (a farmland site) in Korea without optimization. According to the International Geosphere–Biosphere Programme (IGBP) land cover classification, a homogeneous cropland was selected initially for this study. Although the simulated soil moisture had a similar pattern to that of the observed, the former was relatively drier (at 0·1 m3 m?3) than the latter. The simulated net radiation showed good agreement with the observed, with a root mean squared error (RMSE) of 41 W m?2, whereas relatively large discrepancies between the simulation and observation were found in sensible (RMSE of 66 W m?2) and latent (RMSE of 60 W m?2) heat fluxes. On the basis of the sensitivity analysis, soil moisture was more receptive to land cover and soil texture parameterizations when compared to soil temperature and turbulent fluxes. Despite the uncertainty in the predictive capability of CLM employed without optimization, the initial performance of CLM suggests usefulness in a data‐limited heterogeneous farmland in Korea. Further studies are required to identify the controls on water and energy fluxes with an improved parameterization. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
276.
大气CO2体积分数升高导致的海洋酸化不仅会降低海水pH,还会改变其碳酸盐平衡体系,使得海水中文石饱和度(Ω)降低,相应地会降低珊瑚钙化的速率。已有研究表明:珊瑚骨骼δ13C、δ11B和δ15N具有记录Suess Effect、生物生产力、海水pH值以及营养源的能力;主要表现为:δ11B记录的pH值、δ13C记录的海水无机碳库(DIC)δ13C和生物生产力,以及δ15N记录的陆源物质输送量相结合,可用来指示受季风影响的南海“大陆架碳泵”和近海污染与海洋酸化的联系。目前关于珊瑚对海洋酸化的记录研究仍相对较少,珊瑚碳-氮-硼同位素组合的应用将会加深对于海洋酸化与气候变率和全球碳、氮循环的关系的认识,可能成为揭示海水pH值变化规律性的重要手段。 相似文献
277.
Parallel factor analysis of fluorescence excitation emission matrices of surface water samples of a globally large river (Yangtze River, China) watershed identified three classes of fluorescent dissolved organic matter (FDOM) that had ex/em = 280/330 nm, 305/385 nm and 350/450 nm respectively, resembling “peak T”, “peak M” and “peak C” commonly identified in natural water, respectively. Peak T (a tyrosine/tryptophan-like FDOM) did not show correlations to peak M or C which were humic-like substances, while a positive correlation (r = 0.935, p < 0.001) was present between the natural log-transformed maximum fluorescence intensity (Fmax) of peaks T and M indicating a tight link during their production and processing. Fmax values (in Raman unit nm?1) normalized to dissolved organic carbon (DOC) concentration were low, varying in ranges 15.93–85.95, 29.83–83.54 and 19.73–51.05 × 10?5 nm?1 (μmol/L)?1 for peaks T, M and C, respectively, in line with the history of strong photobleaching of the water samples as indicated by fairly high absorption spectral slope ratios (0.75–1.53 with a mean 1.03). Intermediate fluorescence index (FI) (1.46–1.83 with a mean 1.61) and small specific absorption at 254 nm (0.64–1.93 with a mean 1.15 m?1 mg?1 L) of the water samples, indicated the presence of both aquatic microbial DOM (e.g. peak T) and soil DOM (e.g. peak C). Peak C could be substantially removed by UV-A (320–400 nm) irradiation, while peak M was slightly increased when a microbe-containing water was exposed to the same UV-A irradiation. Taken together, peak C was attributed to diffuse soil source while peak M was likely attributed to joint effects of microbial activities and solar irradiation on the chromophores in the sample. 相似文献
278.
S. Widdicombe A. Beesley J.A. Berge S.L. Dashfield C.L. McNeill H.R. Needham S. Øxnevad 《Marine pollution bulletin》2013
A mesocosm experiment was conducted to quantify the relationships between the presence and body size of two burrowing heart urchins (Brissopsis lyrifera and Echinocardium cordatum) and rates of sediment nutrient flux. Furthermore, the impact of seawater acidification on these relationships was determined during this 40-day exposure experiment. Using carbon dioxide (CO2) gas, seawater was acidified to pHNBS 7.6, 7.2 or 6.8. Control treatments were maintained in natural seawater (pH ≈ 8.0). Under normocapnic conditions, burrowing urchins were seen to reduce the sediment uptake of nitrite or nitrate whilst enhancing the release of silicate and phosphate. In acidified (hypercapnic) treatments, the biological control of biogeochemical cycles by urchins was significantly affected, probably through the combined impacts of high CO2 on nitrifying bacteria, benthic algae and urchin behaviour. This study highlights the importance of considering biological interactions when predicting the consequences of seawater acidification on ecosystem function. 相似文献
279.
Based on the estimation of greenhouse gases (GHG) emissions and carbon sequestration of the total conversion of marshlands (TMC), marshlands conversion to paddy fields (MCPFs) and marshlands conversion to uplands (MCULs), this study revealed the contribution to the global warming mitigation (CGWM) of paddy fields versus uplands converted from marshlands in the Sanjiang Plain (excluding the Muling‐Xingkai Plain on south of Wanda Mountain), Heilongjiang Province, northeast China. The results showed that the total area of MCPFs and MCULs was 504.23 × 103 ha between 1982 and 2005. The CGWM per unit area was 45.53 t CO2eq/ha for MCPFs and that was 23.95 t CO2eq/ha for MCULs, with an obvious 47.40% reduction. The MCPFs and MCULs ecosystems acted as the carbon sink all of the year. As far as CGWM per unit area is concerned, MCPFs mitigated the greenhouse effect which was greater than MCULs. And it was effective that the implementation of the uplands transformed into paddy fields in Northeast China with regard to marshlands protection and croplands (including paddy fields and uplands) reclamation. 相似文献
280.
In view of water pollutants becoming more complex, both anionic and cationic pollutants need to be removed. The multi‐pollutants simultaneous removal is paid more and more attention. Hence, development composite materials for treatment complex wastewater are the aim of this study. In this research, iron–nickel nanoparticles deposited onto aluminum oxide (α‐Al2O3) and carbon nanotubes (CNTs) to form nanocomposite materials Fe–Ni/Al2O3 and Fe–Ni/CNTs, respectively, were used as adsorbents. The adsorption capacities of Fe–Ni/Al2O3 and Fe–Ni/CNTs for AO7, HSeO, and Pb2+ were observed to be 5.46, 8.28, 27.02, and 25.6 mg/g, 15.29 and 17.12 mg/g, separately. The composite materials with negative charges were superior in adsorption of anionic pollutants. Using orthogonal experimental design and analysis of variance to co‐treat dye AO7, HSeO and Pb2+ in aqueous solutions, seven testing factors were included: (1) adsorbent types, (2) amount of iron, (3) solution pHs, (4) AO7 concentrations, (5) Pb2+ concentrations, (6) HSeO concentrations and (7) reaction time. The experimental results showed that the removal of complex pollutants AO7, HSeO, and Pb2+ on Fe–Ni/CNTs could reach up to 90% in the optimal treatment conditions. When using Fe–Ni/CNTs as the adsorbent, the sorption isothermals were well fitted in the Freundlich isotherm, and R2 could reach up to 0.98. 相似文献