Carbon isotope stratigraphy of Lochkovian to Eifelian limestones from the Devonian of central and southern Europe

Lower to Middle Devonian carbonates of the Prague Syncline, the Carnic Alps, the Montagne Noire, and the Cantabrian Mountains were investigated for δ¹³C_carb and δ¹³C_org. These values were measured on bulk rocks, selected components and cements. Many carbonates exhibit primary marine values, but some are altered by diagenesis. A δ¹³C curve can be presented for the latest Pridolian to Emsian time interval. Several sharp or broad positive excursions are obvious in the woschmidti-postwoschmidti, sulcatus, kitabicus, Late serotinus, and kockelianus conodont zones. The excursion at the Silurian–Devonian boundary is known worldwide and therefore considered global in nature. Some of the others are described for the first time from central and southern Europe, and their global nature has to be verified by further investigations in other regions. Most excursions relate to and/or started during major regressions whereas sea-level highstands correspond to minimal δ¹³C values. Similar relationships between sea-level changes and δ¹³C have been observed from other early Palaeozoic intervals. The transgressive Chote? (?) and Ka?ák events are marked by positive isotope excursions, this type of combination is usually observed in late Palaeozoic to Cenozoic black shale events.     

潮汐湿地土壤碳矿化及其对电子受体响应研究进展

潮汐湿地是一种重要的湿地类型,受周期性变化的潮汐水位和盐分等特殊因子的影响,其土壤碳矿化过程亦具独特性,综述了潮汐湿地土壤碳矿化及其对电子受体响应的最新研究进展。结果表明,潮汐湿地土壤碳矿化除有氧碳矿化外,三价铁和硫酸盐还原过程主导的厌氧碳矿化也是土壤碳矿化的重要途径;潮汐湿地类型中的红树林土壤碳矿化速率高于盐沼土壤碳矿化速率,并均以二氧化碳为土壤碳矿化的主要产物;生境的差异使不同电子受体在土壤碳矿化中的作用有所不同,并受到电子受体和电子供体数量的调节;潮汐、盐分、生物干扰等是影响潮汐湿地土壤碳矿化过程的主要因子。     

Performance of various similarity functions for nondimensional wind and temperature profiles in the surface layer in stable conditions

The linear functions for non-dimensional wind and temperature profiles are commonly used to describe the surface layer fluxes in atmospheric models. However, their applicability is limited to smaller values of the stability parameter z/L (where z is the height above ground and L is the Obukhov length) i.e. z/L < 1.0. These linear functions have been modified (Webb 1970, Quart. J. Roy. Meteor. Soc. 96, 67–90; Clarke 1970, Quart. J. Roy. Meteor. Soc. 96, 91–114; Hicks 1976, Quart. J. Roy. Meteor. Soc. 102, 535–551; Beljaars and Holtslag 1991, J. Appl. Meteorol. 30, 327–341; Cheng and Brutsaert 2005, Boundary-Layer Meteorol. 114, 519–538) over the years for calculating fluxes when z/L > 1.0 under strongly stable conditions. In view of this, the objective of the present study is to analyze the performance of these similarity functions to compute surface fluxes in stable conditions.The meteorological observations from the Cooperative Atmosphere-Surface Exchange Study (CASES-99) experiment are utilized for computing the surface fluxes in stable conditions. The computed fluxes are found to be reasonably close to those observed. The ratio of observed to computed fluxes reveals that the computed fluxes are close to the observations for all the similarity functions for z/L < 1.0 whereas the computed values show relatively a large scatter from observations for z/L > 1.0. The computed values of u and heat flux do not show significant differences from those observed at 99% confidence limit. The performance of all the similarity functions considered here is found to be comparable to each other in strongly stable conditions.     

A Note on Reviving the Goddard Satellite-Based Surface Turbulent Fluxes （GSSTF） Dataset

Accurate sea surface flux measurements are crucial for understanding the global water and energy cycles. The oceanic evaporation, which is a major component of the global oceanic fresh water flux, is useful for predicting oceanic circulation and transport. The global Goddard Satellite-based Surface Turbulent Fluxes Version-2 (GSSTF2; July 1987--December 2000) dateset that was officially released in 2001 has been widely used by scientific community for global energy and water cycle research, and regional and short period data analyses. We have recently been funded by NASA to resume processing the GSSTF dataset with an objective of continually producing a uniform dataset of sea surface turbulent fluxes, derived from remote sensing data. The dataset is to be reprocessed and brought up-to-date (GSSTF2b) using improved input datasets such as a recently upgraded NCEP/DOE sea surface temperature reanalysis, and an upgraded surface wind and microwave brightness temperature V6 dataset (Version 6) from the Special Sensor Microwave Imager (SSM/I) produced by Remote Sensing Systems (RSS). A second new product (GSSTF3) is further proposed with a finer temporal (12-h) and spatial (0.25^ox0.25^o) resolution. GSSTF2b (July 1987--December 2008) and GSSTF3 (July 1999--December 2009) will be released for the research community to use by late 2009 and early 2011, respectively.     

Transnational linkages and the spillover of environment-efficiency into developing countries

Arguments about the “positive” influence of growing transnational linkages have typically focused on their role in diffusing environmentally superior innovations which help to raise countries’ environment-efficiency. The present article empirically tests these claims by examining whether developing countries’ linkages with more CO₂- and SO₂-efficient economies contribute to domestic improvements in CO₂- and SO₂-efficiency. Our large-N, statistical findings caution against some of the efficiency-oriented optimism voiced by supporters of globalization. Although imports ties with more pollution-efficient countries are found to spillover into improved domestic CO₂- and SO₂-efficiency, neither transnational linkages via exports, inward foreign direct investment (FDI) nor telephone calls appear to have any influence on domestic pollution-efficiency.     

Responses of Vertical Structures in Convective and Stratiform Regions to Large-Scale Forcing during the Landfall of Severe Tropical Storm Bilis （2006）

The responses of vertical structures,in convective and stratiform regions,to the large-scale forcing during the landfall of tropical storm Bilis(2006) are investigated using the data from a two-dimensional cloud-resolving model simulation.An imposed large-scale forcing with upward motion in the mid and upper troposphere and downward motion in the lower troposphere on 15 July suppresses convective clouds,which leads to ～100% coverage of raining stratiform clouds over the entire model domain.The imposed forci...     

地表通量输送对飑线过程影响的数值模拟研究

使用水平分辨率20km的RSM-RANAL再分析资料和WRF模式,对2004年7月12日影响上海地区的一次飑线过程进行分析和数值模拟,结果表明:(1)雷暴发生区域的西北侧约300km处有一冷锋,地面风场辐合;中低层为一致西南急流,雷暴发生区域上空300hPa位于西风急流右后侧辐散区中;地面存在明显的温度梯度。(2)雷暴发生前浙皖交界山区处的CAPE增至1000J/kg,CIN减至30J/kg以下;杭州湾附近的CAPE值大于2000J/kg。这些地方之后均有强对流单体生成,并成为飑线的一部分。(3)WRF模式对这次飑线过程的主要特征模拟较好,包括地面风场和飑线的结构。(4)敏感性试验指出陆面过程对本次飑线过程的形成发展起了重要作用。一方面通过潜热通量输送增大边界层湿度;另一方面通过感热通量输送改变了边界层的层结结构,使得低层辐合(或抬升)比较容易释放不稳定。在强对流天气的预报中地表条件不可忽略。     

Gap Filling and Quality Assessment of CO2 and Water Vapour Fluxes above an Urban Area with Radial Basis Function Neural Networks

Vertical turbulent fluxes of water vapour, carbon dioxide, and sensible heat were measured from 16 August to the 28 September 2006 near the city centre of Münster in north-west Germany. In comparison to results of measurements above homogeneous ecosystem sites, the CO₂ fluxes above the urban investigation area showed more peaks and higher variances during the course of a day, probably caused by traffic and other varying, anthropogenic sources. The main goal of this study is the introduction and establishment of a new gap filling procedure using radial basis function (RBF) neural networks, which is also applicable under complex environmental conditions. We applied adapted RBF neural networks within a combined modular expert system of neural networks as an innovative approach to fill data gaps in micrometeorological flux time series. We found that RBF networks are superior to multi-layer perceptron (MLP) neural networks in the reproduction of the highly variable turbulent fluxes. In addition, we enhanced the methodology in the field of quality assessment for eddy covariance data. An RBF neural network mapping system was used to identify conditions of a turbulence regime that allows reliable quantification of turbulent fluxes through finding an acceptable minimum of the friction velocity. For the data analysed in this study, the minimum acceptable friction velocity was found to be 0.15 m s⁻¹. The obtained CO₂ fluxes, measured on a tower at 65 m a.g.l., reached average values of 12 μmol m⁻² s⁻¹ and fell to nighttime minimum values of 3 μmol m ⁻² s⁻¹. Mean daily CO₂ emissions of 21 g CO₂ m⁻²d ⁻¹ were obtained during our 6-week experiment. Hence, the city centre of Münster appeared to be a significant source of CO₂. The half-hourly average values of water vapour fluxes ranged between 0.062 and 0.989 mmol m⁻² s⁻¹and showed lower variances than the simultaneously measured fluxes of CO₂.     

Light hydrocarbons geochemistry of surface sediment from petroliferous region of the Mehsana block,North Cambay Basin

A study was carried out to test the usefulness of surface geochemical methods as regional evaluation tools in petroliferous region of the Mehsana block, North Cambay Basin. A suite of 135 soil samples collected from the depth of 2.5 m, were analyzed for adsorbed light gaseous hydrocarbons and carbon isotopes (δ¹³C_methane and δ¹³C_ethane). The light gaseous hydrocarbon analysis show that the concentration ranges 402 ppb, 135 ppb, 70 ppb, 9 ppb and 18 ppb of C₁, C₂, C₃, iC₄ and nC₄, respectively. The value of carbon isotopic ranges of methane −29.5 to −43.0‰ (PDB) and ethane −19.1 to −20.9‰ (PDB). This data, when mapped, indicates patterns coinciding with major known oil and/or gas field of Sobhasan/Linch in this study area. The existence of un-altered petroliferous microseeps of catagenetic origin is observed in the study area. A regional study, such as the one described here, can provide important exploration facts concerning the regional hydrocarbon potential in a block. This method has been confirmed and can be applied successfully in frontier basins.     

Upwelling signals in radiocarbon from early 20th-century Peruvian bay scallop (Argopecten purpuratus) shells

We quantified Δ¹⁴C, δ¹⁸O, and δ¹³C cycles along ontogeny within four bay scallop (Argopecten purpuratus) shells collected from Callao Bay, Salaverry, and Sechura Bay, Peru following the 1907–1908 non-El Niño years and the 1925–1926 El Niño. Δ¹⁴C and δ¹³C generally covary; Δ¹⁴C and δ¹⁸O vary inversely. Simultaneous decreases in Δ¹⁴C and increases in δ¹⁸O in non-El Niño shells are followed by constant Δ¹⁴C and gradually decreasing δ¹⁸O, which we interpret as evidence for discrete marine upwelling events followed by warming of the initially cold upwelled water. Upwelling changes from El Niño events are detectable with difficulty in mollusk shell Δ¹⁴C.