ELIMINATING COMPLEX EIGENVECTORS AND EIGENVALUES IN MULTIWAY ANALYSES USING THE DIRECT TRILINEAR DECOMPOSITION METHOD

The direct trilinear decomposition method(DTDM)is an algorithm for performing quantitative curveresolution of three-dimensional data that follow the so-called trilinear model,e.g.chromatography-spectroscopy or emission-excitation fluorescence.Under certain conditions complexeigenvalues and eigenvectors emerge when the generalized eigenproblem is solved in DTDM.Previouspublications never treated those cases.In this paper we show how similarity transformations can be usedto eliminate the imaginary part of the complex eigenvalues and eigenvectors,thereby increasing theusefulness of DTDM in practical applications.The similarity transformation technique was first used byour laboratory to solve the similar problem in the generalized rank annihilation method(GRAM).Because unique elution profiles and spectra can be derived by using data matrices from three or moresamples simultaneously,DTDM with similarity transformations is more efficient than GRAM in the casewhere there are many samples to be investigated.     

第二代航磁黄沙坪异常的分解及其矿产新空间

本文采用同时具有识別、分解、解释异常三重作用的三元解释法■,在黄沙坪异常负值区有效地提取了由未知的深源磁性体引起的剩余异常。该异常与已知的中、浅源磁性体分处于极为类同的成矿地质背景中。后者与隐伏岩体、铅锌多金属盲矿体之间有着密切的成生联系。这为前者间接找矿提供了有力的依据。定量解释结果中,两者间的磁矩等效关系,论证了已知矿床西侧深部空间里,仍存在找到又一个大型矿床的前景。     

Characteristics and analysis of the geomagnetic variations in regions around the Qiongzhou Strait

Ｃｈａｒａｃｔｅｒｉｓｔｉｃｓ　ａｎｄ　ａｎａｌｙｓｉｓ　ｏｆ　ｔｈｅ　ｇｅｏｍａｇｎｅｔｉｃ　ｖａｒｉａｔｉｏｎｓ　ｉｎ　ｒｅｇｉｏｎｓ　ａｒｏｕｎｄ　ｔｈｅ　Ｑｉｏｎｇｚｈｏｕ　Ｓｔｒａｉｔ（范国华）（姚同起）（顾左文）（朱克佳）（陈伯舫）（冯戬...     

Field measurements of NO and NO2 emissions from fertilized and unfertilized soils

Field measurements of NO and NO₂ emissions from soils have been performed in Finthen near Mainz (F.R.G.) and in Utrera near Seville (Spain). The applied method employed a flow box coupled with a chemiluminescent NO _x detector allowing the determination of minimum flux rates of 2 g N m^-2 h^-1 for NO and 3 g m^-2 h^-1 for NO₂.The NO and NO₂ flux rates were found to be strongly dependent on soil surface temperatures and showed strong daily variations with maximum values during the early afternoon and minimum values during the early morning. Between the daily variation patterns of NO and NO₂, there was a time lag of about 2 h which seem to be due to the different physico-chemical properties of NO and NO₂. The apparent activation energy of NO emission calculated from the Arrhenius equation ranged between 44 and 103 kJ per mole. The NO and NO₂ emission rates were positively correlated with soil moisture in the upper soil layer.The measurements carried out in August in Finthen clearly indicate the establishment of NO and NO₂ equilibrium mixing ratios which appeared to be on the order of 20 ppbv for NO and 10 ppbv for NO₂. The soil acted as a net sink for ambient air NO and NO₂ mixing ratios higher than the equilibrium values and a net source for NO and NO₂ mixing ratios lower than the equilibrium values. This behaviour as well as the observation of equilibrium mixing ratios clearly indicate that NO and NO₂ are formed and destroyed concurrently in the soil.Average flux rates measured on bare unfertilized soils were about 10 g N m^-2 h^-1 for NO₂ and 8 g N m^-2 h^-1 for NO. The NO and NO₂ flux rates were significantly reduced on plant covered soil plots. In some cases, the flux rates of both gases became negative indicating that the vegetation may act as a sink for atmospheric NO and NO₂.Application of mineral fertilizers increased the NO and NO₂ emission rates. Highest emission rates were observed for urea followed by NH₄Cl, NH₄NO₃ and NaNO₃. The fertilizer loss rates ranged from 0.1% for NaNO₃ to 5.4% for urea. Vegetation cover substantially reduced the fertilizer loss rate.The total NO _x emission from soil is estimated to be 11 Tg N yr^-1. This figure is an upper limit and includes the emission of 7 Tg N yr^-1 from natural unfertilized soils, 2 Tg N yr^-1 from fertilized soils as well as 2 Tg N yr^-1 from animal excreta. Despite its speculative character, this estimation indicates that NO _x emission by soil is important for tropospheric chemistry especially in remote areas where the NO _x production by other sources is comparatively small.     

Time–frequency representation of earthquake accelerograms and inelastic structural response records using the adaptive chirplet decomposition and empirical mode decomposition

In this paper, the adaptive chirplet decomposition combined with the Wigner-Ville transform and the empirical mode decomposition combined with the Hilbert transform are employed to process various non-stationary signals (strong ground motions and structural responses). The efficacy of these two adaptive techniques for capturing the temporal evolution of the frequency content of specific seismic signals is assessed. In this respect, two near-field and two far-field seismic accelerograms are analyzed. Further, a similar analysis is performed for records pertaining to the response of a 20-story steel frame benchmark building excited by one of the four accelerograms scaled by appropriate factors to simulate undamaged and severely damaged conditions for the structure. It is shown that the derived joint time–frequency representations of the response time histories capture quite effectively the influence of non-linearity on the variation of the effective natural frequencies of a structural system during the evolution of a seismic event; in this context, tracing the mean instantaneous frequency of records of critical structural responses is adopted.The study suggests, overall, that the aforementioned techniques are quite viable tools for detecting and monitoring damage to constructed facilities exposed to seismic excitations.     

Gauss-Markov模型参数的岭型广义逆估计及其优良性

本文继续文献 [10 ]的工作 ,进一步讨论了测量平差 Gauss- Markov模型参数岭型广义逆估计的若干性质 ,如允许性、优效性、相对效率、抗干扰性等等 ,得到了许多重要结论。计算结果表明 ,在设计阵呈病态时 ,岭型广义逆估计确能明显改善 L S估计     

岩石矿物及粉尘中游离二氧化硅的测定

改进了游离二氧化硅（fSiO2)测定中试样的分解方法，采用硫－磷混酸替代单独使用磷酸分解试样，防止了焦磷酸盐的形成，同时，氟硼酸对fSiO2的溶解率符合测定要求。改进的方法用于标准物质中fSiO2的测定，结果与标准值或磷酸溶矿重量法相符。对于ω(fSiO2)=3.26%的标样10次测定的RSD为2．4％。