Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins

The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log α_M(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 10²⁰ M^− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log α_M(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.     

Modelling linear wave transformation induced by dissipative structures—Random waves

The relevant theory is presented and numerical results are compared with the analytical solution for the interaction of non-breaking waves with an array of vertical porous circular cylinders on a horizontal bed. The extension to the cases of unidirectional and multidirectional waves is obtained by means of a transfer function. The influence of the mechanical properties of porous structures and wave irregularity on wave transformation is analysed. Results for unidirectional and multidirectional wave spectra are compared to those obtained for regular waves. The model presented reproduces well the analytical results and provides a tool for analysing several engineering problems.     

波群作用于垂直桩柱的峰力统计性质

研究具有窄谱和Ｗｅｉｂｕｌｌ波高分布的波群对非线性桩柱系统作用力的统计性质。求得了桩桩的波浪峰力的各种特征值及其比值。指出这些数值不仅是阻力一惯性力参数ｂＨ的函数，也随着波群因子而变化。本文模式更具广泛性。文中给出了一系列计算图表，可从理论计算波群作用于桩柱的波浪峰力。     

柴达木盆地新构造运动主要特征与成因机制

研究表明，在壳幔结构、地球物理背景、沉积物结构、多层关地幔和构造样式等方面，达木盆地与中国东部新生代裂谷类伸展盆地具有可比性，应该归属 展性盆 。盆地伸展和收缩作用相间进行，伸展起因于地幔底辟；而收缩受两人因素影响；（１）盆地伸展作用受相邻造山带反作用诱导的挤压应力；（２）板块碰撞传递的远程板内应力。在此基础邮新的构造期达木盆地演化的“双层模式”，即地幔上隆－地壳伸展；被动挤压＋板内应力－地壳收缩     

深圳湾福田红树林区藻类、纤毛虫等生物群落及其与环境的关系

对福田国家级红树林自然保护区近岸水域进行水质及生态调查,结果显示,深圳湾潮汐对红树林中微型生物生态及湿地污染状况产生了最为直接的影响;藻类在红树林中具有较好的水质污染指示作用,其生态功能大于纤毛虫、轮虫等微型生态类群;微型生物可通过食物链对污染物起放大和传递作用,传递途径在水体中以藻→纤毛虫为主,底质中以藻→底栖动物幼虫为主。     

波峰特征量的统计分布

本文在作者另文数值模拟得到的三维海浪基础上 ,进一步分析给出了三维波峰长度、高度及方向角度等特征量的统计分布。发现考虑海浪的方向性质后波峰分布不再是均匀连续的 ;波峰的长度分布受方向函数影响 ,方向分布越宽 ,波峰的平均长度越短 ,波峰的方向角分布越宽 ;波峰高度和长度在波峰高度较小时有很大的相关性 ,而在波峰高度很大时无关     

三次样条函数在海洋水文资料整理中的应用

本文引入三次样条函数插值法,并尝试用于海洋资料处理。根据渤海及北黄海部分海洋站的历史资料进行了试验。用SHARP—PC—1211袖珍计算机进行计算,并将资料处理的结果与传统的过程曲线法订正值作了比较。结果表明,二者之间的误差不大,而样条函数拟合更好。作者认为三次样条函数插值法是可行的,在处理海洋资料时间序列中是有效的。在有温跃层的地方,如何应用,本文也给出了必要的说明。