胶州湾及其邻近河流中壬基酚等有机污染物的分布特征

为分析青岛胶州湾及其邻近河流中的壬基酚（NP）及其短链氧乙烯醚母体化合物、壬基酚单氧乙烯醚（NP1EO）和壬基酚二氧乙烯醚（NP2EO）的污染状况和分布特征,在研究区域内设置了17个站位分别采集了海水和沉积物样品,样品经萃取、浓缩、净化后采用气质联用仪测定各污染物的浓度。胶州湾水体中的NP、NP1EO和NP2EO的浓度分别为20．2-268．7、11．2-200．4和4．8-32．5ng／L。胶州湾沉积物中上述3种污染物的浓度分别为3．6-299．3、3．8-25．2和4．9-103．2ng／g。胶州湾邻近河流中的污染物浓度远远高于湾内,其中墨水河的污染最严重,水体和沉积物中NP的浓度分别达到28656ng／L和31704ng／g。与世界其他海湾NP等污染物的浓度相比,胶州湾属于严重污染地区之一,已经超出了其生物效应临界浓度。研究区域内50％的站位中NP浓度已经超过导致扇贝苗死亡的临界浓度,10％的站位已经超过引起雄性鱼类雌性化的临界浓度。     

胶州湾潮汐潮流动边界数值模拟

基于普林斯顿海洋模式,通过干湿网格判别法引入潮汐潮流的漫滩过程,考虑M₂,S₂,K₁,O₁,M₄和MS₄六个主要分潮,建立了胶州湾潮汐潮流数值模拟和预报模型,研究了该海域潮汐潮流特征,并讨论了漫滩对潮流模拟的影响。与实测资料的对比验证表明,该模式能够对胶州湾的潮汐和潮流做出较为合理的预测。给出了胶州湾潮汐、潮流、余流等分布特征,模拟的潮流场以及余流场涡旋等现象与观测符合良好;计算了潮波能通量,从能量角度探讨了潮波的传播特性;对潮位与潮流场演变规律,以及潮能通量的分析表明,胶州湾内的潮波以驻波为主。通过数值试验发现,漫滩过程的引入对胶州湾潮流速度的模拟至关重要,不考虑漫滩过程的模式会夸大或者低估潮流流速。对于滩涂面积广阔的海域来说,潮流数值模式中考虑漫滩的影响是必要的。     

深圳湾海域表层和柱样沉积物中的重金属分布特征

分析深圳湾表层沉积物中锌、铬、镉、镍、铅、铜等6种重金属元素的含量发现它们的浓度均值已全部超过广东省海岸带沉积物背景值。根据潜在生态危害法,在6种重金属中镉造成的污染最严重,从潜在的生态危害指数评价看镉的含量已达到很高的污染水平。从面状分布看,重金属污染危害指数值在深圳河口区最低,在蛇口段居中等水平,在深圳湾内侧的近岸水域最大。柱样沉积物的浓度变化以1950年为界划分为两部分:1950年以来的现代沉积物中有较强的人类活动干扰痕迹,表现为重金属元素的浓度增长幅度大,且浓度很高,其均值全部大于广东省海岸带的背景值;1950年以前的近代沉积物中有稍弱的人类活动干扰痕迹。研究认为沉积物粒度特征、沉积速率、人类活动与重金属在沉积物中的浓度高低有直接相关关系,并直接影响到重金属在沉积物中的污染水平。     

The investigation on particulate organic carbon fluxes with disequilibria between thorium-234 and uranium-238 in the Prydz Bay, the Southern Ocean

Dissolved and particulate thorium-234, particulate organic carbon in the upper 150 m of water columns from five stations in the Prydz Bay, the Southern Ocean were determined during the 22nd Chinese National Antarctic Research Expedition （from November 2005 to March 2006 ）. The disequilibria between thorium-234 and its parent uranium-238 in upper layer was used to derive the averaged residence time of thorium-234, which decreased along with the latitude to the south and a minimum value, 1 - 8 d for particulate thorium-234 and 29 - 48 d for dissolved thorium-234, appeared at the medium latitude station, and the export fluxes of thorium-234 were calculated too and ＇a maximum value, 0. 35 -0. 63 Bq/（m^3 · d） for the particulate thorium-234 and 0. 44 -0. 65 Bq/ （m^3 ·d） for the dissolved thorium-234, appeared at the same station. The export fluxes of particulate organic carbon at different water columns were derived by two methods with irreversible scavenging model, and the averaged values were 104. 7 mmol/ （ m2 · d ） （ E method） and 120. 6 mmol/（ m2·d ） （ B method ）, respectively, indicating that a relatively high new production would exist in summer in the Prydz Bay where it will play a potential significant role in sequestering the absorption CO2 to deeper ocean.     

Water, organic matter, nitrogen and phosphorus contents in sediment of a large-scale mariculture area in the Zhelin Bay of eastern Guangdong Province, China

The Zhelin Bay is one of the most important bays for large-scale mariculture in Guangdong Province, China. Owing to the increasing human population and the expanding mariculture in the last two decades, the ecological environment has greatly changed with frequent harmful algal blooms. A monthly survey of water content, organic matter （TOM）, and various forms of nitrogen and phosphorous in sediment from July 2002 to July 2003 in the bay was conducted. The results showed that the water content was correlated significantly with TOM and various forms of nitrogen and phosphorus and can be used as proxy for quick and rough estimate of these factors in the future surveys. TOM was also correlated significantly with various forms of nitrogen and phosphorus, indicating that it was one of the key factors affecting the concentrations and distributions of nitrogen and phosphorus in the investigated waters. Average total Kjeldhal nitrogen （TkN） content was（ 1 113.1 ± 382.5）μg/g and average total phosphorus （TP） content was（567.2± 223.3）μg/g, and both were much higher than those of similar estuaries in China and elsewhere. Average nitrogen and phosphorus tended to be higher inside than outside the bay, higher at aquaculture than non-aquaculture areas, and higher at fish-cage culture than oyster culture areas, suggesting that large-scale mariculture inside the bay played an important role in the eutrophication of the Zhelin Bay. Various forms of nitrogen and phosphorus concentrations were higher during the warm season （July--September）, which was due to the increased decomposition and concentration of organic matter resulted from the fast growth and high mortality of the cultured species. Compared with July 2002, TkN and TP contents were much higher in July 2003, in consonance with the eutrophication of the Zhelin Bay. Because exchangeable phosphorus （Ex-P）, iron-bounded phos- phorus （Fe-P） and organic phosphorus （OP） combined accounted for 34.3% of the TP and authigenic phosphorus （Au-P     

Seasonal variability in free-living marine nematode community structure in a sandy beach of the Taiping Bay of Qingdao, China

Nematode assemblage composition, trophic structure and biodiversity were followed over an annual cycle in a sandy beach of the Taiping Bay of Qingdao, China. Nematode assemblage in the sandy beach maintained a high genus diversity （75 genera）. Mlero- laimus and Bathylaimus were the dominant genus of the nematode assemblage, accounting for 66% of the total nematode abundance. The nematodes＇ dominant trophic structure changed seasonally as a response to the seasonal changes in food quality. Epigrowth-feeder nematodes （2A） were the dominant trophic groups in the trophic structure with the highest abundance in spring because of phytoplankton bloom, while the feeding type （ 1 B） showed higher abundance in summer that was due to the increasing of sediment detritus after spring bloom. Furthermore, species diversity and evenness calculated on nematodes identified to the genus level displayed significant temporal changes, which was also reflected by the index of trophic diversity. According to the cluster analysis, the nematode community structure of the whole year was clearly separated into two periods （A and B）. Biota-Envlron- ment matching （BIOENV） results showed that seawater temperature, sediment Chl a and grain size were responsible for the nema- tode community structure variation in spring and summer period （Period A）. However, seawater/interstitial water temperature, interstitial water dissolved oxygen concentration,interstitial water salinity, and sediment Ph a a were more important in constructing the autumn and winter period （Period B） nematode community structure.     

Seasonal and spatial variation in abundance and egg production of Paracalanus parvus (Copepoda: Calanoida) in/out Jiaozhou Bay, China

The spatial distribution of stage-specific abundance and reproduction of the copepod Paracalanus parvus were studied from October 2005 to September 2006 in the Jiaozhou Bay. This copepod occurred continuously in this bay throughout the year. The species reached the lowest abundance in April and peaked in June. From October to December, distribution center mainly occurred in offshore water and at the mouth of the bay. In winter, early copepodites and adults gradually decreased and till February, most of the population was only comprised of CIV–CV stages. Overwintering copepodites matured in March and males tended to mature before female. From May to September, each stage occurred in the population and gradually reached high abundance. Temperature and chlorophyll a (Chl-a) concentration in the three stations can't clearly explain the seasonal variation in stage-specific abundance, so we surmised the important effect of the Yellow Sea. Egg production rate (EPR) reached its lowest in winter and peaked in June at 60.8 eggs female⁻¹ day⁻¹ in nearshore water. In the warming period, EPR in nearshore water was statistically higher and EPR > 10 eggs female⁻¹ day⁻¹ lasted longer than that in offshore water, showing the importance of nearshore water for recruitment of P. parvus. Our study showed that EPR was positively related to temperature and total chlorophyll a in offshore water and mouth of the bay. In nearshore water, the relationships between EPR and temperature and Chl-a in three size fractions were not the same as those in offshore water, suggesting complicated ecosystem in such a eutrophic area in warming period.     

Coastal environmental assessment and management by ecological simulation in Yeoja Bay, Korea

An eco-hydrodynamic model was used to estimate the carrying capacity of pollutant loads and response of water quality to environmental change in Yeoja Bay, Korea. An energy-system model also was used to simulate the fluctuation in nutrients and organic matter in the bordering wetland. Most water quality factors showed a pulsed pattern, and the concentrations of nutrients and organic matter of seawater increased when input loads of nutrients increased due to freshwater discharge. The well-developed tidal zones and wetlands in the northern area of the bay were highly sensitive to input loads. Residence times of water, chemical oxygen demand (COD), and dissolved inorganic nitrogen (DIN) within the bay were estimated to be about 16 days, 43.2 days, and 50.2 days, respectively. Water quality reacted more sensitively to the effects of nitrogen and phosphorus input than to COD. A plan to reduce the present levels of COD and dissolved inorganic phosphorus (DIP) by 20–30% and DIN by at least 50% in pollutant loads is needed for satisfying the target water quality criteria. The natural removal rate of nutrients in wetlands by reeds was assessed to be approximately 10%.     

Dissolved nutrient balance and net ecosystem metabolism in a Mediterranean-climate coastal lagoon: San Diego Bay

The temporal and spatial variability of dissolved inorganic phosphate (DIP), nitrogen (DIN), carbon (DIC) and dissolved organic carbon (DOC) were studied in order to determine the net ecosystem metabolism (NEM) of San Diego Bay (SDB), a Mediterranean-climate lagoon. A series of four sampling campaigns were carried out during the rainy (January 2000) and the dry (August 2000 and May and September 2001) seasons. During the dry season, temperature, salinity and DIP, DIC and DOC concentrations increased from oceanic values in the outer bay to higher values at the innermost end of the bay. DIP, DIC and DOC concentrations showed a clear offset from conservative mixing implying production of these dissolved materials inside the bay. During the rainy season, DIP and DOC increased to the head, whereas salinity decreased toward the mouth due to land runoff and river discharges. The distributions of DIP and DOC also showed a deviation from conservative mixing in this season, implying a net addition of these dissolved materials during estuarine mixing within the bay. Mass balance calculations showed that SDB consistently exported DIP (2.8–9.8 × 10³ mol P d⁻¹), DIC (263–352 × 10³ mol C d⁻¹) and DOC (198–1233 × 10³ mol C d⁻¹), whereas DIN (5.5–18.2 × 10³ mol N d⁻¹) was exported in all samplings except in May 2001 when it was imported (8.6 × 10³ mol N d⁻¹). The DIP, DIC and DOC export rates along with the strong relationship between DIP, DIC or DOC and salinity suggest that intense tidal mixing plays an important role in controlling their distributions and that SDB is a source of nutrients and DOC to the Southern California Bight. Furthermore, NEM ranged from −8.1 ± 1.8 mmol C m⁻² d⁻¹ in September to −13.5 ± 5.8 mmol C m⁻² d⁻¹ in January, highlighting the heterotrophic character of SDB. In order to explain the net heterotrophy of this system, we postulate that phytoplankton-derived particulate organic matter, stimulated by upwelling processes in the adjacent coastal waters, is transported into the bay, retained and then remineralized within the system. Our results were compared with those reported for the heterotrophic hypersaline coastal lagoons located in the semi-arid coast of California–Baja California, and with those autotrophic hypersaline systems found in the semi-arid areas of Australia. We point out that the balance between autotrophy and heterotrophy in inverse estuaries is dependent on net external inputs of either inorganic nutrients or organic matter as it has been indicated for positive estuaries.     

Petroleum pollution in surface sediments of Daya Bay,South China,revealed by chemical fingerprinting of aliphatic and alicyclic hydrocarbons

Nine surface sediments collected from Daya Bay have been Soxhlet-extracted with 2:1 (v/v) dichloromethane-methanol. The non-aromatic hydrocarbon (NAH) fraction of solvent extractable organic matter (EOM) and some bulk geochemical parameters have been analyzed to determine petroleum pollution of the bay. The NAH content varies from 32 to 276 μg g⁻¹ (average 104 μg g⁻¹) dry sediment and accounts for 5.8–64.1% (average 41.6%) of the EOM. n-Alkanes with carbon number ranging from 15 to 35 are identified to be derived from both biogenic and petrogenic sources in varying proportions. The contribution of marine authigenic input to the sedimentary n-alkanes is lower than the allochthonous input based on the average n-C₃₁/n-C₁₉ alkane ratio. 25.6–46.5% of the n-alkanes, with a mean of 35.6%, are contributed by vascular plant wax. Results of unresolved complex mixture, isoprenoid hydrocarbons, hopanes and steranes also suggest possible petroleum contamination. There is strong evidence of a common petroleum contamination source in the bay.