广西苍梧社垌石英脉型钨钼多金属矿床流体演化及来源示踪

广西苍梧社垌矿床是大瑶山隆起南侧新发现的一个大型斑岩-矽卡岩-石英脉型钨钼多金属矿床。本文重点对其中的石英脉型矿床进行了研究,依据脉体穿插关系及矿物共生组合将成矿过程划分为I石英-黄铁矿阶段、II石英-白钨矿-辉钼矿阶段、III石英-多金属硫化物阶段以及IV石英-方解石-萤石阶段,其中II和III阶段为主成矿阶段。从早到晚,均一温度逐渐下降(第一阶段550℃→370℃,第二阶段370℃→330℃,第三阶段330℃→210℃,第四阶段190℃→150℃),流体密度逐渐上升(0.61g/cm3→0.72g/cm3→0.82g/cm3→0.94g/cm3),盐度先升后降(第一阶段5.86%～8.55%NaCleqv,第二阶段4.49%～43%NaCleqv,第三阶段0.53%～46.37%NaCleqv,第四阶段0%～12.85%NaCleqv)。激光拉曼成分分析显示,社垌石英脉型矿床的成矿流体属于H2O-NaCl体系,但是该体系的流体成分在成矿前后发生了较大的变化,反映第I阶段以氧化环境为主,(II、III、)IV阶段则为还原环境。氢氧同位素研究显示成矿流体来自于岩浆水,后期大气降水的加入导致矿质发生沉淀。此外金属硫化物的δ34S组成(-3.8‰～+1.7‰)平均为-0.46‰,接近于零值,也表明为岩浆来源。引起矿质沉淀的主要原因是流体混合导致的温度下降等环境条件的改变。总体而言,社垌石英脉型钨钼多金属矿床的成矿流体主要来自岩浆热液,为中高温、中低盐度、低密度的NaCl-H2O流体体系,钨钼等多金属成矿与区内加里东期岩浆作用密切相关。     

Preservation of diagenetic products of β-carotene in sedimentary rocks from the Lopare Basin (Bosnia and Herzegovina)

Sedimentary rocks from the saline formation of the Lopare Basin were investigated. Sediments contain a moderate amount of immature to marginally mature algal organic matter deposited under slightly reducing to anoxic and slightly saline to hypersaline conditions. Almost all of the samples contain β-carotane in a relatively high quantity, and in some, it represents the most abundant compound in the total distribution of hydrocarbons. The objective of the study was to determine the conditions that are favourable to precursors of β-carotene and/or the preservation of the carotenoid hydrocarbon skeleton. Moreover, the dominant transformation pathways of β-carotene under different redox and salinity conditions, which lead to the formation of aromatic carotenoids were defined.     

Permian volcanic rocks from the Apuseni Mountains (Romania): Geochemistry and tectonic constraints

An Early Permian volcanic assemblage is well exposed in the central-western part of the Apuseni Mountains (Romania). The rocks are represented by rhyolites, basalts and subordinate andesites suggesting a bimodal volcanic activity that is intimately associated with a post-orogenic (Variscan) syn-sedimentary intra-basinal continental molasse sequences. The mafic and mafic-intermediate rocks belong to sub-alkaline tholeiitic series were separated in three groups (I–III) showing a high Th and Pb abundances, depletion in Nb, Ta and Sr, and slightly enriched in LREE patterns (La_N/Yb_N = 1.4–4.4). Isotopically, the rocks of Group I have the initial ratios ⁸⁷Sr/⁸⁶Sr_(i) = 0.709351–0.707112, ¹⁴³Nd/¹⁴⁴Nd_(i) = 0.512490–0.512588 and high positive ?_Nd270 values from 3.9 to 5.80; the rocks of Group II present for the initial ratios values ⁸⁷Sr/⁸⁶Sr_(i) = 0.709434–0.710092, ¹⁴³Nd/¹⁴⁴Nd_(i) = 0.512231–0.512210 and for ?_Nd270 the negative values from −1.17 to −1.56; the rocks of Group III display for the initial ratios the values ⁸⁷Sr/⁸⁶Sr_(i) = 0.710751–0.709448, ¹⁴³Nd/¹⁴⁴Nd_(i) = 0.512347–0.512411 and for ?_Nd270 the positive values from 1.64 to 2.35. The rocks resembling continental tholeiites, suggest a mantle origin and were further affected by fractionation and crustal contamination. In addition, the REE geochemistry (1 > Sm_N/Yb_N < 2.5; 0.9 > La_N/Sm_N < 2.5) suggests that these rocks were generated by high percentage partial melting of a metasomatized mantle in the garnet peridotite facies. The felsic rocks are enriched in Cs, Rb Th and U and depleted in Nb, Ta, Sr, Eu, and Ti. The REE fractionation patterns show a strong negative Eu anomaly (Eu/Eu* = 0.23–0.40). The felsic rocks show the initial ratios the values: ⁸⁷Sr/⁸⁶Sr_(i) = 0.704096–0.707805, ¹⁴³Nd/¹⁴⁴Nd_(i) = 0.512012–0.512021 and for ?_Nd270 the negative values from −5.27 to −5.44. They suggest to be generated within the lower crust during the emplacement of mantle-derived magmas that provided necessary heat to crustal partial melting.     

谱模拟方法在高分辨率地震资料处理中的应用

为了克服地震子波的时变影响,避免复杂的时窗大小选取问题,使得谱模拟方法能更好地适应地震信号是平稳信号的假设条件,将改进S变换与谱模拟方法相结合,形成时频域谱模拟方法。在二维时频谱中进行谱模拟处理,该方法能够克服地震子波随地层深度变化的限制。理论模型及实际资料处理效果显示,时频域谱模拟方法能够有效提高地震分辨率,实现地震资料的高分辨处理。     

微地震监测数据压缩技术

微地震监测数据海量,给数据的长距离实时无线传输带来了很多困难,而且还占用很多磁盘空间。笔者首先采用自适应阈值的STA/LTA算法,选取合适的特征函数,从海量的监测数据中自动快速准确地识别微地震有效信号;然后准确确定有效信号的起止时间,完整地截取有效信号的波形数据,去除大量冗余数据,使得数据减少为原来的20%以下;最后再采用STEIM2算法对截取后的有效信号进行压缩,使监测数据的压缩比达到10∶1。研究结果表明:该方法能够通过去除冗余数据和无损压缩,大幅减少微地震监测数据的传输量,使得最终的数据仅为原数据的10%,从而减少了微地震监测数据的长距离无线实时传输困难,同时也减少数据存储所需要的磁盘空间,取得了较好的应用效果。     

Geochemistry of mafic rocks and melt inclusions and their implications for the heat source of the 14.0°S hydrothermal field,South Mid-Atlantic Ridge

Fresh rocks sampled from the 14.0°S hydrothermal field of the South Atlantic Ridge can be divided into two categories： olivine-gabbro and basalt. The olivine-gabbro is composed mainly of three types of minerals： olivine, clinopyroxene and plagioclase, while a multitude of melt inclusions occur in the plagioclase phenocrysts of the basalts. We analyzed the whole-rock, major and trace elements contents of the basaks, the mineral chemistry of phenocrysts and melt inclusions in the basalts, and the mineral chemistry of olivine-clinopyroxene-plagioclase in the olivine-gabbro, then simulated magma evolution within the crust using the COMAGMAT program. The whole-rock geochemistry shows that all the basalts exhibit typical N-MORB characteristics. In addition, the mineral chemistry characteristics of the olivine-gabbro （low-Fo olivine, low-Mg# clinopyroxene, high-TiO2 clinopyroxene, low-An plagioclase）, show that strong magma differentiation occurred within the crust. Nevertheless, significant discrepancies between those minerals and phenocrysts in the basalts （high-Fo olivine, high-An plagioclase） reflect the heterogeneity of magma differentiation. High Mg# （-~0.72） melt inclusions isobaric partial crystallization simulations suggest that the magma differentiation occurred at the depth shallower than 13.03 km below the seafloor, and both the vertical differentiation column shows distinct discrepancies from that of a steady-state magma chamber. Instead, a series of independent magma intrusions probably occurred within the crust, and their corresponding crystallized bodies, as the primary high-temperature thermal anomalies within the off-axis crust, probably act as the heat source for the development of the 14.0°S hydrothermal system.     

Mineral characteristics and their geological significance of black shales in southeastern Ordos Basin by X-ray diffraction analysis

X-ray diffraction analysis of black shale of Upper Triassic Member Chang 7 of the Yanchang Formation in southeastern Ordos Basin showed that black shales were deposited in brackish, strongly reducing, semi-deep-deep lacustrine facies, and mainly composed of quartz, feldspar, carbonate （dolomite）, clay minerals （illite and il- lite/smectite） and a certain amount of pyrite. The mineral composition characteristics of this set of black shales are similar to those of highly productive shale gas in North America, for example shallow burial, low clay mineral and abundant brittle mineral, so the strata are conducive to the development of cracks and fractures. Thus, this area is favorable for shale oil/gas exploration and development.     

Effects of Lateral Variation in Vegetation and Basin ‘Dome’ Shape on Tropical Lowland Peat Stabilisation in the Kota Samarahan-Asajaya Area, West Sarawak, Malaysia

Field surveys indicate lateral variation in peat humification levels （von Post） in dominantly occurring fibric,fibric to hemic,sapric and hemie to sapric peats across a gradient from the margin towards the centre of tropical lowland peat domes.Cement-peat stabilisation can be enhanced by adding mineral soil fillers （silt,clays and fine sands） obtained from Quaternary floodplain deposits and residual soil （weathered schist）.The unconfined compressive strength （UCS） of the stabilised cement-mineral soil fifler-peat mix increases with the increased addition of selected mineral soil filler.Lateral variation in the stabilised peat strength （UCS） in the top 0 to 0.5 m layer was found from the margin towards the centre of the tropical lowland peat dome.The variations in the UCS of stabilised tropical lowland peats along a gradient from the periphery towards the centre of the peat dome are most likely caused by a combination of factors due to variations in the mineral soil or ash content of the peat and horizontal zonation or lateral variation in the dominant species of the plant assemblages （due to successive vegetation zonation of the peat swamp forest from the periphery towards the centre of the tropical lowland peat dome）.     

不均衡的跨国人口流动：对美墨移民历程与政策的思考

美国是全球最大的移民接收国,墨西哥是美国最大的移民来源国,特殊的地缘关系和巨大的发展差距使众多墨西哥人移民美国。墨裔移民为美国提供了充足的劳动力,在美墨边境地区,移民集聚带动了两国边境地区的发展。但族裔矛盾始终是美国主要社会问题之一,特别是“9·11”事件后,少数族裔和非法移民问题加剧美国社会分裂和对立,成为美国国内政治博弈的焦点。基于区域地缘关系的视角来看,美国与墨西哥之间长期不对等的国际关系决定了跨国移民的流入状态和生存境遇,也是美国族群矛盾的主要原因之一。移民问题政治化将持续强化墨裔移民政策的不确定性,使移民个人与家庭面临更大的融入困难。     

青海北川河流域径流变化的机理研究——基于模型和统计两种方法

气候变化和下垫面变化是影响河道径流的两大驱动力,研究两者对径流的影响有利于深入理解流域水文过程,为水资源管理提供科学依据。鉴于利用不同方法获得的结果存在一定程度的差异,有必要使用多种方法进行交叉验证。论文基于Budyko水量平衡法和新增水库模块的分布式水文模型(DHSVM)法量化了气候变化和下垫面变化对青海省北川河流域径流变化的贡献。结果表明：① 自1960年以来流域出口流量以每年0.037 m³/s的趋势下降,突变年份发生在1969年。② 2种方法的分析结果均表明,年代际尺度上,气候变化对径流影响的贡献率由高到低依次为：1990—1999年>2000—2009年>1970—1979年>1980—1989年=2010—2019年,且下垫面变化是1970—2019年流域出口径流变化的主导因素,对应的贡献率分别为94.58% (Budyko法)和65.68% (DHSVM法)。③ Budyko方法只能揭示流域整体的变化,而DHSVM方法能够体现水文过程变化的时空差异,模型结果表明上中游、下游地区的年平均径流变化分别受气候变化、下垫面变化主导;流域出口处月径流变化则对下垫面条件中的水库调节更敏感。此外,文中就2种方法量化结果差异的原因也展开了讨论。