Petrogenesis of graphitic cherts in the Armorican segment of the Cadomian orogenic belt (NW France)

Graphitic cherts are interbedded within terrigenous sediments in the Cadomian orogenic belt of end-Proterozoic age. In the Armorican Massif (NW France), the graphitic cherts are of two types: massive cherts essentially composed of quartz (SiO₂ > 96%) and with rare sedimentary structures; laminated cherts containing up to 3·4% Al₂O₃ and 92–98% SiO₂. Sedimentary structures observed in the laminated cherts are indicative of a restricted hypersaline tidal or supratidal environment. The origins of both types of chert are to be found in the diagenetic processes of silification of terrigenous and mixed terrigenous-evaporitic facies. These processes, which could be mediated by the presence of organic matter, were controlled by the migration of the freshwater/saltwater mixing zone during periods of relative sea-level change. The proposed diagenetic origin for the cherts places a number of constraints on their use in the establishment of stratigraphic correlations.     

胶辽地块古元古代沉积组合：年代与层序

根据变质岩石组合、成矿特征等方面对比研究，证明胶辽地块古元古代粉子山群、北部辽河群、老岭群可对比，荆山群和南部辽河群、集安群亦可以比，相应的北部和南部变质地层为同时异相。通过对各群同位素年代学资料的收集总结，表明它们沉积于2．5至1．9Ga期间，变质作用起始于2．2Ga，终止于正．6Ga。以辽河群为例，各岩组的原岩恢复及沉积环境讨论，表明整个裂陷带经历了从裂谷盆地向被动大陆边缘转化。最后于该活动带南缘转变为活动大陆边缘的，反映了该活动带完整的层序沉积环境变迁过程。     

Phase equilibria modelling of retrograde amphibole and clinozoisite in mafic eclogite from the Tso Morari massif,northwest India: constraining the P–T–M(H2O) conditions of exhumation

Phase equilibria modelling of post‐peak metamorphic mineral assemblages in (ultra)high‐P mafic eclogite from the Tso Morari massif, Ladakh Himalaya, northwest India, has provided new insights into the potential behaviour and source of metamorphic fluid during exhumation, and constrained the P–T conditions of hydration. A series of P–M(H₂O) pseudosections constructed in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (NCKFMASHTO) system show that a number of petrographically distinct hydration episodes occurred during exhumation from peak P–T conditions (~640 °C, 27–28 kbar), resulting in the formation of abundant compositionally zoned amphibole and minor clinozoisite poikiloblasts at the expense of a peak assemblage dominated by garnet and omphacite. Initial hydration is interpreted to have occurred as a result of the destabilization of talc following isothermal decompression to ~23 kbar, which led to the formation of barroisite–winchite amphibole core domains. An episode of fluid infiltration from an external source at ~19 kbar, with or without syn‐decompressional cooling to ~560 °C, resulted in further barroisitic–winchitic amphibole growth, followed by the formation of clinozoisite poikiloblasts. Continued buoyancy‐driven exhumation to the base of the lower crust is constrained to have taken place with no additional fluid input. A final hydration event is characterized by the formation of magnesiohornblende rims on the barroisite–winchite cores, with the former interpreted to have formed during later prograde overprinting in the middle crust associated with the final stages of exhumation. Notably, the vast majority of externally sourced H₂O, comprising just over half of the current bulk rock fluid content, was added during this later hydration event. In a middle crustal setting, this is interpreted as the result of devolatilization reactions occurring in migmatitic host orthogneiss and/or metasedimentary units, or following the crystallization of partial melt.     

甘肃北山旧井岩体BS03号钻孔岩石地球化学特征

文章对旧井岩体BS03号钻孔的岩石学、岩石化学以及同位素地球化学特征等进行了研究。结果表明:BS03号钻孔所见的主要岩石类型为似斑状二长花岗岩,其次为英云闪长岩、石英闪长岩及中粗粒花岗岩、伟晶岩、细晶岩等。似斑状二长花岗岩、黑云母花岗岩以及英云闪长岩的铝碱指数(ASI)为1.0左右,均为准铝质;而石英闪长岩的铝碱指数(ASI)仅为0.66~0.68,表现为明显的铝不饱和。上述各类岩石均表现为I型花岗岩的稀土配分曲线特征,且其稀土配分曲线总体较为相似,说明它们之间具有一定的成因联系。Nd、Sr同位素地质特征揭示:该区花岗岩的成岩物质来源于下地壳,并可能有上地幔物质的介入。     

Remobilisation of deep Na-Cl waters by a regional flow system in the Alps: Case study of Saint-Gervais-les-Bains (France)

The hydrothermal system of Saint-Gervais-les-Bains, France is located in a south western low-elevation point of the Aiguilles Rouges crystalline Massif. The crystalline rocks are not directly outcropping in the studied area but certainly exist beyond 300 m depth. Uprising waters are pumped from two different aquifers below the Quaternary deposits of the Bon Nant Valley. In the Lower Trias-Permian aquifer crossed by De Mey boreholes (27–36 °C), the ascending Na-SO₄ and high-Cl thermal water from the basement (4.8 g/L) is mostly mixed by a Ca-SO₄ and low-Cl cold water circulating in the autochthonous cover of the Aiguilles Rouges Basement. The origin of the saline thermal water probably results from infiltration and circulation in the basement until it reaches deep thrust faults with leaching of residual brines or fluid inclusions at depth (Cl/Br molar ratio lower than 655). The dissolution of Triassic halite (Cl/Br > 1000) is not possible at Saint-Gervais-les-Bains because the Triassic cold waters have a low-Cl concentration (< 20 mg/L). Water–rock interactions occur during the upflow via north–south strike-slip faults in the basement and later on in the autochthonous cover. For the De Mey Est borehole, gypsum dissolution is occurring with cationic exchanges involving Na, as well as low-temperature Mg dissolution from dolomite in the Triassic formations. The aquifer of imbricated structures (Upper-Middle Trias) crossed by the Lépinay well (39 °C) contains thermal waters, which are strongly mixed with a low-Cl water, where gypsum dissolution also occurs. The infiltration area for the thermal end-member is in the range 1700–2100 m, close to the Lavey-les-Bains hydrothermal system corresponding to the Aiguilles Rouges Massif. For the Ca-SO₄ and low-Cl end-member, the infiltration area is lower (1100–1300 m) showing circulation from the Mont Joly Massif. The geothermometry method indicates a reservoir temperature of probably up to 65 °C but not exceeding 100 °C.     

Genetic Implications of Two Different Ultramafic Rocks from Hongseong Area in the Southwestern Gyeonggi Massif, South Korea

Two distinct ultramafic bodies occur in Baekdong and Bibong in the Hongseong area within Gyeonggi massif of South Korea. The Hongseong area is now extensively documented as an extension of the Dabie-Sulu collision belt in China. The Baekdong ultramafic body has a NWW elongation direction. This elongation trend is similar to the general trend of the Dabie-Sulu collision belt. The Bibong ultramafic body is elongated in a NNE direction and runs parallel to the direction of the main fault in the study area. The Baekdong ultramafic bodies show porphyroclastic and mylonitic textures while those at Bibong exhibit a mosaic texture. Both were grouped into peridotite and serpentinite based on their modal abundance of serpentine. In the olivine (Fo) vs. spinel [Cr# = Cr/ (Cr+Al)] diagram, both ultramafic rocks fall with in olivine spinel mantle array. The compositions of olivine, orthopyroxene and spinel indicate that the Baekdong ultramafic rock formed in deeper parts of the upper-mantle under passive margin tectonic setting. The SREE content of Baekdong ultramafic rock vary from 0.19 to 5.7, exhibits a flat REE pattern in the chondrite-normalized diagram, and underwent 5% partial melting. Conversely, large variation in SREE (0.5 21.53) was observed for Bibong ultramafic rocks with an enrichment of LREE with a negative slope and underwent 17 24% partial melting. The Baekdong ultramafic rocks experienced three stages of metamorphism after a high pressure residual mantle stage. The first stage of metamorphism occurred under the eclogite-granulite transitional facies (1123 911°C, >16.3 kb) the second under the granulite facies (825 740°C, 16.3 11.8 kb) and the third is the retrogressive metamorphism under amphibolite facies (782 718°C, 8.2 8.7 kb) metamorphism. The Baekdong ultramafic rocks had undergone high-P/T metamorphism during subduction of the South China Block, and experienced a fast isothermal uplift, and finally cooled down isobarically. Evidences for metamorphism were not identified in Bibong ultramafic rocks. Hence, the Baekdong ultramafic rocks with in the Hongseong area may indicate a link on the Korean counterpart of Dabie-Sulu collision belt between North and South China Blocks.     

Fine structure of seismotectonics in western Shillong massif,north east India

The epicentral tract of the great Assam earthquake of 1897 of magnitude 8·7 was monitored for about 6 months using an array of portable seismographs. The observed seismicity pattern shows several diversely-oriented linear trends, some of which either encompass or parallel known geological faults. A vast majority of the recorded micro-earthquakes had estimated focal depths between 8–14 km. The maximum estimated depth was 45 km. On the basis of a seismic velocity model for the region reported recently and these depth estimates we suggest that the rupture zone of the great 1897 earthquake had a depth of 11–12 km under the western half of the Shillong massif. Four composite fault plane solutions define the nature of dislocation in three of the seismic zones. Three of them show oblique thrusting while one shows pure dip slip reverse faulting. The fault plane solutions fit into a regional pattern of a belt of earthquakes extending in NW-SE direction across the north eastern corner of the Bengal basin. The maximum principle stress axis is approximately NS for all the solutions in conformity with the inferred direction of the Indian-EuroAsian plate convergence in the eastern Himalaya.     

佳木斯地块南缘牡丹江地区高压变质作用：黑龙江杂岩的岩石学和地质年代学

牡丹江地区出露的黑龙江杂岩是由变质基性岩、泥质片岩、大理岩和变硅质岩系列组成的类似于蛇绿岩层序的构造混杂岩,代表了佳木斯地块西南缘碰撞增生的产物。钠长石和绿帘石变斑晶中共生的矿物组合(钠云母+蓝闪石+多硅白云母+绿帘石)的地质温压计估算结果表明,黑龙江杂岩的峰期变质的温压条件为 T=320~480℃, p=800~1600MPa,为典型的绿帘-蓝片岩相高压变质作用。黑龙江杂岩带中泥质片岩所含的多硅白云母单矿物给出的40Ar/39Ar坪年龄为164.9Ma±0.5Ma。根据白云母中K-Ar同位素体系的封闭温度(350~430℃)接近于得到的黑龙江杂岩的峰期变质温度,可以认为40Ar/39Ar坪年龄指示了这期高压变质事件的年龄,也证实了黑龙江杂岩带中普遍存在一期中侏罗世末期的变质-热事件。     

鄂尔多斯地块早古生代构造格局及演化

本文通过沉积、构造和沉降历史的综合分析，揭示了鄂尔多斯早古生代碳酸盐岩台地演化历史，恢复了不同演化阶段的古构造格局，并探讨了古构造的演化机制。     

Coesite inclusions and prograde compositional zonation of garnet in whiteschist of the HP-UHPM Kokchetav massif, Kazakhstan: a record of progressive UHP metamorphism

Coarse-grained whiteschist, containing the assemblage: garnet+kyanite+phengite+talc+quartz/coesite, is an abundant constituent of the ultrahigh-pressure metamorphic (UHPM) belt in the Kulet region of the Kokchetav massif of Kazakhstan.

Garnet displays prograde compositional zonation, with decreasing spessartine and increasing pyrope components, from core to rim. Cores were recrystallized at T=380°C (inner) to 580°C (outer) at P<10 kbar (garnet–ilmenite geothermometry, margarite+quartz stability), and mantles at T=720–760°C and P_H20=34–36 kbar (coesite+graphite stability, phengite geobarometer, KFMASH system reaction equilibria). Textural evidence indicates that rims grew during decompression and cooling, within the Qtz-stability field.

Silica inclusions (quartz and/or coesite) of various textural types within garnets display a systematic zonal distribution. Cores contain abundant inclusions of euhedral quartz (type 1 inclusions). Inner mantle regions contain inclusions of polycrystalline quartz pseudomorphs after coesite (type 2), with minute dusty micro-inclusions of chlorite, and more rarely, talc and kyanite in their cores; intense radial and concentric fractures are well developed in the garnet. Intermediate mantle regions contain bimineralic inclusions with coesite cores and palisade quartz rims (type 3), which are also surrounded by radial fractures. Subhedral inclusions of pure coesite without quartz overgrowths or radial fractures (type 4) occur in the outer part of the mantle. Garnet rims are silica-inclusion-free.

Type 1 inclusions in garnet cores represent the low-P, low-T precursor stage to UHPM recrystallization, and attest to the persistence of low-P assemblages in the coesite-stability field. Coesites in inclusion types 2, 3, and 4 are interpreted to have sequentially crystallized by net transfer reaction (kyanite+talc=garnet+coesite+H₂O), and were sequestered within the garnet with progressively decreasing amounts of intragranular aqueous fluid.

During the retrograde evolution of the rock, all three inclusion types diverged from the host garnet P–T path at the coesite–quartz equilibrium, and followed a trajectory parallel to the equilibrium boundary resulting in inclusion overpressure. Coesite in type 2 inclusions suffered rapid intragranular H₂O-catalysed transformation to quartz, and ruptured the host garnet at about 600°C (when inclusion P27 kbar, garnet host P9 kbar). Instantaneous decompression to the host garnet P–T path, passed through the kyanite+talc=chlorite+quartz reaction equilibrium, resulting in the dusty micro-assemblage in inclusion cores. Type 3 inclusions suffered a lower volumetric proportion transformation to quartz at the coesite–quartz equilibrium, and finally underwent rupture and decompression when T<400°C, facilitating coesite preservation. Type 4 coesite inclusions are interpreted to have suffered minimal transformation to quartz and proceeded to surface temperature conditions along or near the coesite–quartz equilibrium boundary.