Morphological and speleothemic development in Brujas Cave (Southern Andean Range, Argentine): palaeoenvironmental significance

Brujas Cave, in the Southern Andean Range, is a well-known endokarstic site in Argentina. However, the origin and evolution of this cave system are poorly known. Based on morphological cave features as well as characteristics of cave deposits, we propose a meteogene drawdown cave genesis, including a change from phreatic to vadose conditions related to the high rate of fluvial downcutting in the area. During the vadose period, various cave-related deposits, including authogenic calcite and gypsum speleothems, allogenic volcanic ash and external tufas were deposited. Gypsum crusts are the oldest cave deposits identified (90.2–64.3 ky BP). Their origin, deduced from isotopic characteristics (∂³⁴S=9.6‰), is related to the oxidation of pyrite contained in the Jurassic limestone bedrock as well as the dissolution of overlying Jurassic–Triassic evaporite formations. Gypsum crust deposition is associated with evaporation of water flowing and seeping into the cave during arid environmental conditions. Calcite deposits precipitated from flowing water under equilibrium conditions represent the main speleothem growth period (67.6–34 ky BP in age). Their stable isotope values (∂¹³C=−3‰ to −5‰ and ∂¹⁸O=−9‰ to −11‰) may indicate slightly humid and warm conditions related to the regional Minchin lacustrine phase and global oxygen isotope stage 3. Following this stage, a seismic event is evidenced by accumulations of broken stalactites. Seepage calcite speleothems covering cave walls were deposited under disequilibrium conditions by evaporation, probably during Holocene time. Finally, another more recent gypsum deposition period represented by gypsum balls has been differentiated. Micromorphological as well as isotopic (∂³⁴S=5.6‰) data indicate that these gypsum forms are related to cyclic processes (solution–deposition) from water seeping into the cave under arid conditions. In addition, intense volcanic activity in the area during Holocene time is deduced from allogenic volcanic ash and lapilli located mainly at the entrance cave. At present, limited hydrological activity is observed in the cave and small tufa deposits at karstic discharge points are evidenced. We conclude that the geomorphological evolution of Brujas Cave was controlled by climatic changes (wet and dry stages) under semiarid environmental conditions in a very active tectonic and volcanic setting during Late Quaternary time.     

Early Callovian ingression in southwestern Gondwana. Palaeoenvironmental evolution of the carbonate ramp (Calabozo Formation) in southwestern Mendoza,Neuquen basin,Argentina

The carbonatic sequence of the Calabozo Formation (Lower Callovian) developed in southwestern Gondwana, within the northern area of the Neuquén basin, and is widespread in thin isolated outcrops in southwestern Mendoza province, Argentina. This paper describes the facies, microfacies and geochemical-isotopic analysis carried out in five studied localities, which allowed to define the paleoenvironmental conditions of a homoclinal shallow ramp model, highly influenced by sea level fluctuations, where outer, mid and inner ramp subenvironments were identified. The outer ramp subenvironment was only recognized in the south of the depocenter and is characterized by proximal outer ramp facies with shale levels and interbedded mudstone and packstone layers. The mid ramp subenvironment is formed by low energy facies (wackestone) affected by storms (packstones, grainstones and floatstones). The inner ramp subenvironment is the most predominant and is characterized by tidal flat facies (wackestones, packstones and grainstones) over which a complex of shoals (grainstones and packstones) dissected by tidal channels (packstone, grainstones and floatstones) developed. In the north area, protected environment facies were recorded (bioturbated wackestones and packstones). The vertical distribution of facies indicates that the paleoenvironmental evolution of the Calabozo Formation results from a highstand stage in the depocenter, culminating in a supratidal environment, with stromatolitic levels interbedded with anhydrite originated under restricted water circulation conditions due to a progressive isolation of the basin. δ¹³C and δ¹⁸O values of the carbonates of the Calabozo Formation suggest an isotopic signature influenced by local palaeoenvironmental parameters and diagenetic overprints. The δ¹³C and δ¹⁸O oscillations between the carbonates of the different studied sections are related with lateral facies variations within the carbonate ramp accompanied with dissimilar reactivities in relation to diagenetic fluids. The δ¹⁸O values of all sections exhibit a rather broad scatter which may be attributed to diagenesis and recrystallisation while the carbon isotopic composition has been less affected by those processes. Carbon isotope system has best retained the primary isotopic signal and δ¹³C values (0–3.9‰) are within the Callovian isotope range. The ⁸⁷Sr/⁸⁶Sr ratios of the bulk carbonates of El Plomo creek, La Vaina creek and Potimalal River sections are in agreement with the Callovian seawater Sr-isotope curve.     

Unraveling multiple provenance areas using sandstone petrofacies and geochemistry: An example in the southern flank of the Golfo San Jorge Basin (Patagonia,Argentina)

The aim of this paper is to study the provenance of Late Cretaceous sandstones deposited along the south flank of the Golfo San Jorge Basin. For this purpose, detrital modes of three hundred thirty-seven sandstone samples collected in the Mina del Carmen, Bajo Barreal, and Cañadón Seco Formations were studied in ten oil fields. According to the modal composition of the sandstones, six petrofacies were defined allowing the identification of not only principal, but also secondary provenance areas. The QVM and VQM petrofacies are more than 20% metamorphic, sedimentary, and polycrystalline quartz clasts (Lm + Ls + Qpg > 20%), evidencing a secondary signal of basement supply masked by a predominant volcanic provenance. The petrofacies VP and VF are characterized by Lm + Ls + Qpg <20% and more than 20% total feldspar (Pm + Om >20%.), which indicate a supply of sediment from volcanic terrains and scarce derivation of materials from basement rocks. Based on the plagioclase/k-feldspar ratio, the VF petrofacies is interpreted to be dominated by the supply of sand grains from the Andean volcanic-arc, while VP is supposed have originated through the erosion of intermediate volcanic rock outcroppings in the Macizo del Deseado. Finally, both the VQ and QV petrofacies show Lm + Ls + Qpg <20% and Pm + Om<20%, indicating a provenance of volcanic areas coupled with minor contributions from basement rocks. During the Late Cretaceous, the Golfo San Jorge Basin underwent a sag phase that was characterized by very scarce volcanism and tectonic activity. Although these conditions did not favor defined patterns in the vertical stacking of petrofacies, the sandstones exhibit remarkable changes in their regional distribution, which were determined by the paleogeography of the basin and differences in basement composition within the source areas. Finally, a paleogeographic model for sediment circulation in the basin is proposed. This model recognizes the main fluvial dispersal trends that flowed northwest to southeast and transported large amounts of volcanic clasts (associated with petrofacies VF-VQ). To the extent that rivers flowed eastward, a secondary supply from the Precambrian basement, which were composed of low-to high-grade metamorphic rocks, was also important (petrofacies association VQM and QVM). The southwestern area of the basin is dominated by VP petrofacies that record the supply of plagioclase-rich volcanic clasts. This petrofacies likely corresponds to the erosion of Jurassic volcanic units that crop out in the Macizo del Deseado.     

Quaternary intraplate deformation in the southeastern Sierras Pampeanas, Argentina

Neogene strain from the subducting Nazca plate is widely distributed in theAndean foreland as a result of flat-lying subduction beneath central westernArgentina (28^°–33^°S latitude). This fact is indicated byuplifted basement blocks bounded by reverse faults as far as 600 kms eastof the Chilean trench axis. Some deformation in the southern Sierras deCórdoba (southeastern Sierras Pampeanas) indicates significantdisplacements during Quaternary and even late Holocene time. Thisregion has low to moderate seismicity characterized by earthquakemagnitudes 6.7 with no associated noticeable surface ruptures.This paper presents information recently gathered on the most conspicuousregional structures of the area (El Molino, Sierra Chica and Las Lagunasfaults). The last movement along the El Molino fault thrust basement rocksover organic-rich (0.8–1.3 ka) sediment and fault relationships suggestprevious Quaternary displacements. Along the Sierra Chica fault,Precambrian basement has been thrust a minimum of 13.5 m overPleistocene conglomerates, and faulting also affects latePleistocene-Holocene fluvial sediments. The Las Lagunas fault has beenregarded as the source of the 1934 Ms 5.5 and 6.0 earthquakes, whichheavily damaged the nearby village of Sampacho. The faulted surface isburied under Holocene loess, but its trace is expressed as a 24-km-longrectilinear scarp, despite continuous modification due to land use.Although we lack detailed information on probable rupture lengths duringlarge Sierras Pampeanas thrust earthquakes, some preliminary considerationsare made for the regional seismic hazard of these structures. The geologicevidence described here identifies these faults as possible sources of strongearthquakes in the future.     

Provenance and Evolution of the Guarguariiz Complex, Cordillera Frontal, Argentina

The Guarguardz Complex, basement of the Cordillera Frontal, included in the proposed Chilenia Terrane, consists of metasedimentary rocks deposited in clastic and carbonatic platforms. Turbiditic sequences point out to slope or external platform environments. According to geochemical data, the sedimentary protoliths derived through erosion of a mature cratonic continental basement. Volcanic and subvolcanic rocks with N and E-MORB signature were interbeded in the metasedimentary rocks during basin development. A compressional stage, starting with progressive deformation and metamorphism, followed this extensional stage. Continuing deformation led to the emplacement of slices of oceanic crust, conforming an accretionary prism during Late Devonian. The Guarguardz Complex and equivalent units in western Precordillera and also in the Chilean Coastal Cordillera share common evolutional stages, widely represented along the western Gondwana margin. These evidences imply that Chilenia is not an allochthonous terrane to Gondwana, but a portion of its Early Paleozoic margin. Regional configuration indicates that the Guarguardz Complex and equivalent units represent the accretionary prism of the Famatinian arc (Middle Ordovician-Late Devonian).     

Taxonomy and paleoecology of a new gastropod fauna from dysoxic outer ramp facies of the Lower Cretaceous Agrio Formation,Neuquén Basin,west-central Argentina

Four gastropod species are described from dysaerobic biofacies of the lower part of the Agua de la Mula Member of the Agrio Formation, Neuquén Basin: Metacerithium turriculatum (Forbes, 1845), Nerineopsis acutecarinatum (Behrendsen, 1891) and the new species Ampullina pichinka and Mesalia? kushea. They were active epifaunals and possibly deposit-feeders and/or browsers, and epifaunal to semi-infaunal possibly suspension- or deposit-feeder in the case of M.? kushea, thriving in soft to firm substrates. These gastropods, together with two aporrhaid species, are the dominant components of a typically small-sized, low-diversity macrobenthic fauna that occurs in dark, organic-rich shales. The facies in which this fauna is recorded are thought to represent a transition from lower to upper outer ramp marine settings, in the context of a second-order TST and early stages of a HST. They record a transition from lower dysoxic conditions in the lowest part of the Agua de la Mula Member to upper dysoxic conditions upwards. Two distinct gastropod biofacies were recognized corresponding to the two identified stages: biofacies A, dominated by Protohemichenopus neuquensis and N. acutecarinatum, more tolerant to dysoxic conditions, and biofacies B, dominated by M. turriculatum and Mesalia? kushea, less tolerant to oxygen deficiency.     

Archosauriform remains from the Late Triassic of San Luis province,Argentina, Quebrada del Barro Formation,Marayes–El Carrizal Basin

Here we present archosauriform remains from ‘Abra de los Colorados’, a fossiliferous locality at Sierra de Guayaguas, NW San Luis Province. Two fossiliferous levels were identified in outcrops of the Quebrada del Barro Formation (Norian), which represent the southernmost outcrops of the Marayes–El Carrizal Basin. These levels are composed by massive muddy lithofacies, interpreted as floodplain deposits. The specimens consist of one incomplete maxilla (MIC-V718), one caudal vertebra (MIC-V719), one metatarsal (MIC-V720) and one indeterminate appendicular bone (MIC-V721). The materials can be assigned to Archosauriformes but the fragmentary nature and lack of unambiguous synapomorphies preclude a more precise taxomic assignment. The maxilla is remarkably large and robust and represents the posterior process. It preserved one partially erupted tooth with ziphodont morphology. This bone shows some anatomical traits and size match with ‘rauisuchians’ and theropods. MIC-V719 corresponds to a proximal caudal vertebra. It has a high centrum, a ventral longitudinal furrow, expanded articular processes for the chevrons, a posteriorly displaced diapophysis located below the level of the prezygapophyses, and short prezygapophyses. This vertebra would be from an indeterminate archosauriform. MIC-V720 presents a cylindrical diaphysis, with a well-developed distal trochlea, which present resemblances with metatarsals of theropods, pseudosuchians, and silesaurids, although the size matches better with theropods. MIC-V721 has a slender diaphysis and a convex triangular articular surface, and corresponds to an indeterminate archosauriform. Despite being fragmentary, these materials indicate the presence of a diverse archosauriforms association from Late Triassic beds of San Luis. Thus, they add to the faunal assemblage recently reported from this basin at San Juan Province, which is much rich and diverse than the coeval paleofauna well known from Los Colorados Formation in the Ischigualasto–Villa Union Basin.     

Thermochronological constraints of the exhumation and uplift of the Sierra de Pie de Palo,NW Argentina

The Sierra de Pie de Palo located between 67°30′–68°30′ W and 31°00′–32°00′ S in the Argentine Western Sierras Pampeanas in Argentina is a distinct basement range, which lacks thermochronological data deciphering its exhumation and uplift history below 200 °C. Integrated cooling histories constrained by apatite fission-track data as well as (U–Th)/He measurements of zircon and apatite reveal that the structural evolution of this mountain range commenced during the Late Paleozoic and was mainly controlled by tectonically triggered erosion. Following further erosional controlled exhumation in a more or less extensional regime during the Mesozoic, the modern topography was generated by denudation in the Paleogene during the early stage of the Andean deformation, whereupon deformation propagated towards the west since the Late Mesozoic to Paleogene. This evolution is characterised by a total of 3.7–4.2 km vertical rock uplift and by 1.7–2.2 km exhumation with a rate of 0.03–0.04 mm/a within the Sierra de Pie de Palo since ca. 60 Ma. Onset of uplift of peak level is also referred to that time resulting in a less Pliocene amount of uplift than previously assumed.     

Facies and Architecture of a Carboniferous Grounding-line System From the Guandacol Formation, Paganzo Basin, Northwestern Argentina

New outcrops of Middle Carboniferous glacigenic deposits found in the Guandacol Formation (western Paganzo Basin) are described in this paper. The study locality of Los Pozuelos Creek (northwestern Argentina) includes coarse-grained diamictites, rhythmites, laminated pebbly mudstones and shales that represent an expanded column of the Gondwanic glaciation in this region. Thirteen lithofacies recorded at the measured section have been grouped into three facies associations. Facies Association I is composed of coarse-grained massive and stratified diamictites (lithofacies Dmm, Dms, Dmg, Dcs), laminated siltstones with dropstones (Fld) and interstratified sandstones and mudstones (Fl, Sr). These rocks represent both tillites and resedimented diamictites closely associated to small water bodies where laminated siltstones with dropstones and stratified sandstones and mudstones were deposited. Facies Association II comprises couplets of matrix-supported thinly bedded diamictites (Dmld) and laminated mudstones with dropstones (Fld). This facies association results from the combination of three different processes, subaqueous cohesionless debris flows, coeval rainout of ice-rafted debris and settling of fine-grained particles from supension. Finally, Facies Association III is made up of laminated mudstones without dropstones, thin marl levels and scarce fine- to very fine-grained sandstones. This assemblage clearly suggests sedimentation in a deep marine environment below the wave base.The architecture of the glacigenic deposits has been investigated using photomosaic panels. The geometry of the depositional bodies and facies suggest that Los Pozuelos Creek outcrops exhibit a well preserved three-dimensional example of a grounding-line system. In particular, three different subenvironments of a morainal bank were interpreted: a bank-front, a bank-core and a bank-back. The bank-front assemblage is characterized by coarse-grained, mainly resedimented, diamictites grading laterally to prograding clinoforms composed of interbedded matrix-supported thinly bedded diamictite and mudstones. The bank-core assemblage is formed by a stacking of coarse-grained diamictites where at least five major erosional surfaces, bounding four multistory diamictite bodies, can be recognized. Finally, the bank-back assemblage corresponds to discontinuous intervals of striated lodgement till, and coarse-grained resedimented diamictites showing important post-depositional deformation. The retrogradational stacking of the morainal banks indicate an overall glacial retreat and a glacioeustatic sea-level rise. Erosional surfaces at the base of each morainal bank suggest intervening short term episodes of ice advance.The new data presented here confirm the existence of "true" tillites in western Paganzo Basin and suggest several (at least four) pulses of glacial advance and retreat during the Namurian glaciation in the region and permit a more refined interpretation of the glacial deposits in the Huaco area.