不同粒度颗粒在非恒定管流中跟随性试验

管道中固液两相流水击对管道和输送系统可能产生严重的破坏,而固液两相在这种非恒定流中的运动特性是计算最大水击压力变化的重要依据。采用粒子图像测速技术（Particle Image Velocimetry,PIV）,通过试验研究水击发生时,水平圆管中不同平均流速、颗粒粒径条件下,流体介质和粗颗粒在管道断面的速度分布以及粗颗粒跟随性的变化规律。研究结果表明:①在水击发生的不同时刻,圆管流中粗颗粒的流速在管道断面分布呈不规则的抛物线型分布,主要表现为靠近管道壁面底部的颗粒流速略小于靠近管道顶部流速,当颗粒粒径大于1.5 mm,平均流速小于2.5 m/s时,粗颗粒表现出明显的沉降特性;②粗颗粒的跟随性与颗粒受力有密切关系,其中颗粒速度与流体速度的变化量是影响颗粒受力的重要参数;③基于试验数据拟合得到了水击条件下粗颗粒跟随性系数k的经验公式,并分析了颗粒粒径、管道直径、两相流平均流速以及水击发生时间等不同参数对粗颗粒跟随性系数的影响,公式计算值与实测值之间的误差在5%以内。     

涪陵页岩气田深层气井酸处理技术研究

涪陵页岩气田进入二期产建阶段,页岩气井埋深增加,压裂改造难度增大,尤其是在设备限压仅为93 MPa的前提下,深井施工压力高,酸降效果不明显,严重限制了后期各项改造措施的执行。通过分析深层页岩气井酸降效果降低的主要原因,并在此基础上通过室内及现场试验研究了影响酸处理效果的主要因素,试验表明：提高酸处理排量、增加酸液浓度、合理优化酸液用量将有助于提高酸处理效果,为涪陵页岩气田深层页岩气井后续的压裂施工提出了优化建议。     

短波红外光谱技术在矽卡岩型矿床中的应用——以鄂东南铜绿山铜铁金矿床为例

铜绿山铜铁金矿床是长江中下游铜铁多金属成矿带最重要的矽卡岩型矿床之一,矿床的形成与铜绿山石英闪长岩株体密切相关,矿体主要沿北北东向断裂产于石英闪长岩与大理岩/白云质大理岩的接触带,形成钙-镁复合型矽卡岩铜多金属矿化。围岩蚀变由致矿岩体到接触-蚀变矿化中心为:绢云母-绿泥石-钾化带、高岭石-绿泥石-弱矽卡岩化带、皂石-绿泥石-强矽卡岩化带。蚀变矿化期次可分为岩浆-热液期和表生期,其中,岩浆-热液期可分为矽卡岩阶段、退化蚀变阶段、氧化物阶段、硫化物阶段和碳酸盐阶段。绿泥石是钻孔岩芯中出现最多且分布最为广泛的蚀变矿物之一。经短波红外光谱(SWIR)研究发现,从蚀变矿化中心到外围,绿泥石出现由铁绿泥石/铁镁绿泥石逐渐转变为镁绿泥石,且绿泥石Fe-OH特征吸收峰位值(Pos2250)显示出从高值变为低值的趋势。结合其他蚀变矿物的空间分布特征,文章提出绿泥石的高Fe-OH特征吸收峰位值(Pos22502253 nm)与金云母、蛇纹石、绿帘石、皂石和高岭石的大量出现,对指示铜绿山矽卡岩型矿床的矿化中心具有一定的作用。     

金属矿地震绕射波分离与成像——以庐枞矿集区和钦杭成矿带为例

不同于油气藏能源大多产于沉积地层之中, 金属矿成矿部位的地质条件要更为复杂多变。通常情况下矿体表现为不规则形状, 且连续性较差, 难以满足现有地震反射波法所以依据的镜面反射条件(徐明才等, 2009)。不同的围岩地震地质条件差异很大, 甚至同一种岩性受到蚀变、构造作用的影响, 表现出不同的阻抗特征, 当围岩与矿体间的波阻抗差异较小, 难以形成有效的反射波。在控矿构造方面, 通常大规模的构造对成矿具有控矿、控岩作用, 而与成矿部位密切相关的一般是小规模的断裂, 反射波较难识别。根据菲涅耳带理论, 当地质体的尺度小于地震波的一个波长时, 反射地震成像精度会骤降, 而来自这些小尺度、非均匀地质体产生的绕射波和散射波成像较反射波成像具有明显的高分辨率、甚至超高分辨率。利用绕射波成像能够探测和识别地下重要的构造信息, 如破碎带、断层、尖灭点、礁体边界、次火山岩、小尺度的侵入体、不规则盐丘体, 以及其他不连续的地质体(Karimpoul et al., 2015)。考虑金属矿围岩及控矿构造复杂, 矿体几何尺寸较小、形状不规则, 容易产生绕射波, 理论上利用地震绕射波识别这些地质体较反射波更具优势。     

表层岩溶地下水出露地表后的脱气作用——以重庆市南川区柏树湾表层岩溶泉溪流为例

以重庆市南川区柏树湾表层岩溶泉溪流为例,沿柏枝溪流程以一定间距监测水体中HCO3-的浓度及其pH、电导率、溶解氧等水化学参数,并初步探究溪流水的脱气效应。结果显示(1)表层岩溶地下水出露地表后,HCO3-浓度沿流程呈现出递减的规律;(2)HCO3-浓度递减的快慢反映了脱气作用的强弱,溪流脱气速率具有“枯水期>平水期>丰水期”的特点;(3)暴雨期间由于稀释效应HCO3-浓度递减趋势不明显,但降雨后期,递减又开始逐渐产生;(4)脱气效应在造成溪流水HCO3-浓度减小的同时,也导致电导率(EC)沿柏枝溪流程逐渐降低,而pH值逐渐升高;(5)沿途溶解氧(DO)昼夜变化表明,水生生物作用对脱气作用可能也有一定的影响,但其影响机制还有待进一步的研究。      

Determination of Trace Silver in Polymetallic Ore Samples by Flame Atomic Absorption Spectrometry after Solid‐Phase Extraction Using a Microcolumn Comprising Eggshell Membrane

A rapid and inexpensive method was developed for the determination of trace silver in polymetallic ore samples by use of eggshell membrane (ESM), a natural biomaterial, as the solid‐phase extraction (SPE) adsorbent coupled with flame atomic absorption spectrometry (FAAS). The ESM was used for the separation/pre‐concentration of silver, and the parameters affecting sensitivity, such as pH, sample flow rate, eluent volume and eluent flow rate, were carefully investigated. ESM was found to be an effective solid phase extractant for the adsorption of trace silver over a wide range of acidity from 0.02 to 0.50 mol l^?1 HNO₃. The sample solution in 0.4 mol l^?1 HNO₃ was pumped through an ESM microcolumn at the rate of 1.0 ml min^?1. Silver was absorbed, and then eluted with a solution of 1.0% m/v thiourea–0.5% v/v HCl. Under these optimal conditions, ESM exhibited a good enrichment efficiency for silver with a dynamic adsorption capacity of 1.7 mg g^?1. The proposed method was applied to the FAAS determination of trace silver in polymetallic ores and geological reference materials, GSO‐2, 3 and 5, and GSD‐11, GSD‐12, and the determined values were in good agreement with certified values.     

含沙量对草地坡面径流泥沙沉积和水力特性的影响

通过室内模拟试验,在坡度为3°和9°、流量为20和60L/min条件下研究了不同浓度(0～350kg/m3)含沙水流流经草地的泥沙沉积过程及其水力学特性。结果表明,坡面泥沙沉积量随含沙量的增加而增大,3°时泥沙沉积率与含沙量呈正相关,而9°时沉积率与含沙量呈反势。坡度对泥沙沉积影响显著,而在相同坡度条件下,两种流量试验的泥沙沉积量无明显差异。相同坡面坡上部位流速小于坡下部位,且含沙量对坡面流速影响较小。在相同坡度和流量条件下,水流雷诺数随含沙量的增大而减小。3°时水流阻力系数和曼宁糙率均随含沙量的增加而增大,而9°时含沙量对阻力影响不明显,因此在土壤侵蚀较严重地区进行坡面水文过程演算时需考虑含沙量对缓坡糙率的影响。     

矿产资源开发与泥石流灾害及其防治对策

由于掠夺式开采以及环境保护滞后于经济发展,我国矿产资源开发利用产生了比较严重的环境问题。本文在分析我国矿山人为泥石流灾害状况的基础上,提出了改善生态环境保护与重建的法治建设环境,加大矿山生态环境保护的监督管理力度,并具体提出了矿山人为泥石流灾害预防和工程治理的措施。     

Environmental pollution impact on water and sediments of Kumaun lakes, Lesser Himalaya, India: a comparative study

A study of the water and sediment chemistry of the Nainital, Bhimtal, Naukuchiyatal and Sattal Lakes of Kumaun, has shown that the water of these lakes are alkaline and that electrical conductivity, total dissolved solid and bicarbonate HCO ₃ ⁻ are much higher in Nainital than in the other three lakes. The weathering of limestone lithology and anthropogenic pollution, the latter due to the very high density of population in the Nainital valley, are the primary sources of enhanced parameters. The low pH of Nainital Lake water is due to low photosynthesis and enhanced respiration, increasing CO₂ in the water and the consequent enhancement of Ca²⁺ and HCO ₃ ⁻ . The dissolved oxygen in Nainital Lake is less compared to other lakes, indicating anoxic conditions developing at the mud–water interface at depth. The PO ₄ ³⁻ content in Nainital is higher (124 μg/l), showing an increasing trend over time leading to eutrophic conditions. The trace metals (Cu, Co, Zn, Ni, Mn, and Sr) are present in greater amounts in the water of Nainital Lake than in the other three lakes, though Fe and Cr are high in Bhimtal and Fe in Naukuchiyatal. The higher abundance is derived from the leaching of Fe–Mg from metavolcanic and metabasic rocks. Most of the heavy metals (Cr, Ni, Cu, Mn, Fe, Sr, and Zn) significantly enrich the suspended sediments of the lakes compared to the bed sediments which due to their adsorption on finer particles and owing to multiple hydroxide coating and organic content, except for Fe, which is enriched in the bed sediments. The high rate of sedimentation, 11.5 mm/year in Nainital, compared to Bhimtal with 4.70 mm/year, Naukuchiyatal with 3.72 mm/year, and Sattal with 2.99 mm/year, has resulted in shorter residence time, poor sorting of grains, and lesser adsorption of heavy metals, leading consequently, their depletion in the bed sediments of Nainital Lake.     

基于水体光学分类的鄱阳湖悬沙浓度反演方法研究

鄱阳湖是我国重要的湿地生态系统,对调节流域的水沙变化有着重要作用。由于鄱阳湖湖区面积广,内部差异大,单一的悬浮泥沙反演模型不足以准确反演出湖区的悬浮泥沙浓度。以实测的反射光谱数据、泥沙浓度数据为基础,提出一种基于分类后的反演模型,即根据实测数据的光谱形态特征分类出5种典型的水体类型。在此基础上,将分类后的各类水体分别建立各自合适的反演模型进行反演。结果表明基于水体分类的经验模型反演达到满意效果,平均绝对误差为0.00217g/L,平均相对误差为3.022%。基于分类后的经验反演模型适用于鄱阳湖悬沙浓度分布的监测研究,有助于更加宏观、准确的掌握鄱阳湖泥沙浓度的空间分布和变化,为保持鄱阳湖资源的可持续开发与利用提供决策依据。