The effects of the spinel—garnet phase transition on the formation of rifted sedimentary basins

We have examined the effects of the spinel-garnet phase transition on subsidence of extensional sedimentary basins. For a constant positive Clapeyron slope ( dP/dT ), the phase boundary moves downwards in the syn-rift and upwards in the post-rift phase. For a non-linear Clapeyron curve ( dP/dT > 0 above 900°C and dP/dT < 0 below 900°C), theory predicts for the reaction of the spinel-garnet phase transition, the direction of phase boundary movement is dependent on the stretching factor, the position of the Clapeyron curve and the lithospheric thickness. A smaller syn-rift and larger post-rift subsidence are predicted for a deeper phase boundary and a thicker lithosphere. The model with a non-linear Clapeyron curve is applied to the subsidence histories of a young extensional basin (Gulf of Lion) and an old continental margin (eastern Canada). The observed syn-rift uplift and the larger post-rift subsidence can be reasonably explained by this model, where the optimum depth of the phase boundary for eastern Canada (˜90 km) is consistent with the estimate from seismic observations and is larger than that for the Gulf of Lion (˜ 50 km). The depth of the spinel-garnet phase boundary is sensitive to the composition of mantle rocks and increases with the extraction of basaltic components from the lithosphere, compatible with our result that the phase boundary is deeper for an older and thicker lithosphere. Thus the surface movement associated with the rifting for these areas may reflect the chemical evolution of the continental lithosphere.     

流体的热力学前缘研究

总结了当前国内外关于流体的热力学前缘研究领域如下：（１）流体体系的ｐ－Ｖ－Ｔ－ｘ相关系研究，主要对象是Ｈ２Ｏ－ＣＯ２－盐类多组分体系高温高压下相图的实验和理论研究。（２）矿物在流体中的溶解度及溶解后在流体中溶解类型的形式和热力学性质——平衡常数（或Ｇｉｂｂｓ自由能）及各种偏摩尔性质的研究。（３）流体热力学模型化研究，已研制出大量的计算机软件，包括多种矿物、溶解类型的热力学数据库和模拟热液平衡、矿物溶解性质、反应路径和水—岩相互作用的实用程序。（４）超临界流体的相关系和化学反应等有许多特殊的性质，对认识地球内部的演化将有重要意义。（５）新技术新方法的发展，使分析单个矿物包裹体成分变成了现实。     

二维TIM中的传播矩阵与面波相速度

本文利用横向各向同性介质（ＴＩＭ）中的传播矩阵和面波形成条件，导出了面波波慢度方程。对瑞利波给出了各向同性及横向各向同性弹性介质中其相速度的解析解；对于勒夫波，给出了横向各向同性介质中的波慢度方程。     

钛（Ⅳ）的反相萃取柱色层新体系研究及应用

本文研究了以ｃＨＣｌ＝８ｍｏｌ·Ｌ－１盐酸为移动相，以聚四氟乙烯负载的钽试剂－ＣＨＣｌ３为固定相反相萃取层析钛（Ⅳ）的新体系，柱上层析的钛用ｃＨＣｌ＝３ｍｏｌ·Ｌ－１盐酸洗脱后经二安替比林甲烷光度法测定，不仅钛回收率可达１００％，并可使钛（Ⅳ）与多种离子分离。能用于矿物岩石类复杂样品及其他物质中钛的分离富集与测定，方法简便快速。     

应用Kriging方法研究格尔木河流域地下水位动态观测网的优化配置

地下水动态是水文地质研究的一个重要方面，如何获满足一定精度要求全面而合理的地下水位动态资料具有现实经济效益。本文研究格尔木河流域地下水位动态测网，通过选取理想的变差函，运有Ｋｒｉｇｉｎｇ方法进行地下水位的线性无偏最优估计和计算估计误差的标准差，结合给定的允许误差限评判地下水位动态观测网的配置是否合适，并提出调整现有观测网的方案     

人工合成宝石级翡翠的研究

本文以对化学试剂为原料，用静奇谈怪论同温高压固相转变法合成宝石级翡翠的机理和工艺条件进行了实验研究，测定了与硬玉化学组分相同的玻璃物质的高压熔融曲线和固相转变的区域，提出了在熔融曲线左侧附近固相区生长优质硬玉的观点，以及在宝石级悲翠合成中的若干技术问题。     

Aerosol polarized phase function and single-scattering albedo retrieved from ground-based measurements

Aerosol optical parameters, polarized phase function and single-scattering albdeo, have been retrieved from ground-based sun photometer measurements in Beijing 2003. The measured aerosol optical thickness varies from 0.12 to 0.77 with an average value of 0.39. The measured Ångström coefficient ranges from 0.75 to 1.47 with an average value of 1.21. The retrieved single-scattering albedo at 870 nm is within the 0.76–0.94 range and the average value is 0.85, suggests there are considerable aerosol absorptions in Beijing. The maximum value of retrieved polarized phase function at 870 nm ranges from 0.068 to 0.225 with an average value of 0.16, and it illustrates good correlations with the Ångström coefficient, i.e. the relative size of aerosol particles. Analyses of measurements and theoretical calculations show the polarized phase function is sensitive to aerosol size distribution and complex refractive index, especially the imaginary part of the refractive index which denotes aerosol light absorbing effects. These results suggest that the polarized phase function is an effective and unique aerosol optical parameter and is able to improve the retrieval of aerosol physical properties.