地气测量方法研究及应用

通过对不同介质地气的空白、样品的各种对比分析,基本上可以肯定:含有一定浓度的高纯的液体捕集介质在一定程度上对地气样品的捕集是有效的,并具有元素含量本底低、易操作、分析过程简单等优点;不同介质对地气中不同元素的捕获能力有差异,王水对Au、Ag、Cu、Zn等元素的捕获能力要强于硝酸,泡塑对金元素的吸附也有一定的优势。因此,在今后的实际工作中,可根据具体矿床类型,选择合适的介质或2种介质配合使用。     

第二松花江流域水电厂综合中长期水文预报的分析研究

基于对第二松花江流域上游小山、松山、两江水电站中长期水文预报研究成果，论述了综合中长期水文预报的研究思路和定性预报、定量预报的分析研究方法。该研究通过2002年实践检验，具有较高的预报精度。     

Optimisation de la quantification des flux de matière en suspension d'un cours d'eau alpin : l'Isère à Grenoble (France)

This study seeks to determine suspended-matter flux of the Isère at Grenoble, one of the most important rivers of the northern French Alps. Since 1994, and especially 1996, systematic samplings of the left bank make it possible to follow in one point the variations of suspended particles and matter (SPM) of this river. But from a single measurement, sometimes not very representative of the whole observable concentrations within the section, it remains still difficult to estimate precisely the SPM flux. The results of this study show in particular the successive appearance of several turbidity gradients, whose occurrence is explained mainly by the hydrological and hydro-sedimentary dynamics of this river. The estimate of these gradients thus makes it possible to extrapolate specific measurements more easily and consequently to daily define the quantities of suspended matter exported by the Isère. Since 1996, the results show a very high flow, specific of the Isère at Grenoble, variable between 124 and more than 460 t km^?2 yr^?1. To cite this article: D. Dumas, C. R. Geoscience 336 (2004).     

Mise au point d'un milieu de culture pour l'étude de l'altération de silicates en présence de Pseudomonas aeruginosa

The influence of microorganisms on mineral alteration is not easy to determine in environmental conditions, because of the difficulty to raise for comparison purposes an identical but abiotic system. Another problem in this context is the choice of reliable tracers to evaluate the alteration rate of materials during in vitro experiments. To face such difficulties, we elaborated a defined medium allowing both the growth of Pseudomonas aeruginosa and a precise measurement of the elements solubilized from the minerals. Thanks to this medium, we were able to quantitatively determine the amounts of major elements solubilized from the materials in the presence of bacterial growth, compared to a sterile system. Moreover, the analysis by ICP-MS of trace elements was possible after a chromatographic treatment, which selectively eliminated 99% of the sodium content of the medium. To cite this article: G. Aouad et al., C. R. Geoscience 337 (2005).     

Mechanical transitional behavior of binary mixtures via DEM: Effect of differences in contact-type friction coefficients

This report presents a numerical investigation of the shear behavior of binary mixtures via a two-dimensional discrete element method. The effect of the coarse particle content on the peak shear strength of mixtures is investigated for different contact-type friction coefficients. A detailed analysis on the anisotropies enables us to understand the microscopic mechanisms that result in the dependency of the peak shear strengths on the coarse particle content. The contributions of different contact types to the peak shear strength are quantified. Lastly, the inter-particles structures are examined when the binary mixtures become coarse-particle-supported structures.     

BDS中长距离非差实时动态厘米级定位算法

针对BDS常规实时动态定位(RTK)中,随着流动站与参考站间的距离增加,大气延迟误差的空间相关性大大降低,影响了整周模糊度的快速解算和流动站位置信息的解算精度问题。该文研究了一种基于非差观测误差的BDS中长距离常规RTK定位算法,采用非差误差改正方法为流动站提供误差改正,利用参考站的非差误差改正数以单颗卫星为对象进行误差改正。对电离层延迟误差和相对天顶对流层延迟误差进行参数估计,处理电离层延迟误差和对流层延迟误差的影响。最后通过BDS实测数据对该算法进行了算法验证和结果分析。实验结果表明,该算法可以实现BDS中长距离常规RTK的快速定位,并获得厘米级定位精度。     

强壮前沟藻(Amphidinium carterae Hulbert)在多重逆境条件下的生长和生理响应

尽管单一逆境条件对浮游植物产生的影响已被广泛重视,然而对于多重逆境条件对藻细胞生长生理的研究仍有空白。本研究通过测定强壮前沟藻(Amphidinium carterae Hulbert)光密度(OD750)、叶绿素a含量(chl a)、光合作用效率(F_v/F_m)、碳氮比(C/N)等多个生理指标,分析其在9种环境下(常温光照、低温和低温黑暗三种物理环境,结合全营养、缺氮、缺磷三种营养状态)对多重逆境的生长和生理响应。研究结果表明,在多重逆境条件下,单一物理逆境因素(低温或黑暗)较氮限制或磷限制对藻细胞生长和生理的不利影响更为显著。营养限制并同低温环境双重作用对生物量和碳氮比产生显著性影响(P0.01)。此外,低温和黑暗条件耦合作用下,SYTOX Green染色强度处于较低水平,chl a稳定、F_v/F_m有所升高,强壮前沟藻在逆境环境下作为群体的衰亡得以缓解。     

基于五种油源的中重度风化溢油的常规鉴定指标的应用效果评估

本文利用采集于我国三大油田的五种原油样品开展了长达210天的溢油风化模拟实验,并依据相对偏差和重复性限数学分析法,进行溢油风化过程分析和诊断比值应用效果评估。研究结果表明:经过210天的风化,溢油鉴定诊断比值发生明显改变;其中来源于萜烷、甾烷和多环芳烃的诊断比值变化率要远低于正构烷烃,可用于中长期风化溢油鉴定。此外,研究发现,在这些有效诊断比值中有4个变化率较小,相对偏差低于5%,保持了较好的稳定性,更适合于重度风化溢油鉴定。     

TTI介质拟声波方程数值模拟

TTI介质qP波数值模拟方法因为考虑了倾角因素,可以比VTI介质qP波数值模拟方法更加准确地描述各向异性介质中地震波场的传播规律。文中用拟声波方程对TTI介质中的地震波场进行了高阶有限差分数值模拟,在改进衰减函数分布方式后,通过坐标变换,利用改进的完全匹配层(perfectly matched layer,PML)边界控制方程对波场边界进行吸收处理,取得了良好的效果;然后分析了拟声波方程数值模拟中的稳定性问题,并对波场中的伪横波进行压制。通过对不同模型的数值模拟,验证了文中使用的TTI介质拟声波波动方程的稳定性以及所采用的PML边界控制方程的可靠性和适用性。     

Comparative Study of Hydrogen and Carbon Isotopic Composition of Gases Generated from the Pyrolysis of a Peat under Saltwater and Freshwater Conditions

To understand the influence of the diagenetic water medium on the isotopic compositions of thermogenic coalbed gas, both hydrous and anhydrous closed-system pyrolyses were performed at temperatures of 250°C to 650°C on an herbaceous marsh peat. Compared to the results of anhydrous pyrolysis, the hydrocarbon gases generated from hydrous pyrolyses have very different hydrogen isotopic compositions. However, the carbon isotopic compositions of the hydrocarbon gases became only slightly heavier in hydrous pyrolysis, compared to that from anhydrous pyrolysis. With the progress of thermal evolution from peat to a more advanced thermal maturity of vitrinite reflectance values (Ro) of 5.5% during the pyrolysis, the difference in the average δD value increased from 52‰ to 64‰ between the hydrous pyrolysis with saltwater and anhydrous pyrolysis and increased from 18‰ to 29‰ between the hydrous pyrolysis with freshwater and anhydrous pyrolysis, respectively. The difference in the average δ13C value was only 1‰–2‰ between the hydrous and anhydrous pyrolysis. The relationships between the δD values of the generated hydrocarbon gases and Ro values as well as among δD values of the hydrocarbon gas species are established. The close relationships among these parameters suggest that the water medium had a significant effect on the hydrogen isotopic composition and a minimal effect on the carbon isotopic composition of the hydrocarbon gases. The results of these pyrolyses may provide information for the understanding of the genesis of coalbed gas from herbaceous marsh material with the participation of different diagenetic water media.