Comparison of alternative upscaled model formulations for simulating DNAPL source dissolution and biodecay

This paper compares the performance of analytical and numerical approaches for modeling DNAPL dissolution with biodecay. A solution derived from a 1-D advective transport formulation (“Parker” model) is shown to agree very closely with high resolution numerical solutions. A simple lumped source mass balance solution in which with decay is assumed proportional to DNAPL mass (“Falta1” model) over- or underpredicts aqueous phase biodecay depending on the magnitude of the exponential factor governing the relationship between dissolution rate and DNAPL mass. A modification of the Falta model that assumes decay proportional to the source exit concentration is capable of accurately simulating source behavior with strong aqueous phase biodecay if model parameters are appropriately selected or calibrated (“Falta2” model). However, parameters in the lumped models exhibit complex interdependencies that cannot be quantified without consideration of transport processes within the source zone. Combining the Falta2 solution with relationships derived from the Parker model was found to resolve these limitations and track the numerical model results. A method is presented to generalize the analytical solutions to enable simulation of partial mass removal with changes in source parameters over time due to various remedial actions. The algorithm is verified by comparison with numerical simulation results. An example application is presented that demonstrates the interactions of partial mass removal, enhanced biodecay, enhanced mass transfer and source zone flow reduction applied at various time periods on contaminant flux reduction. Increasing errors that arise in numerical solutions with coarse discretization and high decay rates are shown to be controlled by using an adjusted decay coefficient derived from the Parker analytical solution.     

用水位恢复数据反演越流承压含水层参数

水文地质勘测中,由于水位恢复阶段没有人力和机械因素干扰,由测量数据可以画出平滑的曲线,更适宜于分析水文地质参数,但经典非稳定流Theis公式和Theis水位恢复法所依据的若干假设条件在实际中难以满足。针对越流承压含水层具有补给条件而很快稳定以及非稳定抽水阶段流量常“抖动”的特点,论证了利用稳定流量和Hantush-Jacob越流模型计算的可行性,并用扩展的卡尔曼滤波器反演水文地质参数,经文献中历史数据和实地抽水试验检验结果表明,由该方法反演的预测值和实测值吻合良好。     

Coordinate mapping of analytical contaminant transport solutions to non-uniform flow fields

Existing analytical solutions to 2D and 3D contaminant transport problems are limited by the mathematically convenient assumption of uniform flow. An approximate method is developed herein for coordinate mapping of 2D (vertically-averaged) transport solutions to non-uniform steady-state irrotational and divergence-free flow fields in single-layer aquifers. The method enables existing analytical transport solutions to be applied to aquifer systems with wells, non-uniform saturated thickness, surface water features, and (to a limited degree) heterogeneous hydraulic conductivity and recharge. This mass-conservative coordinate mapping approach is inexact in its approximation of the dispersion process but is still sufficiently accurate for many simple flow systems. The degree of model error is directly proportional to the variation of velocity magnitude within the domain. These mapped analytical solutions are compared to numerical simulation results and the coordinate mapping errors are investigated. The methods described herein may be used in the traditional capacity of analytical transport models, i.e., screening and preliminary site assessment, without sacrificing accuracy by assuming locally uniform flow conditions or applying an ad-hoc coordinate transformation. The solutions benefit from the traditional advantages of analytical methods, particularly the removal of artifacts due to spatial and temporal discretization: no time-stepping or numerical discretization is required.     

Depth–energy and depth–force relationships in open channel flows. II: Analytical findings for power-law cross-sections

In a recent work [Valiani A, Caleffi V. Depth–energy and depth–force relationships in open channel flows: analytical findings. Adv Water Resour 2008;31(3):447–54], the authors analytically inverted the depth–specific energy and depth–total force relationships for flows in open channels with wide rectangular cross-sections.     

Comments on “Two-dimensional concentration distribution for mixing-controlled bioreactive transport in steady-state” by O.A. Cirpka and A.J. Valocchi

In this comment we present a re-analysis of the analytical solution presented by Cirpka and Valocchi for steady-state concentrations of dissolved bioreactive compounds and bacterial biomass in porous media. We discuss the validity range of the analytical solution. In particular, the criterion used to determine the sustainability of biomass is revisited. This re-analysis shows that the ω$\omega$ criterion used by Cirpka and Valocchi is only a necessary but not a sufficient criterion to determine the bioreactive zones. As a consequence, the analytical solution does not provide the exact distribution of compounds throughout the domain, but can serve as upper or lower boundaries for species concentrations at a given location. These conclusions are supported by the simulation results obtained from an established reactive transport model.     

基于吸收滤波技术的储层气水性质识别方法

目前,人们主要从岩性、物性、电性、弹性阻抗等角度,对储层中气水的性质进行预测,然而成功率却并非很高.其实,从频率或能量响应的角度出发,或许能提高气水识别的成功率.由于频率是物质的固有属性,地震波经过含气或含水的储层后,在不同的频段将有不同的响应特征,但在原始地震剖面上却很不容易发现.利用基于ARMA模型时间序列分析方法和Prony信号分析理论的吸收滤波技术,结合测井、岩石物理、地质、地震等资料,分析含气储层和含水储层的不同吸收衰减特征和响应差异.由此可以实现气水性质的有效识别,最终达到直观、快捷的预测优质含气储层的目的.将该技术应用到气水裂缝理论模型的试算和川西坳陷深层须家河组气藏的含气性识别中,均获得了良好的应用效果.     

The feasibility of isolation and detection of fullerenes and carbon nanotubes using the benzene polycarboxylic acid method

The incorporation of fullerenes and carbon nanotubes into electronic, optical and consumer products will inevitably lead to the presence of these anthropogenic compounds in the environment. To date, there have been few studies isolating these materials from environmental matrices. Here we report a method commonly used to quantify black carbon (BC) in soils, the benzene polycarboxylic acid (BPCA) method, for measurement of two types of single walled carbon nanotubes (SWCNTs), two types of fullerenes and two forms of soot. The distribution of BC products (BPCAs) from the high pressure and high temperature oxidation illustrates the condensed nature of these compounds because they form predominantly fully substituted mellitic acid (B6CA). The conversion of carbon nanoparticles to BPCAs was highest for fullerenes (average of 23.2 ± 4.0% C recovered for both C₆₀ and C₇₀) and lowest for non-functionalized SWCNTs (0.5 ± 0.1% C). The recovery of SWCNTs was 10 times higher when processed through a cation-exchange column, indicating the presence of metals in SWCNTs compromises the oxidation chemistry. While mixtures of SWCNTs, soot and sediment revealed small losses of black carbon during sample processing, the method is suitable for quantifying total BC. The BPCA distribution of mixtures did not agree with theoretical mixtures using model polyaromatic hydrocarbons, suggesting the presence of a matrix effect. Future work is required to quantify different types of black carbon within the same sample.     

洞庭湖区减压井井管及滤层结构试验研究

为研究适用于洞庭湖区二元结构堤基的减压井结构型式,采用室内试验对比分析了土工织物包扎塑料花管式、钢管式、砂滤体式及无砂混凝土式井管的排水减压效果,并结合洞庭湖区何家堤减压井试验工程研究了合理的滤层结构。试验表明,塑料盲沟和毛细板减压井是适合洞庭湖区二元堤基的两种减压井结构型式。     

Comparative ecophysiology of active zoobenthic filter feeding, essence of current knowledge

The present contribution gives an overview of current knowledge of a comprehensive and steadily growing research field. The first section deals with water pumping and particle retention mechanisms in ciliary and muscular filter feeders. The second section examines the biological filter pumps in order to assess adaptation to the environment. Filter-feeding benthic invertebrates have evolved filter pumps to solve common basic problems. This has led to a large degree of similarity between otherwise distant standing species, which makes comparative studies interesting and important. The present review of zoobenthic filter feeding aims at accentuating such recognition.     

集合Kalman滤波同化理论及其数值试验

集合Kalman滤波用于数值试验有着坚实的理论基础.本文介绍了集合Kalman滤波理论及其技术实现, 在此基础上搭建了集合Kalman滤波同化系统, 用MM5模式同化了实测探空资料并作了48 h的预报试验, 并将预报结果与实测值及4D VAR同化的结果作了比较.试验结果表明: 集合Kalman滤波同化探空资料可以改进MM5模式的预报效果, 且集合Kalman滤波同化后模式的预报效果明显优于4D VAR同化后模式的预报效果.