Polymetallic Mineralization at the Suttsu Vein-type Deposit, Southwestern Hokkaido, Japan

Abstract. The Suttsu polymetallic vein-type deposit, hosted by tuff, tuff breccia and shale of the Miocene Kunnui Formation and propylitized hornblende-augite andesite, is located in southwestern Hokkaido, Japan. It has been exploited and explored for Cu, Pb, Zn and Ag until 1962.
In this study, we examined K-Ar ages, ore mineralogical characteristics and fluid inclusions to obtain new data for the deposit.
The K-Ar ages on sericite indicate that the polymetallic mineralization occurred in Late Miocene (8.1–5.7 Ma). The polymetallic banded ore from the Ohkubo vein is characterized by an abundance of Au, Ag, Sn, Bi, in, Se and Te. These metals are mainly ascribed to electrum (30.3–37.8 atom% Ag), Se-bearing pavonite (8.5–9.5 wt% Se), gustavite-lillianite solid solution, Se-bearing bismuthinite (5.0–5.3 wt% Se), kawazulite, cassiterite, Sn-bearing chalcopyrite (3.3–4.2 wt% Sn), In-bearing stannite, stannite-chalcopyrite solid solution, and In- and Sn-bearing sphalerite (2.6–8.4 wt% In and 1.8–4.3 wt% Sn), occurring in narrow bands of the ore. The In- and Sn-bearing sphalerite likely forms a sphalerite-roquesite-stannite solid solution with the contents of roquesite and stannite being about 2–9 and 2-A mole%, respectively. Temperatures and salinities (in wt% NaCl equiv.) of the ore fluids are estimated to be 180-250C and 3–4 wt%, respectively. The Sn-bearing chalcopyrite therefore probably precipitated metastably. The geologic and mineralogical features suggest that pre-Tertiary basement rocks rich in organic material underlie the Miocene Kunnui Formation nearby the deposit and that they contributed to local and temporary reduction of magnetite-series magmas favorable for the early stage tin-polymetallic mineralization.     

Experimental pressure solution compaction of synthetic halite/calcite aggregates

Experimental observations are reported of weakening of sediment-like aggregates by addition of hard particles. Sieved mixtures of calcite and halite grains are experimentally compacted in drained pressure cells in the presence of a saturated aqueous solution. The individual halite grains deform easily by pressure solution creep whereas calcite grains act as hard objects and resist compaction. The fastest rate of compaction of the mixed aggregate is not obtained for a 100% halite aggregate but for a content of halite grains between 45% and 75%. We propose that this unusual compaction behavior reflects the competition between two mechanisms at the grain scale: intergranular pressure solution at grain contacts and grain boundary healing between halite grains that prevent further compaction.     

Simulations of a coupled hydro-chemo-mechanical system in rocks

A coupled hydro-chemo-mechanical numerical model is developed for these coupled phenomena in many engineering fields. The model has been applied to predicting the response of a stressed rockmass column to an injected reactive fluid (reagent) flow. The response includes evolutions of porosity, permeability, reagent and mineral concentrations during dissolution. In the model, the progress of dissolution is defined by the change in porosity ratio and the porosity increases with dissolution assuming there is no precipitation. The numerical evolutions of porosity, permeability, reagent and mineral concentrations during dissolution are validated against steady state solutions. The model results show that these evolutions are regulated to a certain extent by the applied external loadings: an applied extensional stress enhances the progress of the dissolution process while an applied compression stress slows the progress of the dissolution process. This revised version was published online in July 2006 with corrections to the Cover Date.     

Effet du vieillissement des céramiques poreuses sur leur capacité à évaluer la concentration de pesticide en solution

The soil solution sampling by ceramic cups allows pesticide transfer monitoring in the soil during long times. The ageing of material involves a bias in the sampling results. In laboratory, the comparison of two types of ceramic suction cups, new and installed in situ during four years, shows a modification of the hydrodynamic properties and a possible evolution of the adsorption capacity of the matrix. The passage rate, as well qualitative as quantitative, is better for the old material. Recommendations about site management are finally exposed. To cite this article: N. Domange et al., C. R. Geoscience 336 (2004).     

聚合物溶液在地下连续墙施工中的试验研究

简要叙述了一种新型地下连续墙施工稳定液——聚合物溶液的研制及其与细分散泥浆性能的对比，这种新型聚合物溶液克服了目前使用的地下连续墙稳定液品种单一、性能较差的缺点，满足复杂地层的地下连续墙施工需要。同时阐述了这种稳定液的组成成分和性能及其主要特点。     

Seismic activity at the MCT in Sikkim Himalaya

A microearthquake survey in the Sikkim Himalaya raised a question whether the north–south segment of the Main Central Thrust (MCT) in this part of the Himalaya is seismically active(?). Fault-plane solution of a cluster of events occurred below this segment of the MCT shows right-lateral strike-slip motion. The seismic observations and the geological evidences suggest that a NNE–SSW trending strike-slip fault, beneath this segment, caused right lateral movement on the MCT, and is seismically active.     

Erratic judgements: re-evaluating solutional erosion rates of limestones using erratic-pedestal sites, including Norber, Yorkshire

The re-interpretation of surface karst landforms in Northern England has led to a re-examination of well-known erratic-pedestal sites that were the origin for karst denudation rates applied extensively, on the supposition that erratics protect underlying limestone from rainwater solution. Height of the pedestal has been used to calculate long-term solutional-lowering, as much as 50 cm in 15 ka (33.3 mm/ka) from UK sites. The sites include Norber and Scar Close, Yorkshire, UK. This paper shows that the sites have been misinterpreted, in particular at Norber where the erratics lie on a pre-existing structurally stepped surface. Norber and several other sites also experience much mechanical weathering, in relatively weak, well-fractured limestones, a process which must be distinguished from solution. Sites in strong, less-fractured limestones demonstrate lower rates, which are sounder indications of land surface lowering. Some pedestals have been confirmed as partly resulting from solutional weathering in surrounding soil and vegetation. Re-evaluation reduces solution rates to 3–13 cm in 15 ka. Applying such rates has profound implications for understanding limestone landscapes, challenging orthodox views.     

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

浓硫酸钠水溶液中的离子对

不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。