The Peloritani Mountains are a fragment of an orogen variably attributed to the Alpine or Hercynian orogeny. On the basis of 39Ar-40Ar, U-Pb and Rb-Sr dating, the main metamorphism of the two medium–high grade metamorphic units, the Mela and Aspromonte Units, and most of the thrusting responsible for stacking the orogenic edifice are seen to be Hercynian. The main thrusting of the Aspromonte Unit over the lower grade units took place at 301±2 Ma. Brittle deformation during Tertiary reactivation of Hercynian thrust planes did not generate any rejuvenation of white micas in the studied sector. Our dataset shows a great complexity and we propose to unravel it by considering different levels of information. To first order, the Mela and Aspromonte Units differ in their metamorphic paths and their geochronological evolution. The Mela Unit shows generally younger ages (Carboniferous) than the Aspromonte Unit and, unlike the latter, was extensively retrogressed in greenschist facies. The Aspromonte Unit is itself geochronologically heterogeneous. Proterozoic ages are preserved both in titanite and in amphibole relics of one tectonic subunit; Devonian to Carboniferous amphibole ages are found in different other subunits; tertiary overprint is minor and spatially limited. We propose to consider the chronologically heterogeneous subunits as accreted pre-Hercynian terranes amalgamated late during the Hercynian orogeny. Micas in both units give scattered Mesozoic 39Ar-40Ar and Rb-Sr ages, with evidence for heterochemical mica generations. We interpret them as a result of widespread hydrothermal circulation event(s). Tertiary overprint is generally absent, with the exception of a small area near Messina where biotite and muscovite underwent a complex recrystallisation history in the interval between 48 and 61 Ma.An erratum to this article can be found at 相似文献
Amphiboles are the main mafic minerals in most metaluminous to peralkaline alkali-feldspar granites and syenites, and they usually preserve an important record of the compositional evolution of the melts from which they crystallize. In the alkaline association of the Serra da Graciosa A-type Granites and Syenites (southern Brazil), amphibole compositions span a large range, including calcic, sodic–calcic, and sodic amphiboles. Calcic amphiboles are typically observed in the metaluminous rocks, while sodic amphiboles are characteristic of the more strongly peralkaline rocks; sodic–calcic amphiboles are found in intermediate varieties. Compositional variations record the differentiation trends within two petrographic series of the alkaline association. The overall evolution of amphibole compositions is similar in both: they reveal a progressive increase in Na and Fe3+ with differentiation (increase in alkalinity of the magmas), a characteristic shared by undersaturated peralkaline (or agpaitic) differentiation trends. In detail, however, the evolutions of the amphibole compositions in the two series are distinct. In Alkaline series 1, the cores of the crystals form a continuum from calcic to sodic compositions, with the exception of a small compositional gap within the sodic–calcic amphiboles. The rims, however, show compositions that diverge from this main trend; this divergence results from increasing amounts of the oxy-amphibole component, and reflects more oxidizing conditions at the final stages of magmatic crystallization. In Alkaline series 2, these oxidation trends are much more subtle and a reverse trend is observed in the sodic amphiboles. Sodic–calcic amphiboles are in several cases replaced by intergrowths of post-magmatic sodic amphibole and Al-poor (“tetrasilicic”) biotite. 相似文献
After the major 1991–1993 eruption, Mt. Etna resumed flank activity in July 2001 through a complex system of eruptive fissures
cutting the NE and the S flanks of the volcano and feeding effusive activity, fire fountains, Strombolian and minor phreatomagmatic
explosions. Throughout the eruption, magmas with different petrography and composition were erupted. The vents higher than
2,600 m a.s.l. (hereafter Upper vents, UV) erupted porphyritic, plagioclase-rich trachybasalt, typical of present-day summit
and flank activity. Differently, the vents located at 2,550 and 2,100 m a.s.l. (hereafter Lower vents, LV) produced slightly
more primitive trachybasalt dominated by large clinopyroxene, olivine and uncommon minerals for Etna such as amphibole, apatite
and orthopyroxene and containing siliceous and cognate xenoliths. Petrologic investigations carried out on samples collected
throughout the eruption provided insights into one of the most intriguing aspects of the 2001 activity, namely the coeval
occurrence of distinct magmas. We interpret this evidence as the result of a complex plumbing system. It consists in two separate
magma storage systems: a shallow one feeding the activity of the UV and a deeper and more complex storage related to the activity
of LV. In this deep storage zone, which is thermally and compositionally zoned, the favourable conditions allow the crystallization
of amphibole and the occurrence of cognate xenoliths representing wall cumulates. Throughout 2001 eruption, UV and LV magmas
remain clearly distinct and ascended following different paths, ruling out the occurrence of mixing processes between them.
Furthermore, integrating the 2001 eruption in the framework of summit activity occurring since 1995, we propose that the 2001
magma feeding the vents lower than 2,600 m a.s.l. is a precursor of a refilling event, which reached its peak during the 2002–2003
Etna flank eruption. 相似文献
A corundum-bearing mafic rock in the Horoman Peridotite Complex, Japan, was derived from upper mantle conditions to lower crustal conditions with surrounding peridotites. The amphiboles found in the rock are classified into 3 types: (1) as interstitial and/or poikilitic grains (Green amphibole), (2) as a constituent mineral of symplectitic mineral aggregates with aluminous spinel at grain boundary between olivine and plagioclase (Symplectite amphibole) and (3) as film-shaped thin grains, usually less than 10 μm in width, at grain boundary between olivine and clinopyroxene (Film-shaped amphibole). The Film-shaped amphibole is rarely associated with orthopyroxene extremely low in Al2O3, Cr2O3 and CaO (Low-Al OPX). These minerals were formed by infiltration of SiO2- and volatile-rich fluids along grain boundaries after the rock was recrystallized at olivine-plagioclase stability conditions, i.e. the late stage of the exhumation of the Horoman Complex.
Chondrite-normalized rare earth element patterns and primitive mantle-normalized trace-element patterns of the Green amphibole and clinopyroxene are characterized by LREE-depleted patterns with Eu positive and negative anomalies of Zr and Hf. These geochemical characteristics of the constituent minerals were inherited from original whole-rock compositions through a reaction involving both pre-existing clinopyroxene and plagioclase. We propose that the fluids were originally rich in a SiO2 component but depleted in trace-elements. Dehydration of the surrounding metamorphic rocks in the Hidaka metamorphic belt, probably related to intrusion of hot peridotite body into the Hidaka crust, is a plausible origin for the fluids. 相似文献
This paper reports detailed analyses of Nb and Ta concentrations of 19 eclogite samples and their principal mineral constituents from the main drill hole of the Chinese Continental Scientific Drilling Project (CCSD) and nearby outcrops. We observe highly fractionated and overall suprachondritic Nb/Ta values in minerals, e.g., rutile (4.8–87), titanite (12–62) and amphibole (2.0–67). Amphiboles in amphibolites (retrograded from eclogite) can be classified into two groups: a low Nb/Ta group that bears higher Al contents and is thus of higher pressure origin, and a high Nb/Ta, lower pressure group. The former group was likely formed during subduction; the latter may have formed during exhumation in the presence of rutile and titanite. The significant Nb/Ta fractionation in rutile and other minerals may reflect early dehydration of the subducted slab at shallow depths before the formation of rutile, which occurs at depths ≥50 km. The dehydration, with amphiboles existing as the main Nb–Ta-bearing phase, would lead to Nb/Ta fractionation, i.e., forming subchondritic Nb/Ta ratios in the released fluids and, complementarily, suprachondritic Nb/Ta ratios in the residual phases. While a large proportion of the fluids may escape from the slab to the mantle wedge, considerable amounts of the fluids can be retained in hydrous minerals within the descending slab, thus forming hydrated cold eclogites with subchondritic Nb/Ta characteristics. As subduction continues to depths over 50 km, rutile appears and consequently controls the Nb–Ta budget. In the presence of rutile, melting of the hydrated cold eclogites with very low Nb/Ta ratios would form magmas with negative Nb, Ta anomalies and subchondritic Nb/Ta. Further dehydration of the continuously descending slab results in even more fractionated Nb/Ta ratios in subsequently released fluids and residues, providing a feasible explanation for the large Nb/Ta variation observed in the modern arc magmas and residual eclogites. 相似文献
Constraining crystallization pressure and thus intrusion depth of granites in various geodynamic settings remains challenging, yet important to further our understanding of magma system and crustal evolution. We propose that titanite, which is a common accessory in metaluminous and weakly peraluminous granites, can be used as a barometer if it crystallized in magmatic, near-solidus conditions and in equilibrium with amphibole, plagioclase, K-feldspar, quartz, biotite, and magnetite ± ilmenite. Titanite Al2O3 increases with pressure (P) according to: P (in MPa) = 101.66 × Al2O3 in titanite (in wt%) + 59.013 (R2 = 0.83) with estimated uncertainties of ~±60 to ~±100 MPa for crystallization between ~150 and 400 MPa. We highlight that the current calibration dataset is limited, and that systematic experimental studies are needed to rigorously quantify the relation. The most important use of this empirical barometer will be for rocks in which amphibole is present but significantly altered, or in combination with amphibole barometry, as titanite can be easily dated by LA-ICP-MS. 相似文献
The P21/mC2/m displacive phase transition in the synthetic end-member amphibole Na NaMg Mg5 Si8 O22 (OH)2 has been studied by monitoring changes in unit-cell parameters and the intensities of superlattice reflections at 25–400 °C. This amphibole allows investigation of the effects of compositional variations at the A- and B-group sites upon the transition. Polynomial fitting of a 24 Landau potential to the evolution of the order parameter with T yielded a Tc of 257 ± 3 °C, and Landau coefficients compatible with a second-order transition. Structure refinement of single-crystal data collected at 25, 140, 270 and 370 °C allowed modelling of the structural changes as a function of T and symmetry. Crystal-chemical analysis suggests that differences in Tc in cummingtonites and in the crystal of this work depend mainly upon the relations between the aggregate ionic radii of the B- and C-group cations.
Electronic Supplementary Material: of Table 5 is available in the online version of this article at http://dx.doi.org/10.1007/s00269-003-0348-9 相似文献
ABSTRACTTongling, in eastern China, is an area well-known for intra-plate adakites. Here, we present the mineral chemistry and zircon U–Pb ages for amphibole cumulate xenoliths, the mineral chemistry of amphibole megacrysts, and the whole–rock chemistry, zircon U–Pb age and Sr–Nd isotopic compositions of host gabbros from Tongling. Zircon U–Pb dating yields a crystallization age of 120.6 ± 1.2 Ma (MSWD = 4.2) for the host gabbros, which are characteristically depleted in high field strength elements (Nb, Ta, and Ti) and enriched in large ion lithophile elements (Ba and Sr), with εNd (t) of ?3.00 to ?4.52 and initial 87Sr/86Sr ratios of 0.7068–0.7072, suggesting an enriched mantle source. Parental melts, as estimated from average amphibole megacryst and cumulate compositions, have Mg# values of 26–33, are enriched in Ba, Th, U, and Nd, and depleted in Nb, Ta, Zr, Hf, and Ti, similar to 136 Ma mafic magmas in Tongling. Zircon U–Pb dating yields a crystallization age of 135.4 ± 1.0 Ma (MSWD = 1.6) for the amphibole cumulates. It is concluded that the Tongling adakitic rocks were formed by polybaric crystallization involving early high-pressure intracrustal fractional crystallization of cumulates comprising hornblende and clinopyroxene, and late low-pressure fractional crystallization of hornblende and plagioclase phenocrysts. The flat subduction of Pacific plate and its subsequent foundering during the Cretaceous may have triggered the generation of extensive adakitic magmas and lithospheric thinning in the Lower Yangtze Region. 相似文献