Crystal chemistry of tremolite–tschermakite solid solutions

Tremolite–tschermakite solid solutions have been synthesized between 700 and 850 °C and 200 and 2000 MPa. The starting materials were oxide–hydroxide mixtures and an additional 0.1–1.8 molal CaBr₂ solution. The run products were characterized using SEM, HRTEM, EMP, XRD and FTIR. The synthesized Al tremolites formed needles and lath-shaped crystals of up to 300 × 20 μm. HRTEM investigations showed that the majority of the amphiboles were well ordered. The EMP analysis revealed that the Al tremolites were solid solutions in the ternary tremolite–tschermakite–cummingtonite. The highest observed Al content was close to the composition of magnesiohornblende (X_ts=0.54). Different cummingtonite concentrations (X_cum=0.00–0.18) were observed, which generally increased with Al content. Rietveld refinements of the lattice constants showed a linear decrease of the cell parameters a and b with increasing Al content, whereas c and β increased. Small deviations from the linear behaviour were caused by variable amounts of the cummingtonite component. For pure tschermakite lattice parameters of a=9.7438(11) Å, b=17.936(14) Å, c=5.2995(3) Å, β=105.68(9)° and V=891.7 ± 1.4 ų were extrapolated by least-squares regression. Using the a and β lattice parameters for tremolite, tschermakite and cummingtonite, it was possible to derive amphibole compositions using powder XRD. IR spectra of the Al tremolites showed a total of 12 individual bands. The FWHMs of all bands increased with increasing Al content. According to their FWHMs, these bands were grouped into three band systems at 3664–3676 cm^?1 (I), 3633–3664 cm^?1 (II) and 3526–3633 cm^?1 (III). Assuming ^[6]Al substitution at M2 and/or M3 and ^[4]Al at T1, three principal different configurational groups could be assigned as local environments for the proton. I: only Si⁴⁺ at T1 and one or two Al³⁺ at M2 and/or M3_far, II: one Al³⁺ at T1 and one to three Al³⁺ at M2 and/or at M3_far, III: either Al³⁺ on M3_near and/or two Al³⁺ on T1 and additional one to four Al³⁺ at M2. It is assumed that these three configurational groups correspond to the three groups of observed bands. This was quantitativly supported by Monte-Carlo simulations. A model with random distribution at M2 and M3 including Al avoidance at tetrahedral and octahedral sites yielded the best agreement with the spectroscopical results.     

Uncertainty in adaptive capacity

The capacity to adapt is a critical element of the process of adaptation: it is the vector of resources that represent the asset base from which adaptation actions can be made. Adaptive capacity can in theory be identified and measured at various scales, from the individual to the nation. The assessment of uncertainty within such measures comes from the contested knowledge domain and theories surrounding the nature of the determinants of adaptive capacity and the human action of adaptation. While generic adaptive capacity at the national level, for example, is often postulated as being dependent on health, governance and political rights, and literacy, and economic well-being, the determinants of these variables at national levels are not widely understood. We outline the nature of this uncertainty for the major elements of adaptive capacity and illustrate these issues with the example of a social vulnerability index for countries in Africa. To cite this article: W.N. Adger, K. Vincent, C. R. Geoscience 337 (2005).     

临沭县国土资源局信息化建设的几点做法

开创国土资源管理事业新局面和带出一支高素质的干部队伍成为国土资源管理工作面前的重大课题。临沭县国土资源局以满足经济社会发展和国土资源管理需要为宗旨,以国土资源业务管理为主线,以促进高效管理、科学决策和依法行政为目标,突出现代化、精细化管理特点,走出了一条以信息化建设推进精细化管理的新思路。     

State of seawater intrusion and its adaptive management countermeasures in Longkou City of China

Longkou City is a coastal area,and lacks water resources.The overexploitation of groundwater causes seawater intrusion.At present,seawater intrudes an area of 68 km2.With the decrease of groundwater extraction,the seawater intrusion area has generally declined.The paper expounds the development process of seawater intrusion as well as the corresponding prevention and control measures of using groundwater replenishment and groundwater throttling in Longkou City.In view of the seawater intrusion problem in Longkou City,some adaptive management countermeasures are put forward,which include:Adjusting industrial and agricultural structure,promoting economic and social development to match water resources;improving water usage structure,optimizing the utilization of water resources;advancing the construction of a water-saving society,using water resources efficiently;implementing inter-basin water transfer,using water resources rationally;developing and utilizing unconventional water sources,making full use of water resources;strengthening water infrastructure construction,increasing the development and utilization potential of water resources;carrying out ecological restoration,protecting water resources and ecological environment;improving the management informationalization level,strengthening the capabilities of groundwater monitoring and management;increasing publicity,improving public awareness of participation.     

Dehydration experiments on natural omphacites: qualitative and quantitative characterization by various spectroscopic methods

A series of natural omphacites from a wide range of P, T occurrences were investigated by electron microprobe (EMP), infrared (IR)-, Mössbauer (MS)- and optical spectroscopy in the UV/VIS spectral range (UV/VIS), secondary ion mass spectrometry (SIMS) and single crystal structure refinement by X-ray diffraction (XRD) to study the influence of hydrogen loss on valence state and site occupancies of iron. In accordance with literature data we found Fe²⁺ at M1 as well as at M2, and in a first approach assigned Fe³⁺ to M1, as indicated by MS and XRD results. Hydrogen content of three of our omphacite samples were measured by SIMS. In combination with IR spectroscopy we determined an absorption coefficient: ε _i,tot = 65,000 ± 3,000 lmol_H2O ^?1 cm^?2. Using this new ε _i,tot value, we obtained water concentrations ranging from 60 to 700 ppm H₂O (by weight). Hydrogen loss was simulated by stepwise heating the most water rich samples in air up to 800°C. After heat treatment the samples were analyzed again by IR, MS, UV/VIS, and XRD. Depending on the type of the OH defect, the grade of dehydration with increasing temperature is significantly different. In samples relatively poor in Fe³⁺ (<0.1 Fe³⁺ pfu), hydrogen associated with vacancies at M2 (OH bands around 3,450 cm^?1) starts to leave the structure at about 550°C and is completely gone at 780°C. Hydrogen associated with Al³⁺ at the tetrahedral site (OH bands around 3,525 cm^?1, Koch-Müller et al., Am Mineral, 89:921–931, 2004) remains completely unaffected by heat treatment up to 700°C. But all hydrogen vanished at about 775°C. However, this is different for a more Fe³⁺-rich sample (0.2 Fe³⁺ pfu). Its IR spectrum is characterized by a very intense OH band at 3,515 cm^?1 plus shoulder at 3,450 cm^?1. We assign this intense high-energy band to vibrations of an OH dipole associated with Fe³⁺ at M1 and a vacancy either at M1 or M2. OH release during heating is positively correlated with decrease in Fe²⁺ and combined with increase in Fe³⁺. That dehydration is correlated with oxidation of Fe²⁺ is indirectly confirmed by annealing of one sample in a gas mixing furnace at 700°C under reducing conditions keeping almost constant OH^? content and giving no indication of Fe²⁺-oxidation. Obtained data indicate that in samples with a relatively high concentration of Fe²⁺ at M2 and low-water concentrations, i.e., at a ratio of Fe^{2+ M2}/H > 10 dehydration occurs by iron oxidation of Fe²⁺ exclusively at the M2 site following the reaction: \( {\left[ {{\text{Fe}}^{{{\text{2 + [ M2]}}}}{\text{OH}}^{ - } } \right]} = {\left[ {{\text{Fe}}^{{{\text{3 + [ M2]}}}} {\text{O}}^{{{\text{2}} - }} } \right]} + {\text{1/2}}\;{\text{H}}_{{\text{2}}} \uparrow . \) In samples having relatively low concentration of Fe²⁺ at M2 but high-water concentrations, i.e., ratio of Fe^{2+ M2}/H < 5.0 dehydration occurs through oxidation of Fe²⁺ at M1.     

自适应海洋观测

“自适应海洋观测”指固定或移动的海洋观测平台能够根据海洋环境和信号的变化,自主调节测量和运行参数,获取最关键的海洋信息.自主水下航行器运用自适应检测和采样技术,在研究上升流锋面等实验中显示出前所未有的观测准确度和效率.一个海洋观测系统的综合效能,取决于固定平台和移动平台的功能互补以及自适应观测能力的增强.     

A high order Godunov scheme with constrained transport and adaptive mesh refinement for astrophysical and geophysical MHD

We propose to extend the well-known MUSCL-Hancock scheme for Euler equations to the induction equation modeling the magnetic field evolution in kinematic dynamo problems. The scheme is based on an integral form of the underlying conservation law which, in our formulation, results in a “finite-surface” scheme for the induction equation. This naturally leads to the well-known “constrained transport” method, with additional continuity requirement on the magnetic field representation. The second ingredient in the MUSCL scheme is the predictor step that ensures second order accuracy both in space and time. We explore specific constraints that the mathematical properties of the induction equations place on this predictor step, showing that three possible variants can be considered. We show that the most aggressive formulations reach the same level of accuracy than the other ones, at a lower computational cost. More interestingly, these schemes are compatible with the Adaptive Mesh Refinement (AMR) framework. It has been implemented in the AMR code RAMSES. It offers a novel and efficient implementation of a second order scheme for the induction equation. The scheme is then adaptated to solve for the full MHD equations using the same methodology. Through a series of test problems, we illustrate the performances of this new code using two different MHD Riemann solvers (Lax–Friedrich and Roe) and the need of the Adaptive Mesh Refinement capabilities in some cases. Finally, we show its versatility by applying it to the ABC dynamo problem and to the collapse of a magnetized cloud core.     

A three-tiered approach to participatory vulnerability assessment in the Solomon Islands

Greater recognition of the seriousness of global environmental change has led to an increase in research that assesses the vulnerability of households, communities and regions to changing environmental or economic conditions. So far, however, there has been relatively little attention given to how assessments can be conducted in ways that help build capacity for local communities to understand and find their own solutions to their problems. This paper reports on an approach that was designed and used to work with a local grass roots organization in the Solomon Islands to promote inclusivity and participation in decision-making and to build the capacity of the organization to reduce the vulnerability of communities to drivers of change. The process involved working collaboratively with the organization and training its members to conduct vulnerability assessments with communities using participatory and deliberative methods. To make best use of the learning opportunities provided by the research process, specific periods for formal reflection were incorporated for the three key stakeholders involved: the primary researchers; research assistants; and community members. Overall, the approach: (1) promoted learning about the current situation in Kahua and encouraged deeper analysis of problems; (2) built capacity for communities to manage the challenges they were facing; and (3) fostered local ownership and responsibility for problems and set precedents for future participation in decision-making. While the local organization and the communities it serves still face significant challenges, the research approach set the scene for greater local participation and effort to maintain and enhance livelihoods and wellbeing. The outcomes highlight the need for greater emphasis on embedding participatory approaches in vulnerability assessments for communities to benefit fully from the process.     

Spinning in circles? A systematic review on the role of theory in social vulnerability,resilience and adaptation research

An increasing number of publications focus on social vulnerability, resilience, and adaptation (SVRA) towards natural hazards and climate change. Despite this proliferation of research, a systematic understanding of how these studies are theoretically grounded is lacking. Here, we systematically reviewed 4432 articles that address SVRA in various disciplinary fields (e.g. psychology, sociology, geography, mathematics) for various hazards, including floods, droughts, landslides, storm surges, wildfires, tsunamis, earthquakes, and volcano eruptions. We focus on the extent to which these studies explicate the frameworks, theoretical constructs or theories they rely on. Surprisingly, we found that about 90% of the reviewed studies do not explicitly refer to a theoretical underpinning. Overall, theories focusing on individuals’ SVRA were more frequently used than those focusing on systems, society, groups, and networks. Moreover, the uptake of theories varied according to the hazard investigated and field of knowledge, being more frequent in wildfire and flood studies and articles published in social science journals. Based on our analysis, we propose a reflexive handling of theories to foster more transparent, comparable, and robust empirical research on SVRA.     

Upscaling the resilience assessment through comparative analysis

Resilience is the capacity of any system to maintain its function, structure and identity despite disturbances. Assessing resilience has been elusive due to high levels of abstraction that are difficult to empirically test, or the lack of high quality data required once appropriate proxies are identified. Most resilience assessments are limited to specific situation arenas, making comparision one of the unresolved challenges. Here we show how leveraging comparative analysis can provide insights on how Arctic communities (N = 40) can best deal with social and environmental change. We found that the capacity to self-organize, and nurturing diversity are sufficient conditions for Arctic communities whose livelihoods have been resilient, or for communities whose livelihoods have been transformed. Our study provides an alternative perspective on how to assess resilience by leveraging comparsion across cases. It also identify governance patways to support adaptations and transformations in the Arctic, a geography with some of the most dramatic social and natural challenges to come.