玛珥湖与纹泥年代学

火山活动是影响全球变化的重要因素之一，玛珥湖和纹泥年代学是近年来古气候研究的新领域。玛珥湖由于其独特的封闭性及其物化条件，使之成为古环境变迁信息的理想载体。纹泥年代学是高分辨率研究过去全球变化的重要手段。玛珥湖的现存状态可以分为空型、湖型、沼泽型和干枯型。纹泥是某些玛珥湖中比较常见的一种沉积构造，它的形成需要一种精细的平衡。硅藻作为纹泥的一个重要组成部分，对光量、温度和各种无机盐反应敏锐，具有重要的古环境意义。能否制作完好的沉积物薄片是纹泥年代学成功与否的关键，本文对纹泥年代学的具体操作方法做了扼要介绍。中国有广泛的火山分布，其中不乏玛洱湖的存在，对之进行详细研究，不仅可以获得可与黄土、冰芯和深海岩芯相媲美的古气候序列，而且可以解决古气候学中某些难题。     

锂盐水溶液的热力学性质研究

本文用Ｍｅｉｓｓｎｅｒ公式、Ｂｒｏｍｌｅｙ公式、Ｃｈｅｎ公式、Ｐｉｔｉｅｒ公式及经作者改进的平均球近似（ＭＳＡ）方法对锂盐水溶液（最大浓度达２０ｍｏｌ／ｋｇ）的离子平均活度系数进行了计算和比较，结果表明改进后的ＭＳＡ方法的计算精度最高。另外，本文还应用改进的ＭＳＡ法，使用由单一电解质水溶液离子平均活度系数得到的参数，不用任何混合参数，预测了２９８．１５ｋ时ＬｉＣｌ＋Ｌｉ２ＳＯ４和ＬｉＣｌ＋ＫＣｌ水溶液的等温溶解度图．其结果与文献实验值基本一致。     

348-YEAR PRECIPITATION RECONSTRUCTION FROM TREE-RINGS FOR THE NORTH SLOPE OF THE MIDDLE TIANSHAN MOUNTAINS

Correlation census shows that the correlation between the tree-ring chronologies in theUrumqi River Basin and precipitation during July in the last year to February in the concurrent yearis significant,and the best single correlation coefficient is 0.74,with significance level of 0.0001.Using two residual chronologies collected from west Baiyanggou and Boerqingou,precipitation for348 years can be reconstructed in the North Slope of middle Tianshan Mountains,its explainedvariance is 62%.According to much verification from independent precipitation data,historicalclimate records,glacier and other data.it shows that the reconstructed precipitation series of 348years is reliable.Analysis of precipitation features indicates that there were three wet periodsoccurring during 1671(?)—1692,1716—1794 and 1825—1866 and three dry periods during 1693—1715,1795—1824 and 1867—1969.Two wet periods,during 1716—1794 and 1825—1866,correspond to the times of the second and the third glacial terminal moraine formation,which is infront of No.1 glacier in Urumqi River source.According to computation,corresponding annualprecipitation amounts are 59mm and 30mm more than now.The reconstructed precipitation serieshas a significant drying trend from 1716 to 1969.and has better representativeness to theprecipitation of Urumqi and Changji Prefecture on the North Slope of Tianshan Mountains.     

Sm-Nd isotope systematics in garnet from different lithologies (Eastern Alps): age results, and an evaluation of potential problems for garnet Sm-Nd chronometry [Chem. Geol. 185 (2002) 255-281]

Interpretation of Sm-Nd garnet ages is frequently impaired by one of the following restrictions: (a) high-LREE inclusions, (b) isotopic disequilibrium, and (c) the uncertainty about the closure temperature. These issues are addressed by way of an evaluation of garnet Sm-Nd data from different rock types of the Austroalpine basement units, Eastern Alps, including metabasic eclogites, mica schist and paragneiss, metapegmatite and metagranite.Nd concentration in handpicked garnet varies between 0.021 and 23.1 ppm in metabasites, 0.49 and 17.4 ppm in metapelites and between 0.024 and 4.6 ppm in metapegmatites and metagranites. The overall range of ¹⁴⁷Sm/¹⁴⁴Nd is 0.15-2.5 in garnet from metabasites, 0.12-3.03 in metapelite garnet and 0.66-7.21 in Mn-rich garnet from metapegmatites and metagranites. A clear negative correlation between Nd concentration and Sm/Nd is observed in garnets from all these lithologies. Therefrom, it is concluded that even optically “clean” garnet separates may contain high-LREE microinclusions, such as epidote-allanite, zoisite, apatite, sphene, monazite or zircon. However, very low Nd concentrations correlated with low Sm/Nd as well as high Nd concentrations (>5 ppm) correlated with fairly high Sm/Nd ratios (0.8) have also been observed. Apart from replicate analyses within as well as between samples with a common PT-history, leaching experiments are a useful technique to elucidate any distorting influence of unequilibrated inclusions on the garnet age, especially if the observed Sm/Nd ratio is low (<0.5). Leaching of garnet separates with HCl (2.5, 5.8 M) produces no obvious element fractionation, but may improve Sm/Nd, and hence age precision, considerably. Isotopic disequilibrium between garnet and other matrix minerals is observed preferentially in basic eclogites, derived from gabbroic precursors.Sm-Nd garnet analysis allows the recognition of several distinct garnet-forming events in the Eastern Alps.(a) A Variscan high-P event is documented in metabasites from the northern-central Ötztal basement around 360-350 Ma, whereas garnet from sillimanite-bearing gneisses dates the Variscan thermal peak in the western part of the same subunit around 345-330 Ma.(b) A long-lived, Permian to Triassic event (285-225 Ma), correlated with crustal extension and low-P metamorphism, is documented by spessartine-rich garnet from metapegmatites as well as almandine-rich garnet cores from mica schist.(c) Age data of garnet from eo-Alpine (Cretaceous) deeply subducted rocks of the southern/eastern Austroalpine units are related to near-peak PT, eclogite- to amphibolite-facies metamorphic conditions (peak: 2 GPa/685 °C), and/or incipient isothermal decompression, due to fast, tectonically driven exhumation (110/100-85 Ma). At cooling rates of 20-30 °C/Ma (exhumation rates: 3-5 km/Ma), the Sm-Nd closure temperature (T_c) for mm-sized garnet in these rocks is estimated at 650-680 °C.     

Re-Os同位素体系在陨石研究中的应用

铁陨石中的Re ,Os含量反映其结晶分异历史。通过铁陨石定年修正187Re的衰变常数为 :λ(187Re) =1 6 6 6× 10 -11a-1。ReOs同位素测年法可以直接用于对铁陨石的定年 ,结果表明天然铁陨石大体同时形成 ,但ReOs定年技术已有可能揭示不同化学群铁陨石形成年代的序列 ,但研究尚需深入。这些方法也可以用来探讨铁陨石和石铁陨石的形成源区、冷却历史和后期变化。虽然在石陨石中Re ,Os同位素的浓度很低 ,但也有了探索性研究成果。随着技术的不断发展 ,ReOs同位素体系在天体化学中的作用将愈加明显和重要。     

MgO活性及其在MgCl2溶液中溶度的研究

测定了不同MgO的碘值和比表面积 ,给出了MgO活性与煅烧温度之间的关系式。研究了MgO活性、煅烧温度、溶解温度和MgCl2 浓度等对MgO溶解的影响。并讨论了活性MgO在含不同硼碱比 [n(B2 O3) :n(MgO) =n]的MgCl2 溶液中形成硼酸镁盐过饱和溶液与增溶的MgO关系。     

Reconstructing lake and drainage basin history using terrestrial sediment layers: analysis of cores from a post-glacial lake in New England, USA

Four sediment cores and twenty-five ¹⁴C ages from Ritterbush Pond in northern Vermont provide a detailed and continuous temporal record of Holocene lake and watershed dynamics. Using visual logs, carbon content, magnetic susceptibility, stable isotope signatures, and X-radiography, all measured at 1-cm scale, we identify and date discrete layers of terrestrially-derived sediment in the organic-rich, lacustrine gyttja. These inorganic layers range in thickness from <1 mm to >10 cm and range in grain size and sorting from homogeneous silt to graded sand. AMS radiocarbon ages both from macrofossils within the thickest layers, and gyttja bracketing these layers, provide the basis for correlation among the cores, the dating of 52 basin-wide sedimentation events, and the development of a detailed sedimentation chronology for the Holocene.Physical, chemical, and isotopic analyses suggest the inorganic layers are terrestrially derived and result from hydrologic events large enough to erode and transport sediment from the watershed into the pond. The temporal and spatial distribution of the inorganic layers suggests changing basin-wide sedimentation and thus erosion dynamics since deglaciation over 12,000 years ago. Specifically, for intervals lasting 400 to 1000 years, during the early (>8600 cal yBP), middle (6400 to 6800 cal yBP) and late Holocene (1800 to 2600 cal yBP), the Ritterbush Pond watershed eroded more rapidly than at other times and terrestrially derived material poured into the pond. Analysis of Ritterbush Pond sediments demonstrates the potential for North American lakes to preserve a record of drainage basin dynamics.     

稀散金属化合物热力学性质的研究Ⅱ:HCl-In2(SO4)3-H2O体系

在HCl In2 (SO4) 3 H2 O体系中 ,溶液表观总离子强度恒定为I=0 2、0 4、0 6、0 8、1 0、1 5mol·kg-1,硫酸铟在溶液中的表观离子强度分数恒定为yB =0 0 0、0 1 0、0 2 0、0 3 0、0 5 0和 0 70条件下 ,应用经典的电动势方法测定无液体接界电池 (A)在 2 78 1 5～ 3 1 8 1 5K温度范围内的电动势 :Pt,H2 (1 0 1 3 2 5kPa) |HCl(mA) ,In2 (SO4) 3 (mB) ,H2 O|AgCl Ag (A)根据测得电池 (A)的电动势数据 ,考虑到该体系存在硫酸的二级解离 ,应用数学迭代方法确定平衡体系氢离子的浓度 ,进而确定了混合溶液中HCl的活度系数γA。结果表明 ,HCl的活度系数服从扩展的Harned规则。     

地震活动参数似然比检验研究

在地震活动性参数估计中 ,对同一地区具有相同地震资料和相同统计方法的情况下 ,活动性参数会出现因人而异的估计结果。为了对这些参数的不同估计做出评价 ,文中从统计角度将似然比检验引入到地震活动性参数的不同估计的选优排序决策中 ,分析了似然比检验的基本特征 ,并以华北地区为例示范性地分析了似然比检验对地震活动性参数的决策性检验     

松辽盆地火山岩的同位素年代、地球化学特征及意义

沉积盆地内部的火山岩是研究盆地形成的构造环境以及探讨盆地发展演化的动力学特征的重要线索。松辽盆地具有二元结构特征，断陷构造层发育大量的火山岩。但是，前人尚未对比进行深入系统的研究。根据采自钻井岩芯的火山岩样品，通过同位素测年（K／Ar)和地球化学分析等结果，讨论了松辽盆地晚中生代火山岩的岩石学、岩石化学和地球化学特征，探讨了盆地发育早期的构造环境及其地球动力学背景。指出松辽盆地在其形成早期（即断陷期）是一个发育陆缘岩浆弧构造背景上的走滑拉张盆地，火山岩岩浆源区具有多成分、复合性的演化特点。