Equilibrium constants of triethanolamine in major seawater salts

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.     

Effects of crab–halophytic plant interactions on creek growth in a S.W. Atlantic salt marsh: A Cellular Automata model

The Bahía Blanca Estuary (38° 50′ S, and 62° 30′ W) presents salt marshes where interactions between the local flora (Sarcocornia perennis) and fauna (Chasmagnathus granulatus) generate some kind of salt pans that alter the normal water circulation and condition its flow and course towards tidal creeks. The crab–vegetation dynamics in the salt marsh presents variations that cannot be quantified in a reasonable period of time. The interaction between S. perennis plant and C. granulatus crab is based on simple laws, but its result is a complex biological mechanism that causes an erosive process on the salt marsh and favors the formation of tidal creeks. To study it, a Cellular Automata model is proposed, based on the laws deduced from the observation of these phenomena in the field, and then verified with measurable data within macroscale time units. Therefore, the objective of this article is to model how the interaction between C. granulatus and S. perennis modifies the landscape of the salt marsh and influences the path of tidal creeks. The model copies the basic laws that rule the problem based on purely biological factors.The Cellular Automata model proved capable of reproducing the effects of the interaction between plants and crabs in the salt marsh. A study of the water drainage of the basins showed that this interaction does indeed modify the development of tidal creeks. Model dynamics would likewise follow different laws, which would provide a different formula for the probability of patch dilation. The patch shape can be obtained changing the pattern that dilates.     

Effect of the Twin Jetties as A Regulating Structure at the Tao-er Estuary

The phase one project of the twin jetties at the Tao-er Estuary yields no effect on the flow, and there is a large area of deposition. A numerical model is employed to simulate the flow field, and the scouring and silting in the channel be-tween the two jetties are analyzed. The results show that the effective tidal flux between the two jetties is reduced due to the notch located at the heel of the east jetty, and the effect of contraction-flush is not obvious. As for the regulation of this kind of estuary under the tide action, the capability of tidal flux should be fully used.     

基于GIS的城市交通网络要素可视化表达方法研究

城市交通网络要素的可视化表达是GIS—T研究和应用领域中的一个难题,本文在对目前流行的交通网络数据模型进行系统研究的基础上,选择了动态分段技术下的结点-弧段模型,对交通网络复杂要素进行可视化表达,并对城市交通网络要素的可视化表达方法和形式进行了分析,最后结合交通网络复杂要素的可视化表达,设计和创建了具体的数据结构表和数据结构图。     

基于MAPGIS的市政设施数据模型研究

本文主要介绍了市政基本设施的组成,提出了基于MAPGIS基本数据组织的市政设施数据模型,并讨论了市政设施数据模型的实现。从而,利用该数据组织模型可实现城市级的市政设施管理的综合集成与共享,提高市政设施管理和养护水平。     

网络导航中基于SVG的地理空间数据组织与传输

介绍网络导航服务系统,通过对MapX Mobile、ArcPad和SVG的地理空间数据组织的比较,得出基于Mobile SVG的地理空间数据组织方式优于其它两种组织方式。它不但适合网络导航服务系统的数据交互操作,而且同一图幅的数据量也明显少于MapX Mobile、ArcPad两种格式的数据。然后利用gzip软件包对数据进行压缩,减少数据传输所需的时间。     

Modelling Positional Uncertainty of Line Features by Accounting for Stochastic Deviations from Straight Line Segments

The assessment of positional uncertainty in line and area features is often based on uncertainty in the coordinates of their elementary vertices which are assumed to be connected by straight lines. Such an approach disregards uncertainty caused by sampling and approximation of a curvilinear feature by a sequence of straight line segments. In this article, a method is proposed that also allows for the latter type of uncertainty by modelling random rectangular deviations from the conventional straight line segments. Using the model on a dense network of sub‐vertices, the contribution of uncertainty due to approximation is emphasised; the sampling effect can be assessed by applying it on a small set of randomly inserted sub‐vertices. A case study demonstrates a feasible way of parameterisation based on assumptions of joint normal distributions for positional errors of the vertices and the rectangular deviations and a uniform distribution of missed sub‐vertices along line segments. Depending on the magnitudes of the different sources of uncertainty, not accounting for potential deviations from straight line segments may drastically underestimate the positional uncertainty of line features.