IAGC and IAEA Interlaboratory Comparisons of Geothermal Water Chemistry: The Propagation of Uncertainty in the Reservoir pH Calculation

A statistical evaluation of the results of geochemical analyses of geothermal waters during interlaboratory comparison programmes of the International Association of Geochemistry and Cosmochemistry (IAGC) and International Atomic Energy Agency (IAEA) was performed to estimate the uncertainty of measurement of pH, electrical conductivity, Na⁺, K⁺, Ca2⁺, Mg²⁺, Li⁺, Cl^?, HCO₃^?, SO₄^2?, SiO₂ and B. The uncertainty of measurement was found to increase exponentially with decrease in value (concentration) for all the parameters except for pH, electrical conductivity and SiO₂ and was of the same order of magnitude as the concentrations for values of less than 1 μ ml^?1. There was an overall uncertainty of ± 2.5% in the measurement of pH and ± 30% in SiO₂. For all the other chemical species the uncertainty data were modelled by exponential curves. The sample IAEA14 was prepared by dissolving commercial reagents (i.e., represents a solution of known composition). Thus, the calculated values are considered to be the conventional true values for each chemical parameter. The difference between the measured mean of the data submitted by participating laboratories and the conventional true value for each parameter (i.e., bias of submitted measurements) for the species Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl^? and SO₄^2? was ‐3.5, ‐1.1, ‐13.3, ‐53.6, ‐12.6 and ‐86.6%, respectively. The observed bias was of the same order of magnitude as statistical fluctuations (1s) for Na⁺ and K⁺, but significantly higher for Ca²⁺, Mg²⁺, Cl^? and SO₄^2?. Two methods, uncertainty interval and GUM (“guide to the expression of uncertainty of measurement”) were used to propagate uncertainty in the pH calculation of geothermal reservoir fluid. The application of the methods is illustrated by considering the IAEA10 and IAEA11 samples analysed in the interlaboratory comparisons as separated geothermal waters at atmospheric pressure.     

Analysis, in a free surface steady flow, of the interstitial velocity field inside a sedimentary bed

The objective of our study is to exploit ultrasonic Doppler velocimetry (UDV) to analyze the velocity field within a steady flow on a porous sedimentary bottom. Velocities are measured for several sedimentary beds, as well within the fluid vein as within the sediment. Our results highlight an exponential distribution of the velocities inside the sediment and a discontinuity of the velocity at the interface water–sediment, between the velocity in the free flow and the velocity within the sediment. These results highlight the need to base the analysis of sedimentary transport on the reality of the physical processes at the interface water–sediment.     

Organic contamination identification in sediments from a Mediterranean coastal ecosystem: The case of the Nador lagoon (Eastern Morocco)

The Nador lagoon ecosystem (North-East of Morocco) displays a major socioeconomic interest. In fact, it is essential to evaluate consequences of anthropogenic activities in the lagoon especially by organic matter studies (nature and distribution) in the sedimentary compartment. Surface sediments show variable rates in total organic carbon and in sulfur, high in some cases (7.5 and 1.8% respectively). These high contents are recorded in the center of the lagoon. Their distributions are controlled by the hydrodynamism and the anthropogenic degree. The molecular biomarkers analyses and especially n-alkanes distribution reveal: a zone of marine influence; and a zone of continental influence. The occurrence of pentacyclic triterpanes with a typical distribution of a thermally mature organic matter reveals a contamination due to petroleum products in the entire lagoon except for the center. Coprostanol occurrence near cities indicates wastewater effluents inputs and reducing conditions underlined by high values of stanols/sterol ratios. Thus, the organic contamination (petroleum by-products and wastewater effluents) occurs in the vicinity of the cities whereas the littoral edge and center remain weakly affected by these contaminations.     

Impact ejecta and carbonate sequence in the eastern sector of the Chicxulub crater

The Chicxulub 200 km diameter crater located in the Yucatan platform of the Gulf of Mexico formed 65 Myr ago and has since been covered by Tertiary post-impact carbonates. The sediment cover and absence of significant volcanic and tectonic activity in the carbonate platform have protected the crater from erosion and deformation, making Chicxulub the only large multi-ring crater in which ejecta is well preserved. Ejecta deposits have been studied by drilling/coring in the southern crater sector and at outcrops in Belize, Quintana Roo and Campeche; little information is available from other sectors. Here, we report on the drilling/coring of a section of 34 m of carbonate breccias at 250 m depth in the Valladolid area (120 km away from crater center), which are interpreted as Chicxulub proximal ejecta deposits. The Valladolid breccias correlate with the carbonate breccias cored in the Peto and Tekax boreholes to the south and at similar radial distance. This constitutes the first report of breccias in the eastern sector close to the crater rim. Thickness of the Valladolid breccias is less than that at the other sites, which may indicate erosion of the ejecta deposits before reestablishment of carbonate deposition. The region east of the crater rim appears different from regions to the south and west, characterized by high density and scattered distribution of sinkholes.     

Late Glacial-Holocene sequence of Lake Saint-Point (Jura Mountains, France): Detrital inputs as records of climate change and anthropic impact

A sediment sequence (SP05, 12.5 m long) was taken from the deep zone of Lake Saint-Point (850 m a.s.l.). Sedimentological analyses highlight two main contrasted periods of sedimentation: the Last Glacial Maximum (LGM)/Late Glacial characterized by high silicates and quartz contents the Holocene dominated by the carbonated fraction. At the beginning of the Holocene (11 400 years cal. BP), silicates fraction flux abruptly decreased. The shift between the Late Glacial and the Holocene periods may be explained by forest development in the catchment. From 10 200 to 6800 years cal. BP, silicates and detrital carbonate fractions remained stable before they progressively increased steady till 5000 years cal. BP. Both increases cannot be totally attributed to an anthropic impact since pollen data indicate continuous anthropic activities only dated back from 3000 years cal. BP. They thus resulted from a dominant climatic control. From 5000 years cal. BP, silicates content still increased while detrital carbonates input became steady due to a change in pedogenetic processes affecting the catchment. During the last millennium, silicates and detrital carbonate decreased, probably due to pastureland development.     

Holocene hydrological and vegetation changes in southern France inferred by the study of an alluvial travertine system (Saint-Guilhem-le-Désert, Hérault)

A geobotanical study of the travertine system of Saint-Guilhem-le-Désert (southern France) was carried out in order to reconstruct the local Holocene environment in a region where the postglacial vegetation history is poorly documented. The travertinisation process has started at ca. 8500 cal. BP, in a landscape dominated by Pinus sylvestris type (probably Pinus nigra sub sp. salzmannii). Around 7000 cal. BP, the travertine system recorded torrential events not evidenced at the regional scale, showing the particularity of the Verdus hydrological regime. More recently, ca. 5100 cal. BP, a lake or a marsh was filled within the Verdus plain, as attested to by sand and silt particles accumulated in the sequence. The present-day vegetation dominated by Quercus ilex, on south facing slopes, was most likely established between the Bronze Age and the Gallo-Roman period correlatively to the decline of Pinus nigra and deciduous Quercus, most probably under human influence.     

Preparation and Certification of Biogeochemical Reference Materials

The Institute of Geophysical and Geochemical Exploration in China recently prepared ten biogeochemical certified reference samples GSB1‐10 (CRMs). The samples are primary agricultural products such as rice, wheat, corn, soybean, cabbage, spinach, tea, powder, chicken and apple. Lyophilisation technology and a high‐alumina ball mill were used to process the samples. Fourteen laboratories and hundreds analysts in China participated in the certification analysis. Over ten reliable analytical methods, predominately ICP‐MS, ICP‐AES and INAA, were used for analysing the samples for fifty‐nine elements. A total of 22477 determinations led to 5136 average data sets. Certified values of fifty‐four elements were assigned.     

Apparent/spurious multifractality of data sampled from fractional Brownian/Lévy motions

Many earth and environmental variables appear to be self‐affine (monofractal) or multifractal with spatial (or temporal) increments having exceedance probability tails that decay as powers of − α where 1 < α ≤ 2. The literature considers self‐affine and multifractal modes of scaling to be fundamentally different, the first arising from additive and the second from multiplicative random fields or processes. We demonstrate theoretically that data having finite support, sampled across a finite domain from one or several realizations of an additive Gaussian field constituting fractional Brownian motion (fBm) characterized by α = 2, give rise to positive square (or absolute) increments which behave as if the field was multifractal when in fact it is monofractal. Sampling such data from additive fractional Lévy motions (fLm) with 1 < α < 2 causes them to exhibit spurious multifractality. Deviations from apparent multifractal behaviour at small and large lags are due to nonzero data support and finite domain size, unrelated to noise or undersampling (the causes cited for such deviations in the literature). Our analysis is based on a formal decomposition of anisotropic fLm (fBm when α = 2) into a continuous hierarchy of statistically independent and homogeneous random fields, or modes, which captures the above behaviour in terms of only E + 3 parameters where E is Euclidean dimension. Although the decomposition is consistent with a hydrologic rationale proposed by Neuman (2003), its mathematical validity is independent of such a rationale. Our results suggest that it may be worth checking how closely would variables considered in the literature to be multifractal (e.g. experimental and simulated turbulent velocities, some simulated porous flow velocities, landscape elevations, rain intensities, river network area and width functions, river flow series, soil water storage and physical properties) fit the simpler monofractal model considered in this paper (such an effort would require paying close attention to the support and sampling window scales of the data). Parsimony would suggest associating variables found to fit both models equally well with the latter. Copyright © 2010 John Wiley & Sons, Ltd.     

Photometric study of distant open clusters in the second quadrant: NGC 7245, King 9, King 13 and IC 166

We present a UBV CCD photometric study of four open clusters, NGC 7245, King 9, IC 166 and King 13, located between   l = 90°  and 135°. All are embedded in a rich Galactic field. NGC 7245 and King 9 are close together in the sky and have similar reddenings. The distances and ages are: NGC 7245, 3.8 ± 0.35 kpc and 400 Myr; King 9 (the most distant cluster in this quadrant), 7.9 ± 1.1 kpc and 3.0 Gyr. King 13 is 3.1 ± 0.3 kpc distant and 300 Myr old. King 9 and IC 166 (4.8 ± 0.5 kpc distant and 1 Gyr old) may be metal-poor clusters  ( Z = 0.008)  , as estimated from isochrone fitting. The average value of the distance of young clusters from the Galactic plane in the above longitude range and beyond 2 kpc (−47 ± 16 pc, for 64 clusters) indicates that the young disc bends towards the southern latitudes.     

松辽盆地西缘断裂带中花岗质糜棱岩的锆石SHRIMP和云母氩-氩年龄及其构造意义

松辽盆地西缘发育大型的北北东走向韧性断裂带,该韧性断裂带的性质、活动时限一直存在争议,制约了对松辽盆地构造成因的认识以及松辽盆地西缘油气勘探开发的进展。腾克、金星及嘎拉山地区是松辽盆地西缘韧性断裂带的代表性出露区,主体岩石组合为条带状花岗质糜棱岩、眼球状花岗质糜棱岩等。腾克、金星及嘎拉山地区发育一组糜棱面理和线理,其中面理为110°~135°∠45°~65°、线理为倾伏向10°~25°,倾伏角10°~35°;其运动性质均显示左行走滑特征。确定韧性断裂带活动时限的样品采自构造带内花岗质糜棱岩的锆石和同变形云母,其中锆石SHRIMP谐和年龄为296.9~299.4 Ma;黑云母⁴⁰Ar-³⁹Ar年龄为(123.0±0.7)Ma,白云母的⁴⁰Ar-³⁹Ar年龄为(124.4±0.9)Ma。松辽盆地西缘韧性断裂带应该属于嫩江断裂带的北段。年龄结果表明该韧性断裂带中花岗岩侵位于晚石炭世,大型北北东向韧性构造变形发生于早白垩世。腾克金星嘎拉山剪切带控制松辽盆地西缘,同时表明松辽盆地在早白垩世经历了走滑挤压盆地演化阶段,这种大型北北东向韧性断裂带的形成可能与当时西太平洋伊泽纳崎板块向欧亚大陆俯冲发生转向有关。