铅—试铁灵络合物吸附波及溴化十六烷基三甲基铵增敏效应的研究

在０３０ｍｏｌ／ＬＨＡｃ介质中，Ｐｂ（Ⅱ）与７＿碘＿８＿羟基喹啉＿５＿磺酸（试铁灵，Ｆｅｒｏｎ）的络合物于－０５４Ｖ（ｖｓ．ＳＣＥ）产生一尖锐的极谱波，加入溴化十六烷基三甲基铵（ＣＴＭＡＢ）显著增敏，可使极谱波增高约４倍。峰电流与Ｐｂ（Ⅱ）浓度在９６×１０－９～４８×１０－６ｍｏｌ／Ｌ呈良好的线性关系，检出限为４８×１０－９ｍｏｌ／Ｌ。用多种电化学方法研究了该极谱波的性质及电极反应机理表明，络合物组成比为ｎＰｂ（Ⅱ）∶ｎＦｅｒｏｎ＝１∶１，极谱波为吸附波，峰电流由中心离子Ｐｂ（Ⅱ）还原产生，电子转移数为２。试验了多种离子对峰电流的影响，拟定的方法用于矿样分析，结果与原结果相符。     

地震和测井资料联合反演储层物性参数的方法

为了充分利用测井资料较高的纵向分辨率及其反映井壁周围物性直接准确的特点和地震资料良好的横向可追踪性，针对厚储层和薄储层地震—地质模型分别提出了利用测井和地震资料联合反演纵横波速度和密度参数的方法。理论模型的计算结果表明，反演方法是切实可行的     

Observations of particle movement in a monitoring well using the colloidal borescope

The colloidal borescope consists of a set of lenses and miniature video cameras capable of observing natural particles in monitoring wells. Based on field observations of these particles, it appears possible to measure in situ groundwater velocity in a well bore. Field observations have shown that directional measurements using the colloidal borescope are generally in good agreement with expected flow directions. However, the magnitude of flow velocity is higher compared with values based on conventional test methods. High relative flow velocities, even after correction factors have been applied to compensate for well bore effects, are believed to be due to preferential flow zones in the surrounding aquifer. Low flow zones exhibit swirling multidirectional flow that does not allow for a linear velocity measurement. Consequently, groundwater flow velocities measured by the colloidal borescope in heterogeneous aquifers will be biased toward the maximum velocity values present in the aquifer. A series of laboratory experiments was conducted to assess the reliability of the instrument. Based on this work, a seepage velocity correction factor ( ) of 1–4 was found for quantifying groundwater seepage velocity in the adjacent aquifer from observations in a well bore. Laboratory measurements also indicate that preferential flow in the surrounding aquifer dominates flow in the well. Results of this work suggest the possibility of quantifying higher-flow velocities associated with preferential flow zones in the subsurface.     

Biodegradability of the Anti-tumour Agents 5-Fluorouracil,Cytarabine, and Gemcitabine: Impact of the Chemical Structure and Synergistic Toxicity with Hospital Effluent

Most anti-tumour agents are known to be carcinogenic, mutagenic, teratogenic, embryotoxic or fetotoxic. Only little is known about the environmental impact of pharmaceuticals. Unmetabolized active substances are excreted and will show up in municipal wastewater. Therefore, we examined the biodegradability of the widely used anti-tumour agent 5-fluorouracil (5-FU), also as an example for assessing the impact of hospital effluent on the biodegradation of a test compound. The biodegradability of the structurally similar anti-tumour agents cytarabine and gemcitabine was also examined. Test systems used were the closed bottle test (OECD 301 D) and the modified Zahn-Wellens test (OECD 302 B). 5-FU was not biodegradable in the closed bottle test (CBT) nor in the Zahn-Wellens test (ZWT). At the highest concentration of 5-FU, with hospital effluent an inhibition of the degradation of substances present in hospital effluent was observed, probably as a result of a synergistic effect by 5-FU with antibiotics present in hospital sewage. Gemcitabine was biodegraded 42% in the CBT. The prolongation of the test period to 40 days only improved the result to 45%. In the ZWT, the biodegradation of gemcitabine was 50%. Cytarabine was partially biodegraded in the CBT (50%), but only after an adaptation period of 20 days. After a test prolongation to 40 days, the degree of biodegradation was 80%. In the ZWT, the biodegradability was > 95% after only a few days.     

油田中,高含水期小层剩余油研究

综合利用岩心分析、测井及动态开发资料研究了扶余油田西一、二区北的剩余油分布规律，所研制的油田中、高含水期确定小层剩余油分布图，解决了油田开发中的动态预测小层剩余油分布的难题，并且对１９８２年和１９９２年底的剩余油分布规律作了分析。     

Kinetics of the Gas-Phase Reactions of OH Radicals, NO3 Radicals and O3 with Three C7-Carbonyls Formed From The Atmospheric Reactions of Myrcene, Ocimene and Terpinolene

Rate constants for the gas-phase reactions of OH radicals, NO₃ radicals and O₃ with the C₇-carbonyl compounds 4-methylenehex-5-enal [CH₂=CHC(=CH₂)CH₂CH₂CHO], (3Z)- and (3E)-4-methylhexa-3,5-dienal [CH₂=CHC(CH₃)=CHCH₂CHO] and 4-methylcyclohex-3-en-1-one, which are products of the atmospheric degradations of myrcene, Z- and E-ocimene and terpinolene, respectively, have been measured at 296 ± 2 K and atmospheric pressure of air using relative rate methods. The rate constants obtained (in cm³ molecule^–1 s^–1 units) were: for 4-methylenehex-5-enal, (1.55 ± 0.15) × 10^–10, (4.75 ± 0.35) × 10^–13 and (1.46 ± 0.12) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3Z)-4-methylhexa-3,5-dienal: (1.61 ± 0.35) × 10^–10, (2.17 ± 0.30) × 10^–12, and (4.13 ± 0.81) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3E)-4-methylhexa-3,5-dienal: (2.52 ± 0.65) × 10^–10, (1.75 ± 0.27) × 10^–12, and (5.36 ± 0.28) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; and for 4-methylcyclohex-3-en-1-one: (1.10 ± 0.19) × 10^–10, (1.81 ± 0.35) × 10^–12, and (6.98 ± 0.40) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively. These carbonyl compounds are all reactive in the troposphere, with daytime reaction with the OH radical and nighttime reaction with the NO₃ radical being predicted to dominate as loss processes and with estimated lifetimes of about an hour or less.     

地热井井位确定研究——以豫煤二队院内地热井为例

通过对龙门地热田地质构造、地下水运动特点及规律的研究，提出了在地热田内寻找地下热水的富水靶区，并推算了其范围。又以地面调查、地面电法等手段进行了验证，确定了地下热水富水带的具体位置及地热井施工井位，一次成功地打中千米以下地热水的富水区，为地热田内寻找、开发地下热水总结了经验，丰富了深井及地热田找水的理论。     

测井技术在灰岩地区隧道深孔勘探中的应用

鄂西地区完整灰岩地层的视电阻率、密度、声波、自然伽马等曲线形态受灰岩胶结物质成份和泥质含量影响并具有一定的规律性，当灰岩地层受到构造、溶蚀作用产生破碎带、岩溶、裂隙等不良地质体或存在地下含水体时，各测井物理参数发生变化并在曲线形态上呈现异常反映，据此可以对不良地质体的位置、规模、类型进行准确判断。测井技术在鄂西地区灰岩地区隧道深孔勘探中的应用，补充、验证了钻探资料，为隧道设计、施工提供了可靠的依据。     

应用GMS5多通道云图估计降水技术的研究

对近两年来5～8月中国东部地区120多个测站雨量观测资料和对应4400多幅GMS-5四个通道云图的研究发现：红外亮温的时间、空间变率、红外和水汽通道亮温差等云图衍生资料对消除卷云，弥补夜间缺少可见光云图的不足起到明显作用。从而，应用双判据双重MOS多元回归法建立四通道云图因子、衍生因子与降水量之间的回归方程，进行6小时分级降水估计。为了进一步消除厚卷云和特殊地形的影响，提出使用逐日实时资料自动建立多元回归方程估计降水量，从而对双判据双重MOS多元回归法估计结果进行校正。上海中心气象台的业务使用表明，总体估计的准确率达70％左右。     

98.7湖北特大暴雨的天气分析与降水模拟

1998年7月20～23日，湖北省南部发生了一次持续性特大暴雨过程，采用双向嵌套的非静力中尺度数值模式(MM5)对这次强暴雨过程进行初步模拟试验。结果表明，粗、细网格均能较好地模拟出雨带的走向和变动以及武汉地区的暴雨中心，尤其是嵌套域(细网格)模拟的降水强度比粗网格有明显改进，和实际观测结果更接近；另外，对引发这次特大暴雨的对流层低层的中尺度系统也能够很好地模拟出来。