Photochemistry of N2O4 Adsorbed on Ice Surfaces at 193 nm

A multi-layer deposited ice film was prepared through water vapor deposition on a Ni plate in a vacuum chamber at 90 K, and was used as it was or after annealing at 140 K. NO₂ was adsorbed as N₂O₄ approximately 90 K on the ice film prepared as above, and irradiated by 193 nm excimer laser light. The time-of-flight (TOF) spectra of the desorbed species, i.e., NO₂, NO, O₂ and O, were measured by a quadrupole mass spectrometer. The photochemical process obeyed an one-photon process. The relative yields of the products and their TOF spectra were dependent on the preparation condition of the ice film and also varied with the continuation of the laser irradiation. From the ice film annealed at 140 K, NO₂, NO and O₂ were desorbed with an approximate ratio of 1:1:0.01. From the non-annealed film, the relative yield of NO₂ was much smaller than that of NO. The TOF spectrum of NO from the non-annealed ice film consisted of distinctly different two components corresponding to the 1700 and 100 K translational temperature, respectively. The fast component was lost when additional ice was deposited on the adsorbed N₂O₄. NO was supposed to be a predissociation product from the electronically excited NO₂ prepared through the photodissociation of N₂O₄.     

农田生态系统温室气体排放研究进展

自1985年起,中国科学院大气物理研究所利用自行设计制造的自动观测仪器系统,历时十六年先后对我国四大类主要水稻产区的甲烷排放规律及其与土壤、气象条件和农业管理措施的关系进行了系统野外观测实验,并对稻田甲烷产生、转化和输送机理进行了理论研究,探讨了控制稻田甲烷排放的实用措施,建立了估算和预测稻田甲烷排放的数值模型.在甲烷排放的时空变化规律和转化率研究方面有一系列新的发现,在稻田甲烷产生率、排放率及其与环境条件的关系方面取得一系列新的成果,以充分证据改变了国际上关于全球和中国稻田甲烷排放总量的估算.在对稻田甲     

Fengyun-4 Geostationary Satellite-Based Solar Energy Nowcasting System and Its Application in North China

Surface solar irradiance (SSI) nowcasting (0–3 h) is an effective way to overcome the intermittency of solar energy and to ensure the safe operation of grid-connected solar power plants. In this study, an SSI estimate and nowcasting system was established using the near-infrared channel of Fengyun-4A (FY-4A) geostationary satellite. The system is composed of two key components: The first is a hybrid SSI estimation method combining a physical clear-sky model and an empirical cloudy-sky model. The second component is the SSI nowcasting model, the core of which is the derivation of the cloud motion vector (CMV) using the block-matching method. The goal of simultaneous estimation and nowcasting of global horizontal irradiance (GHI) and direct normal irradiance (DNI) is fulfilled. The system was evaluated under different sky conditions using SSI measurements at Xianghe, a radiation station in the North China Plain. The results show that the accuracy of GHI estimation is higher than that of DNI estimation, with a normalized root-mean-square error (nRMSE) of 22.4% relative to 45.4%. The nRMSE of forecasting GHI and DNI at 30–180 min ahead varied within 25.1%–30.8% and 48.1%–53.4%, respectively. The discrepancy of SSI estimation depends on cloud occurrence frequency and shows a seasonal pattern, being lower in spring–summer and higher in autumn–winter. The FY-4A has great potential in supporting SSI nowcasting, which promotes the development of photovoltaic energy and the reduction of carbon emissions in China. The system can be improved further if calibration of the empirical method is improved.     

4DSVD分析误差与样本选取方法和样本容量的关系初探

分析误差与样本选取方法和样本容量的关系是4DSVD同化方法一个亟需研究的重要问题。获得支撑大气模式空间和观测空间吸引子的基向量是4DSVD研究的关键部分,样本的好坏和样本容量的范围是决定4DSVD基向量和分析结果质量的一个重要前提条件。首先利用Lorenz28变量模式,用4DSVD方法做了一些简单三维同化试验,探讨了Lorenz28变量模式的分析误差与样本容量和样本选取方法的关系。数值试验结果表明,对一个具体的模式,有限的样本容量就能够获得较高精度的分析结果;在模式系统和观测系统不变情况下,用一定样本容量得到的支撑模式空间和观测空间的基向量具有很好的稳定性,即一旦获得一组较好的基向量,在观测系统和模式系统不变的情况下,对同化任何时刻的观测适用;分析结果对选取方法没有太大的依赖性,但具体的样本容量要视不同模式和样本选取方法而定。用WRF模式做的4DSVD四维观测系统模拟试验结果表明,若样本选取方法得当,所需要的样本容量要远远小于模式自由度。4DSVD要真正获得较高精度的分析结果,需要的条件是尽可能的在吸引子上取样并选取充足的样本容量;间隔取样可以一定程度上减少计算量。根据数值试验结果提出了4DSVD在实际同化时样本选取的一些初步的方法。     

Modeling Methane Emissions from Paddy Rice Fields under Elevated Atmospheric Carbon Dioxide Conditions

Methane(CH4 ) emissions from paddy rice fields substantially contribute to the dramatic increase of this greenhouse gas in the atmosphere.Due to great concern about climate change,it is necessary to predict the effects of the dramatic increase in atmospheric carbon dioxide(CO2 ) on CH4 emissions from paddy rice fields.CH4MOD 1.0 is the most widely validated model for simulating CH4 emissions from paddy rice fields exposed to ambient CO2(hereinafter referred to as aCO2 ).We upgraded the model to CH4MOD 2.0 b...     

基于FY-4A卫星和随机森林算法的西藏山南市雷电短临预报方法

针对青藏高原地区雷电短临预报缺乏雷达资料的问题,采用FY-4A卫星多通道数据、欧洲中心第5代再分析资料(ERA5)中的对流指数、闪电定位仪资料等多源监测数据,根据雷电的发生、发展机理,提出了18个关键预报因子,利用随机森林算法建立了适用于西藏山南地区的雷电短临预报模型。统计分析各预报因子在有无雷电天气样本中的概率密度分布与随机森林模型得到的特征重要度指标,结果表明提出的预报因子物理意义明确,建立的模型可信度较高。利用随机森林算法分别对未来10 min、20 min、30 min建立雷电预报模型,并与光流外推预报方法进行对比检验,结果表明：随机森林模型预报效果命中率(POD)、临界成功指数(CSI)均高于光流法,空报率(FAR)也相对较低;未来20 min的随机森林预报模型CSI评分最高,整体预报效果最佳。     

Chlorphenole und Nonylphenole in Klärschlämmen. Teil II: Hat die Belastung mit Pentachlorphenol und Nonylphenolen abgenommen?

Chlorophenols and Nonylphenols in Sewage Sludges. Part II: Did Contents of Pentachlorophenol and Nonylphenols Reduce? Sewage sludges were analyzed for pentachlorophenol and isomeric 4-nonylphenols. These environmental pollutants are not regulated by the German sewage sludge regulations (Klärschlammverordnung) but are subsequently controlled by the pentachlorophenol prohibition ordinance and the industry’s voluntary declaration of renouncing the use of alkylphenol ethoxylates. The samples analyzed originated from sewage treatment plants in the state Rheinland-Pfalz from 1994 till 1995. The analytical results are presented graphically by histograms and numerically by quantiles (median, 90%-percentile).The results are compared to those we formerly obtained from all West German states from 1987 till 1989. To verify the statistical significance of median differences, we used the Wilcoxon test suitable for non parametric data distributions. All histograms show non symmetrical frequency distributions. In almost all 101 analyzed samples, pentachlorophenol was found at a median of 19 μg/kg related to dry matter (d.m.) and a 90%-percentile of 86 μg/kg related to d.m. Compared with the past, there seems to be a tendency to lower values which, however, cannot be proved statistically. In almost all sewage sludge samples, nonylphenols could be found at a median of 4.6 mg/kg related to d.m. and a 90%-percentile of 24.8 mg/kg. In contrast to the past, these values are very low; nonylphenols in sewage sludges have significantly reduced. This may be a hint that the industry’s voluntary dec-laration has been taken seriously.     

Seasonal Variations of CH_4 Emissions in the Yangtze River Delta Region of China Are Driven by Agricultural Activities

Developed regions of the world represent a major atmospheric methane(CH_4) source, but these regional emissions remain poorly constrained. The Yangtze River Delta(YRD) region of China is densely populated(about 16% of China's total population) and consists of large anthropogenic and natural CH_4 sources. Here, atmospheric CH_4 concentrations measured at a 70-m tall tower in the YRD are combined with a scale factor Bayesian inverse(SFBI) modeling approach to constrain seasonal variations in CH_4 emissions. Results indicate that in 2018 agricultural soils(AGS, rice production) were the main driver of seasonal variability in atmospheric CH_4 concentration. There was an underestimation of emissions from AGS in the a priori inventories(EDGAR—Emissions Database for Global Atmospheric Research v432 or v50), especially during the growing seasons. Posteriori CH_4 emissions from AGS accounted for 39%(4.58 Tg, EDGAR v432) to 47%(5.21 Tg, EDGAR v50) of the total CH_4 emissions. The posteriori natural emissions(including wetlands and water bodies) were1.21 Tg and 1.06 Tg, accounting for 10.1%(EDGAR v432) and 9.5%(EDGAR v50) of total emissions in the YRD in2018. Results show that the dominant factor for seasonal variations in atmospheric concentration in the YRD was AGS,followed by natural sources. In summer, AGS contributed 42%(EDGAR v432) to 64%(EDGAR v50) of the CH_4 concentration enhancement while natural sources only contributed about 10%(EDGAR v50) to 15%(EDGAR v432). In addition, the newer version of the EDGAR product(EDGAR v50) provided more reasonable seasonal distribution of CH_4 emissions from rice cultivation than the old version(EDGAR v432).     

Present-day climatology and projected changes of warm and cold days in the CNRM-CM3 global climate model

The impact of global warming on the warmest and coldest days of the annual cycle is explored according to an A2 scenario simulated by the CNRM-CM3 climate model in the framework of the IPCC AR4 intercomparison. Given the multi-model spread in IPCC projections, a validation strategy is proposed using the NCEP/NCAR reanalysis. Validation of the late twentieth century model climatology shows that warm and cold model events are slightly too long and infrequent. Although interannual trends in the warm (cold) day occurrence were positive (negative) only for six (three) of the nine considered sub-continental regions, simulated model trends are always positive (negative). This different behaviour suggests that simulated non-anthropogenic decadal variability is small relative to anthropogenic trends. Large-scale synoptic processes associated with European regional warm and cold peaks are also described and validated. Regional cold peaks are better reproduced than warm peaks, whose intensity accuracy is limited by other physical variables. Positive (negative) winter anomalies of sea and land surface temperature lead to summers with severe (weak) temperatures. These inter-annual anomalies are generated by a persistent pressure dipole over Europe. Regarding climate change, warm (cold) events will become more (less) frequent and longer (shorter). The number of warm days will largely rise and the number of cold days will dramatically decrease. The intensity of warm days will be particularly pronounced over Europe, given the projected summer drying in this region. However, according to the limited skill of the CNRM model, these results must be considered with caution.     

Numerical experiments for Typhoon Dan incorporating AMSU-A retrieved data with 3DVM

Two sets of assimilation experiments on a landfalling typhoon—Typhoon Dan(1999)over the western North Pacific were designed to compare the performances of two kinds of variational data assimilation schemes that are the 3-Dimensional Variational data assimilation of Mapped observation(3DVM)and the 4-dimensional variational data assimilation(4DVar).Results show that:(1)both the 3DVM and 4DVar successfully improved the simulations of typhoon intensity and track incorporating the satellite AMSU-A retrieved temperature and wind data into the initial conditions,and the 3DVM more significantly due to the flow-dependent of background error covariance matrix and observation error covariance matrix like 3-dimensional variational data assimilation(3DVar)circle;(2)inclusions of extra model integration iterations at each observation time in the 3DVM make it more consistent with prediction model;(3)the 3DVM is much more time-saving due to the exclusion of the adjoint technique in it.