酸溶-电感耦合等离子发射光谱法测定密西西比型铅锌矿床矿石中的铅

密西西比型(MVT)铅锌矿床的主要矿物有方铅石、闪锌矿,常伴生有重晶石、萤石等矿物,使得MVT型矿石在酸处理过程中易生成不溶于水和酸的硫酸铅钡复盐,故而检测矿样中铅的含量偏低。本文建立了采用盐酸-硝酸-氢氟酸体系酸溶分解MVT型矿石,电感耦合等离子体发射光谱法(ICP-OES)测定铅含量的分析方法。实验比较了盐酸-硝酸-氢氟酸、盐酸-硝酸-氢氟酸-高氯酸、盐酸-硝酸-硫酸三种酸溶体系的溶样效果,并通过X射线衍射论证了方法的可行性。结果表明,盐酸-硝酸-氢氟酸体系克服了复盐硫酸铅钡和硫酸铅沉淀的生成,适量的氢氟酸促进了Pb SO4的溶解,X射线衍射表征也表明此种酸溶体系的沉淀中不含有Pb SO4,可更彻底地分解MVT型矿石。本方法精密度(RSD)为0.3%~0.6%,实际样品的加标回收率为96.0%~99.2%,铅的最佳检测范围为0.01%~20.0%。     

长岭凹陷深层天然气藏中CO_2及CH_4充注次序的流体包裹体证据

对长岭凹陷深层天然气藏储层——营城组火山岩中发育的流体包裹体进行了详细研究,结果表明在火山岩发育的石英、方解石细网脉中均存在较多的碳质流体包裹体,单个包裹体激光拉曼光谱分析结果表明其主要为CO2及CH4两种类型的碳质包裹体。其中方解石细网脉体中发育有原生及次生CH4包裹体,而含CO2包裹体多以原生包裹体产于石英细网脉中。很多含CO2包裹体的石英细脉中发现了含CH4包裹体的方解石脉体的角砾,这就表明石英细脉形成晚于方解石细脉。营城组火山岩储层中CO2及CH4包裹体的产状特征研究表明,松辽盆地深层天然气藏的形成系火山岩成岩后CO2及CH4等气体不同期次充注的结果,CH4气的充注时间早于CO2气,火山岩中发育的原生孔隙及次生裂隙为上述气体的充注和聚集提供了重要通道。     

2008年汶川地震(Ms8.0)非对称同震破碎带的确定:来自WFSD-1随钻流体的证据

地震过程中相当可观的一部分能量消耗于裂隙的活化与形成,来自汶川地震断裂带科学钻探一号孔(WFSD-1)的随钻流体表明,地震新形成的裂隙对应有较强的流体异常,它们为流体的入侵提供了良好的通道。随钻流体呈非对称性分布于主滑移面的两侧,主要的流体异常带集中在主滑移带下方须家河组顶部120 m范围内,该带中气体的含量以及变动的频率明显高于上部相同的宽度范围以及下部沉积岩层,来自地球物理测井的资料同样显示这一带破碎严重并伴随有大量水的侵入,暗示汶川地震形成的裂隙具有非对称性分布的特征。这一特征可能同时受控于断裂上盘彭灌杂岩与下盘须家河组岩层的力学性质差异以及地震破裂过程中形成的非对称性应力分布。     

Raman Micro-Spectroscopic Study of Sulfate Ion in the System Na2SO4 – H2O

This work aims to quantify sulfate ion concentrations in the system Na₂SO₄-H₂O using Raman micro-spectroscopy.Raman spectra of sodium sulfate solutions with known concentrations were collected at ambient temperature（293 K） and in the 500 cm^₁-4000 cm^-1 spectral region.The results indicate that the intensity of the SO₄^2- band increases with increasing concentrations of sulfate ion.A linear correlation was found between the concentration of SO₄^2-（c） and parameter I₁,which represents the ratio of the area of the SO₄^2- band to that of the O-H stretching band of water（A_s/A_w）:I₁=-0.00102+0.01538 c.Furthermore,we deconvoluted the O-H stretching band of water(2800 cm^-1-3800 cm^-1) at 3232 and 3430 cm^-1 into two sub-Gaussian bands,and then defined Raman intensity of the two sub-bands as A_Bi(3232 cm^-1) and A_B2(3430 cm^-1),defined the full width of half maximum（FWHM） of the two sub-bands as W_B1(3232 cm^-1) and W_B2(3430 cm^-1).A linear correlation between the concentration of SO₄^2-（c） and parameter I₂,which represents the ratio of Raman intensity of SO₄^2-（A_s）(in 981 cm^-1) to(A_B1+A_B2),was also established:I₂=-0.0111+0.3653 c.However,no correlations were found between concentration of SO₄^2-（c） and FWHM ratios,which includes the ratio of FWHM of SO₄^2-（W_s） to W_B1 W_B2 and W_B1+B2(the sum of W_B1 and W_B2),suggesting that FWHM is not suitable for quantitative studies of sulfate solutions with Raman spectroscopy.A comparison of Raman spectroscopic studies of mixed Na₂SO₄ and NaCI solutions with a constant SO₄^2- concentration and variable CI^- concentrations suggest that the I\ parameter is affected by CI^-,whereas the I₂ parameter was not.Therefore,even if the solution is not purely Na₂SO₄-H₂O,SO₄^2- concentrations can still be calculated from the Raman spectra if the H₂O band is deconvoluted into two sub-bands,making this method potentially applicable to analysis of natural fluid inclusions.     

AMT勘查贵州铁(稀土)多金属矿效果分析

贵州铁(稀土)多金属矿资源储量丰厚,但是因其赋存条件的特殊性,勘查具有一定的挑战性,在此开展铁(稀土)多金属矿的物探方法试验研究,对今后勘查工作具有重要的指导意义。这里简要介绍了AMT(音频大地电磁法)工作方法以及贵州威宁秋木构工区的地质和地球物理特征,重点讨论了AMT在秋木构工区铁(稀土)多金属矿勘查中的应用效果,通过对电阻率断面图的综合推断解释,划分出了二叠系宣威组与峨嵋山玄武岩组地层界面,圈出了含矿有利部位。经钻孔验证,取得了良好的找矿效果。     

晚中新世-上新世黄土高原佳县红粘土剖面碳同位素记录与C4植被演化

新生代C4植被开始扩张的年代、过程和驱动机制是全球古气候变化研究的焦点问题.中国黄土高原的黄土-红粘土剖面保存了连续的古生态演化记录,是研究这一关键科学问题的理想载体.本文选择黄土高原北部佳县厚达64m的红粘土剖面(8.2～2.7Ma),对190个层位的次生方解石矿物进行了无机碳同位素测试,由此分析了晚中新世-上新世末的C4植被扩张和演化过程.C4植被持续增长与全球冰盖的扩张基本一致,表明气候变冷很可能导致了黄土高原区域气候的干旱化与降雨季节性的增强.C4植被的扩张存在明显的3个阶段,分别以6.6Ma和3.6Ma为界限,每一次扩张增加10％左右,暗示了全球性的构造事件对黄土高原植被演化的控制.此外,佳县红粘土剖面呈现10次持续时间为10 ～ 20万年的碳同位素正漂移事件,平均每40万年发生一次,说明40万年轨道周期也控制着C4植被的演化.     

黄土高原西部地区黄土地层有机质主要来源分析*

黄土有机质的主要来源是决定其稳定碳同位素(δ13Corg.)能否应用于重建过去C3/C4相对丰度变化及相应的古气候变化的关键基础科学问题.如若黄土地层当中的有机质主要由粉尘携带而来,而非当地植被,显然其δ13Corg.不是一个局地植被过去C3/C4相对丰度变化及古气候变化的良好指示器.本文对黄土高原西部地区(六盘山以西)新获得和已发表的相关数据进行综合分析,尝试对该地区黄土有机质的主要来源进行定量的分析.结果表明,总体而言,该地区黄土地层有机质主要来源于当地植被,由粉尘携带而来的有机质贡献量不超过8％,所造成的有机碳同位素变化幅度不超过1.7‰.这些结果说明该地区的黄土地层有机质δ13Corg.是可以用来重建过去C3/C4植物相对丰度及相应的古气候变化的.为了更精确的重建,后续的工作应当更多考虑粉尘搬运过程当中的有机质输入以及粉尘沉积之后的微生物活动的可能潜在影响.     

EH-4电磁系统在寻找地下水中的应用

EH-4电磁成像系统具有勘查深度大、轻便高效、反映成果直观等特点。在寻找地下水及水文地质方面得到了广泛的应用。为帮助青海省平安县严重缺水南部山区寻找地下水,选用了EH-4电磁系统进行剖面探测,通过确定该区内隐伏断层的位置及断层破碎带,进行构造找水,实践证明:以其他电磁法相比,EH-4电磁成像系统穿透力强、不受浅部高阻层的影响,适用性强、效率高。     

一种面向服务的应用系统智能组装技术

针对目前GIS应用软件所面临的开发难度大、周期长,更新维护困难、扩展性差等诸多问题,秉承面向服务的设计理念,文章提出了一种智能组装式软件开发方式,研究了实现过程中的4个关键技术:用户需求分析、服务智能匹配、自动化组装和人机协同调整机制,并应用NewMap Plat4软件研制开发了原型系统——智能组装器,实现了应用系统的可视化一键式组装开发,使得系统开发变得简单、快捷,且系统具有良好的扩展性。     

Changes in the Geometry and Volume of Rabots glaciär,Sweden, 2003–2011: Recent Accelerated Volume Loss Linked to More Negative Summer Balances

Terminus geometry, ice margins, and surface elevations on Rabots glaciär were measured using differential GPS during summer 2011 and compared with those similarly measured in 2003. Glacier length over the eight years decreased by ～105 m corresponding to 13 m a^?1, a rate consistent with ice recession over the last several decades. Measured changes in surface elevations show that between 2003 and 2011 the glacier's volume decreased by ～27.6 ± 2.6 × 10⁶ m³, or 3.5 ± 0.3 × 10⁶ m³ a^?1. This compares favorably with an estimate of ?28.1 ± 2.6 × 10⁶ m³ based on a mass‐balance approach. The rate of volume loss appears, however, to have significantly increased after 2003, being substantially greater than rates determined for the intervals 1959–80, 1980–89, and 1989–2003. This increase corresponds to a sustained interval of more negative summer balances. Previous work suggests that as of 2003 Rabots glaciär had not yet completed its response to a ～1°C warming that occurred c. 1900, and thus the current marked increase rate of ice loss might reflect the effect of recent, or accelerated regional warming that occurred during the last decade superimposed on its continued response to that earlier warming.