Rate constants for the reactions of the NO3 radical with HCOOH/HCOO− and CH3COOH/CH3COO− in aqueous solution between 278 and 328 K

The kinetics of the aqueous phase reactions of NO₃ radicals with HCOOH/HCOO^– and CH₃COOH/CH₃COO^– have been investigated using a laser photolysis/long-path laser absorption technique. NO₃ was produced via excimer laser photolysis of peroxodisulfate anions (S₂O ₈ ^2– ) at 351 nm followed by the reactions of sulfate radicals (SO ₄ ^– ) with excess nitrate. The time-resolved detection of NO₃ was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO₃ with formic acid (1) and formate (2) rate coefficients ofk ₁=(3.3±1.0)×10⁵ l mol^–1 s^–1 andk ₂=(5.0±0.4)×10⁷ l mol^–1 s^–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k ₁(T)=(3.4±0.3)×10¹⁰ exp[–(3400±600)/T] l mol^–1 s^–1 andk ₂(T)=(8.2±0.8)×10¹⁰ exp[–(2200±700)/T] l mol^–1 s^–1. The rate coefficients for the reactions of NO₃ with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k ₃=(1.3±0.3)×10⁴ l mol^–1 s^–1 andk ₄=(2.3±0.4)×10⁶ l mol^–1 s^–1. The temperature dependences for these reactions are described by:k ₃(T)=(4.9±0.5)×10⁹ exp[–(3800±700)/T] l mol^–1 s^–1 andk ₄(T)=(1.0±0.2)×10¹² exp[–(3800±1200)/T] l mol^–1 s^–1. The differences in reactivity of the anions HCOO^– and CH₃COO^– compared to their corresponding acids HCOOH and CH₃COOH are explained by the higher reactivity of NO₃ in charge transfer processes compared to H atom abstraction. From a comparison of NO₃ reactions with various droplets constituents it is concluded that the reaction of NO₃ with HCOO^– may present a dominant loss reaction of NO₃ in atmospheric droplets.     

Modelling of the vertical fluxes of nitric acid,ammonia, and ammonium nitrate

Results from numerical investigations regarding the exchange of HNO₃, NH₃, and NH₄NO₃ between the atmosphere and the biosphere are presented. The investigations were performed with a modified inferential method which is based on the generally accepted micrometeorological ideas of the transfer of momentum, sensible heat and matter near the Earth's surface and the chemical reactions among these nitrogen compounds. This modified inferential method calculates the micrometeorological quantities (such as the friction velocity and the fluxes of sensible and latent heat), the height-invariant fluxes of the composed chemically conservative trace species with group concentrationsc ₁=[HNO₃]+[NH₄NO₃] (total nitrate),c ₂=[NH₃]+[NH₄NO₃] (total ammonia), andc ₃=[HNO₃]-[NH₃] as well as the fluxes of the individual nitrogen compounds. The parameterization of the fluxes is based on the flux-gradient relationships in the turbulent region of the atmospheric surface layer. The modified inferential method requires only the data of wind velocity, temperature, humidity and concentrations (HNO₃, NH₃, and NH₄NO₃) measured at a reference height by stations of a monitoring network.     

LonGSp: A near infra-red spectrometer

We present a new cooled grating near infra-red spectrometer designed to acquire spectra at the TIRGO telescope in the 0.9÷2.5m region with a resolving power of 300÷4000, equipped with a Rockwell NICMOS 3 detector.     

Automatic equipment to monitor groundwater radon

Prototype instrumentation, able to automatically measure groundwater radon content variations, is presented. The equipment is made of stainless steel and has spherical valves with automatic and pneumatic control. The deemanation of the gases from the water is obtained by evacuating a suitable expansion chamber. The instrumentation can make discrete sampling ranging from 1 per hour to 1 per 99 hours. The equipment was tested in the laboratory: the efficiency was measured by means of a²⁶⁶Ra solution. A mean value of (0.65±0.07) count/s/Bq was obtained. A calibration test was carried out by comparing countings from the automatic equipment with those obtained by the standard laboratory cell. Results of an operational check over a period of approximately one year indicate that variations in radon at the calibration site are attributable more to meteorological than to tectonic causes.     

1983年菏泽5.9级地震前后沂水泉氡的变化

沂水泉位于山东省沂水一汤头断裂带上。多年来的观测分析表明,影响沂水泉氡值变化的最大干扰是降雨。由于这种干扰存在着“记忆”滞后影响,所以用一般的相关分析难以将这种影响排除干净。本文对最小二乘法为建立模型的判据,用动态灰箱分析法拟合并推估观测系统的变化。在分析中用了四个状态变量：长趋势成分Ｌ（ｔ）、年周期变化成分Ｐ（ｔ）、降雨影响部分Ｒ（ｔ）和随机变化部分Ｓ（ｔ）。经过分析表明,沂水泉氡的长趋势部分１     

A Step Towards Evaluation of the Seismic Response Reduction Factor in Multistorey Reinforced Concrete Frames

A seismic nonlinear time-history analysis was made for four-, six-, and eight-storey reinforced concrete buildings. These buildings were made as three-dimensional space frame structures with shear walls in both orthogonal directions. They have five bays with 4.8 m spacing each in the horizontal direction, and three bays with 4.2 m spacing each in the transversal direction. The frames were designed according to the Jordanian Seismic Code of practice for Seismic Zones 4, 3, 2, and 1 as proposed for Jordan by several authors. Time-history analysis was made using the El Centro (N-S) earthquake record of May 1940 as an actual earthquake excitation. The response reduction factor (R) that primarily consists of two factors that are the ductility reduction (Rµ) and the overstrength (), is obtained. It has been seen that the seismic zoning has a slight effect on the ductility reduction factor for different buildings, since it ranges from Zone 4 to Zone 1 as 2.37 to 2.52, 1.72 to 1.78, and 1.14 to 1.18 for four-, six-, and eight-storey buildings, respectively. Moreover, it is observed that, for different buildings and different seismic zones, the ductility reduction factor (Rµ) is slightly different from the system ductility factor (µ) especially for higher values of µ (i.e., Rµ µ). The response reduction factor, called overstrength (), was evaluated. The overstrength factor was found to vary with seismic zones (Z) , number of stories, and design gravity loads. However, the dependency on seismic zones was the strongest. The average overstrength of these buildings in Zones 4 and 1 was 2.61 and 6.94, respectively. The overstrength increased as the number of storeys decreased: overstrength of a four-storey building was higher than an eight-storey building by 36% in Zone 4, and 39% in Zone 1. Furthermore, buildings of the three heights had an average overstrength 165.9% higher in Zone 1 than in Zone 4. These observations have a significant implications for the seismic design codes which currently do not take into account the variation of the response reduction factor, R (i.e., ductility reduction factor times overstrength).     

地震短临综合预报方法的研究

本文在《中国震例》资料基础上,详细分析了华北地区１７次中强以上地震前的短临异常,得到华北地区中强以上地震短临异常的三个综合特征,在归纳出短临异常综合特征的基础上,提出了两个判定孕震过程、前兆异常由中期向短期过渡的定量的综合标志。据中期异常的追踪分析和短临异常综合分析相结合的原则,定义并计算了综合预报指标Ｓ值,以此值作为是否发生中强以上地震的判据。本文的重点是在分析短临异常综合特征的基础上,结合实用     

合肥遥测台网地震速报系统

论述了适用于遥测地震台网大震速报的一套计算机处理系统,系统设计以《全国遥测台网观测技术规范》和《近震分析》理论为依据,实现了数据输入,震相选择,数据处理,地震定位,震级计算,结果输出及贮存等多项功能,达到了快速确定地震三要素,提高速报速度和精度之目的,是一个较完善的,实用的速报系统。     

Possible creep-related tilt precursors obtained in the Central Apennines (Italy) and in the Southern Caucasus (Georgia)

Daily averaged tilt component data from two sites of the Central Apennines (Italy) and of the Southern Caucasus (Georgia), respectively, revealed intermediate-term tilts as possible precursors to earthquakes (M=3.0÷4.7) which occurred in the above-mentioned seismic areas within a distance of 50 km from the sites. A good temporal correlation as well as a fair spatial correspondence between these residual tilts (with amplitude and duration of some microradians and months, respectively) and main shocks were pointed out, by removing both secular trends and seasonal thermoelastic effects from the raw tilts. An attempt was made to justify the above-mentioned results, based on the assumption that the observed intermediate-term preseismic tilts are the manifestation of aseismic creep episodes of comparable duration in the fault materials of thrust faults close to the tilt sites. The mechanism refers to a strain field slowly propagating from the preparation focal area to the tilt site, through crustal blocks separated by weak transition zones. This propagation is thought to be the cause of the local aseismic fault slip recorded by the tiltmeters. Previously, both discrete structures and strain propagation effects were revealed in the Central Apennines and are thought also to exist in the Southern Caucasus. As in the past, the rheological properties of fault materials are revealed as viscoelastic ones. In fact, creep equations obtained by applying several viscoelastic models on our data, proved to fit quite well some of the observed tilt precursors, producing viscosity and rigidity values very similar to those reported in literature.Professor Petr Viktorovich Manjgaladze died during the writing of this paper     

Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.