大气污染物质SO2对雾水酸度的控制作用

主要研究了青岛大气污染物质ＳＯ２对雾水酸度的控制作用，用实测结果统计得到雾得水ＰＨ值与Ｃｓｏ２的经验关系式，青岛、烟台等地雾水ｐＨ值与计算值吻合一致，表明统计关系的合理性。通过对青岛雾水中ＳＯ２清除率的估算，说明在青岛雾期，人为污染物质所占比值越高，其污染物质沉降百分率也越高，存留在大气雾中百分率就愈低。     

南黄海夏季海水pCO2研究Ⅱ--下层海水涌升和长江冲淡水对海-气界面CO2通量的贡献

根据2001年7月对南黄海的大面积调查,研究了南黄海夏季pCO2的分布机制,着重讨论下层海水涌升和长江冲淡水对海-气界面CO2通量的贡献,并给出了南黄海海-气界面CO2通量。研究结果表明:夏季南黄海总体上是CO2的1个弱源,大约向大气中释放45.05×104t C。夏季南黄海表层海水pCO2分布表现出了极大的不均性,其汇区主要由长江冲淡水造成,影响区域占汇区吸收CO2的99.9%;而在源区,下层海水涌升虽然面积较小却占源区释放CO2的35.2%。可见陆架边缘海区源/汇格局的地域差异非常之特别。     

A new approach for predicting the extreme response of structures

In this article a method to estimate the mean upcrossing intensity, μ(u), of a stochastic process is proposed. It is assumed that the stochastic process is a sum of a Gaussian process and a second-order correction term. The method is based on the two-dimensional Saddlepoint approximation. The accuracy of the method is tested on processes having analytical solutions for μ(u). Numerical examples are given where the stochastic process represents (i) the horizontal response of a floating offshore structure in a Gaussian sea, and (ii) the response of a structure subjected to a Gaussian wind velocity process. In addition, the estimates are compared to empirical upcrossing intensities of simulated responses. For case (ii), the obtained μ(u) estimates are compared to estimates obtained by numerical integration.     

Optimum Sample Size to Detect Perturbation Effects: The Importance of Statistical Power Analysis – A Critique

Abstract. The current article describes statistical power analysis as an efficient strategy for the estimation of the optimum sample size. The principle aim is constructively to criticise and enrich the results presented by Mouillot et al. (1999) , who estimate the optimum sample size for evaluating possible perturbations. The authors did not make any reference to statistical power analysis, even though their objective clearly went beyond a simple stock evaluation to assess management strategies in a particular marine ecosystem. Surprisingly, they proposed (a priori) an ANOVA design to test a hypothesis considering both space and temporal scales. However, the authors did not cover important topics related with power analysis and the precautionary principle, both used into environment impact assessment programmes for marine ecosystems. Based on their results and on statistical power analysis, it is demonstrated that the variability (dispersion statistics), a key factor they used to estimate the sample size, is less relevant than the magnitude of perturbation (effect size). Therefore, a greater effort must be devoted to estimate the effect size of a particular phenomenon rather than a desired variability.     

3D gravity modelling for Anyongbok Seamount in the East Sea

A seamount chain with an approximately WNW trend is observed in the northeastern Ulleung Basin. It has been argued that these seamounts, including two islands called Ulleung and Dok islands, were formed by a hotspot process or by ridge related volcanism. Many geological and geophysical studies have been done for all the seamounts and islands in the chain except Anyongbok Seamount, which is close to the proposed spreading ridge. We first report morphological characteristics, sediment distribution patterns, and the crustal thickness of Anyongbok Seamount using multibeam bathymetry data, seismic reflection profiles, and 3D gravity modeling. The morphology of Anyongbok Seamount shows a cone shaped feature and is characterized by the development of many flank cones and flank rift zones. The estimated surface volume is about 60 km³, and implies that the seamount is smaller than the other seamounts in the chain. No sediments have been observed on the seamount except the lower slope, which is covered by more than 1,000 m of strata. The crustal structure obtained from a 3D gravity modeling (GFR = 3.11, SD 3.82 = mGal) suggests that the seamount was formed around the boundary of the Ulleung Plateau and the Ulleung Basin, and the estimated crustal thickness is about 20 km, which is a little thicker than other nearby seamounts distributed along the northeastern boundary of the Ulleung Basin. This significant crustal thickness also implies that Anyongbok Seamount might not be related to ridge volcanism.     

Spatial variability in the partial pressures of CO2 in the northern Bering and Chukchi seas

In the summers of 1999 and 2003, the 1st and 2nd Chinese National Arctic Research Expeditions measured the partial pressure of CO₂ in the air and surface waters (pCO₂) of the Bering Sea and the western Arctic Ocean. The lowest pCO₂ values were found in continental shelf waters, increased values over the Bering Sea shelf slope, and the highest values in the waters of the Bering Abyssal Plain (BAP) and the Canadian Basin. These differences arise from a combination of various source waters, biological uptake, and seasonal warming. The Chukchi Sea was found to be a carbon dioxide sink, a result of the increased open water due to rapid sea-ice melting, high primary production over the shelf and in marginal ice zones (MIZ), and transport of low pCO₂ waters from the Bering Sea. As a consequence of differences in inflow water masses, relatively low pCO₂ concentrations occurred in the Anadyr waters that dominate the western Bering Strait, and relatively high values in the waters of the Alaskan Coastal Current (ACC) in the eastern strait. The generally lower pCO₂ values found in mid-August compared to at the end of July in the Bering Strait region (66–69°N) are attributed to the presence of phytoplankton blooms. In August, higher pCO₂ than in July between 68.5 and 69°N along 169°W was associated with higher sea-surface temperatures (SST), possibly as an influence of the ACC. In August in the MIZ, pCO₂ was observed to increase along with the temperature, indicating that SST plays an important role when the pack ice melts and recedes.     

Design of a 3D Chirp Sub-bottom Imaging System

Chirp sub-bottom profilers are marine acoustic devices that use a known and repeatable source signature (1–24 kHz) to produce decimetre vertical resolution cross-sections of the sub-seabed. Here the design and development of the first true 3D Chirp system is described. When developing the design, critical factors that had to be considered included spatial aliasing, and precise positioning of sources and receivers. Full 3D numerical modelling of the combined source and receiver directivity was completed to determine optimal source and receiver geometries. The design incorporates four source transducers (1.5–13 kHz) that can be arranged into different configurations, including Maltese Cross, a square and two separated pairs. The receive array comprises 240 hydrophones in 60 groups whose group-centres are separated by 25 cm in both horizontal directions, with each hydrophone group containing four individual elements and a pre-amplifier. After careful consideration, it was concluded that the only way to determine with sufficient accuracy the source–receiver geometry, was to fix the sources and receivers within a rigid array. Positional information for the array is given by a Real Time Kinematic GPS and attitude system incorporating four antennas to give position, heading, pitch and roll. It is shown that this system offers vertical positioning accuracy with a root-mean-square (rms) error less than 2.6 cm, while the horizontal positioning rms error was less than 2.0 cm. The system is configured so that the Chirp source signature can be chosen by software aboard the acquisition vessel. The complete system is described and initial navigational and seismic data results are presented. These data demonstrate that the approach of using fixed source-receiver geometry combined with RTK navigation can provide complete 3D imaging of the sub-surface.     

添加纳米TiO2的氯醚树脂的XPS分析

在紫外线老化前后,利用光电子能谱(XPS)研究了分别添加金红石型和锐钛型纳米TiO2的氯醚树脂。研究发现,氯醚树脂中氯、氧元素具有表面富积现象——趋肤效应,而钛和碳元素在内层聚集;添加颜料粒子越小,在表面含量越大;金红石型纳米二氧化钛紫外屏蔽性好,减缓树脂老化;而锐钛型纳米二氧化钛具有显著的光催化活性,加速树脂老化。因此,金红石型纳米二氧化钛将是一种有前途的紫外线吸收剂。     

氨基酸在粘土高岭石上吸附等温线的研究

研究了4种氨基酸（甘氨酸，赖氨酸，天冬氨酸，谷氨酸）在粘土高岭石上的吸附等温线以及金属铜离子对其等温线的影响。研究表明，氨基酸在高岭石上的吸附等温线以及金属铜离子存在时的吸附等温线均属Langmuir型等温线；铜离子浓度增加时，其等温线斜率也增加，并认为体系可形成Ⅰ型三元表面络合物，铜离子对氨基酸在高岭石上等温线影响的规律和在相同体系中它对氨基酸在高岭石上交换吸附百分率E（%）-pH曲线的影响规律相一致。