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981.
Estelle Turpin Christa Fittschen Alexandre Tomas Pascal Devolder 《Journal of Atmospheric Chemistry》2003,46(1):1-13
We have determined the 2-oxo-propyl CH3C(O)CH2 (sometimes called 1-methylvinoxy or acetonyl) radical yield for the reaction of acetone with OH radical relative to the 2-oxo-propyl yields for the reactions of F- and Cl atoms with acetone using the Discharge Flow technique. The 2-oxo-propyl radical has been monitored by Laser Induced Fluorescence LIF at short reaction times in the systems: OH + acetone (R1), F + acetone (R2), and Cl + acetone (R3). From these measurements we have deduced the branching ratio for the 2-oxo-propyl radical formation in the title reaction to be in the range 0.8 11k402407x476/xxlarge8804.gif" alt="le" align="MIDDLE" BORDER="0"> R 11k402407x476/xxlarge8804.gif" alt="le" align="MIDDLE" BORDER="0"> 1. 相似文献
982.
We present a simple statistical model of the water-table fluctuations based on a set of multiple regressions for a dune slack of the Do1;ana National Park, and its utility to understand some ecological processes. The variation in the coefficients of the regressions for different locations allows discrimination between different zones in the dune slack, and explains the spatial pattern of heath vegetation observed in the stabilized sands. Model simulations were compared with an existing sparse data set of water-table levels, and suggests possible mechanisms responsible for the catastrophic pine tree mortality, which happened during the drought of 1979 13;83. 相似文献
983.
Prosopis pallida H.B.K. is one of the most economically and ecologically important tree species in the arid and semi-arid lands of the American continent. Sections of P. pallida were used to describe its wood anatomy and to determine whether annual rings were visible or not. Results showed that P. pallida has well-differentiated annual growth rings and is therefore suitable for dendrochronological studies. Tree ring chronologies correlate well with precipitation events related to El Ni1;o Southern Oscillation phases. A master chronology for the northern area of Peru was built with these data, and some physiological derivations from the anatomy of P. pallida wood are discussed. 相似文献
984.
在283~308K温度范围内测定了NaCl在DMF和1,2-丙二醇混合溶剂中的电导率,根据公式求得NaCl的摩尔电导率值,应用Kohlrausch经验规则,使用Origin软件进行线性拟合,作图外推求得NaCl在DMF和1,2-丙二醇混合溶剂中的无限稀释摩尔电导率λ0值,并讨论了NaCl溶液的电导率、摩尔电导率、无限稀释摩尔电导率与温度和浓度的关系。 相似文献
985.
CLM在淮河流域数值模拟试验 总被引:8,自引:1,他引:8
文中利用 1998年HUCEX资料对CommonLandModel(CLM )的模拟能力进行了验证。结果表明 ,CLM不但能够较好地模拟陆 气间各种能量通量 ,而且还能模拟出土壤中温度的时空分布特征。春季 ,CLM对潜热模拟偏高 ,从而引起土壤温度模拟偏低 ;而在夏季 ,潜热模拟偏低 ,在旱地下垫面由于净辐射模拟偏低使土壤温度的模拟仍然偏低 ,水田下垫面的土壤温度模拟趋向合理。夏季的水田无论在对大气的能量输送还是土壤的温度分布上 ,都有其特殊性 ,需在陆面模式中予以特殊的考虑。 相似文献
986.
Mayuri Inoue Masato Nohara Takashi Okai Atsushi Suzuki Hodaka Kawahata 《Geostandards and Geoanalytical Research》2004,28(3):411-416
Trace elements in the Geological Survey of Japan carbonate reference materials Coral JCp-1 and Giant Clam JCt-1 were determined by inductively coupled plasma-mass spectrometry after digestion with 2% v/v HNO3 . A standard addition method was adopted in this determination in order to neutralise the Ca matrix effect. In addition, Sc, Y, In and Bi were used as internal standards to control the matrix effect and correct instrumental drift. Of the eighteen elements measured in JCp-1, precisions for fourteen elements, including Cu, Cd and Ba, were better than 10% RSD and concentrations ranged from 0.002 μg g-1 (Cs) to 8.02 μg g-1 (Ba). The concentrations of measured trace elements in JCt-1, except for Cu, were lower than those in JCp-1. Precisions for all elements with concentrations higher than 0.04 μg g-1 in JCt-1 were also better than 10% RSD and concentrations were found to be between 0.001 μg g-1 (Cs) and 4.84 μg g-1 (Ba). The concentrations of more than fifteen trace elements in the aragonite reference materials are reported here for the first time. Both reference materials are suitable for use in geochemical studies of environmental reconstruction based upon biogenic carbonate materials. 相似文献
987.
Adam J.R. Kent Benjamin Jacobsen David W. Peate Tod E. Waight Joel A. Baker 《Geostandards and Geoanalytical Research》2004,28(3):417-429
We present data for the concentrations of eleven rare earth elements (La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Er, Yb, Lu) in eleven international geochemical reference materials obtained by isotope dilution multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). We have analysed both rock powders and synthetic silicate glasses, and the latter provide precise data to support the use of these as reference materials for in situ trace element determination techniques. Our data also provide precise measurements of the abundance of mono-isotopic Pr in both glasses and powders, which allows more accurate constraints on the anomalous redox-related behaviour of Ce during geochemical processes. All materials were analysed in replicate providing data that typically reproduce to better than one percent. Sm/Nd ratios in all these materials also reproduce to better than 0.2% and are accurate to < 0.2% and can thus be used as calibrants for Sm-Nd geochronology. Our analyses agree well with existing data on these reference materials. In particular, for NIST SRM 610, USGS BHVO-2, AGV-1 and AGV-2, our measured REE abundances are typically within < 2% (and mostly 1%) of REE concentrations previously determined by isotope dilution analysis and thermal ionisation mass spectrometry, consistent with the higher degree of precision and accuracy obtained from isotope dilution techniques. Close agreement of results between basaltic glass reference materials USGS BHVO-2G and BCR-2G and the BHVO-2 and BCR-2 powders from which they were created suggests that little fractionation, concentration or dilution of REE contents occurred during glass manufacture. 相似文献
988.
Nancy Beller‐Simms 《The Professional geographer》2004,56(2):213-222
This study examines mitigation and preparation activities selected by four county and state governments in anticipation of the 1997–1998 El Ni1;o. It expands the knowledge of how state and local governments plan short‐term projects and mitigate with longer‐term activities in anticipation of a natural hazard. It also provides a preliminary understanding of divergent responses and plans under similar disaster warnings. It outlines stages that governments follow in determining their natural hazard mitigation and preparedness activities. This model should provide hazard planners, particularly those planning for slower onset hazards, with insights into their own local circumstances, allowing them to choose appropriate strategies. 相似文献
989.
ABSTRACT. The Pur1;pecha region of Michoacán State, in west‐central Mexico, has a strong tradition of craft production, especially wooden items. Transportation improvements in the region since the mid‐twentieth century have led to a higher level of integration of the regional economy, yet access to the broader Mexican market remains limited. Towns throughout the region have experienced substantial changes in the types of crafts produced, the extent of their local and external markets, and the location of craft production. Transportation improvements have, in part, led to agglomeration economies and a resultant contraction in the number of different types and an increase in the volume of the crafts produced. Market changes have led to the proliferation of craft storefronts in towns with higher levels of accessibility. Conversely, remote towns still rely heavily on distributors and have not been able to expand their markets. As a result, the region has seen the development of a two‐tiered system whereby towns with increased accessibility have viable craft industries and towns with limited accessibility struggle with stagnant craft industries. 相似文献
990.
上世纪70年代以来,由于雨花台组与其他砂砾层之间接触关系未被发现,南京—仪征地区新近纪地层层序及时代一直存在着争议。笔者对仪征大仪集新仪1孔剖面进行了重新整理划分,新近纪各地层叠置关系明显,同时结合其他剖面及岩相古地理分析,在前人工作的基础上,对新近纪地层层序及时代进行了讨论。该地区新近纪地层层序为中新世中期的洞玄观组(N1d)、中新世晚期的六合组(N1l)黄岗组(N1h)及上新世的雨花台组(N2γ)以及非正式岩石地层单位方山玄武岩(fb)。雨花台组沉积是位于六合组之上的另一套砂砾层,其沉积时代为上新世晚期。 相似文献