全文获取类型
收费全文 | 5303篇 |
免费 | 918篇 |
国内免费 | 1430篇 |
专业分类
测绘学 | 638篇 |
大气科学 | 995篇 |
地球物理 | 1112篇 |
地质学 | 2809篇 |
海洋学 | 914篇 |
天文学 | 302篇 |
综合类 | 381篇 |
自然地理 | 500篇 |
出版年
2024年 | 34篇 |
2023年 | 118篇 |
2022年 | 205篇 |
2021年 | 230篇 |
2020年 | 247篇 |
2019年 | 295篇 |
2018年 | 220篇 |
2017年 | 230篇 |
2016年 | 268篇 |
2015年 | 269篇 |
2014年 | 345篇 |
2013年 | 379篇 |
2012年 | 323篇 |
2011年 | 341篇 |
2010年 | 269篇 |
2009年 | 345篇 |
2008年 | 402篇 |
2007年 | 349篇 |
2006年 | 367篇 |
2005年 | 308篇 |
2004年 | 300篇 |
2003年 | 236篇 |
2002年 | 195篇 |
2001年 | 166篇 |
2000年 | 181篇 |
1999年 | 159篇 |
1998年 | 131篇 |
1997年 | 118篇 |
1996年 | 97篇 |
1995年 | 86篇 |
1994年 | 87篇 |
1993年 | 84篇 |
1992年 | 72篇 |
1991年 | 41篇 |
1990年 | 46篇 |
1989年 | 26篇 |
1988年 | 20篇 |
1987年 | 11篇 |
1986年 | 12篇 |
1985年 | 13篇 |
1984年 | 11篇 |
1983年 | 4篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1954年 | 3篇 |
1877年 | 1篇 |
排序方式: 共有7651条查询结果,搜索用时 0 毫秒
901.
HU Zhikai LI Yi LI Qi DIAO Yujie MA Xin LIU Hejuan FENG Guanhong WANG Fugang YU Qingchun 《《地质学报》英文版》2023,97(3):911-924
Gas breakthrough pressure is a key parameter to evaluate the sealing capacity of caprock, and it also plays important roles in safety and capacity of CO2 geological storage. Based on the published experimental results, we present numerical simulations on CO2 breakthrough pressure in unsaturated low-permeability rock under 9 multiple P-T conditions (which can keep CO2 in gaseous, liquid and supercritical states) and thus, a numerical method which can be used to accurately predict CO2 breakthrough pressure on rock-core scale is proposed. The simulation results show that CO2 breakthrough pressure and breakthrough time are exponential correlated with P-T conditions. Meanwhile, pressure has stronger effects on experimental results than that of temperature. Moreover, we performed sensitivity studies on the pore distribution index λ (0.6, 0.7, 0.8, and 0.9) in van Genuchten-Muale model. Results show that with the increase of λ, CO2 breakthrough pressure and breakthrough time both show decreasing trends. In other words, the larger the value of λ is, the better the permeability of the caprock is, and the worse the CO2 sealing capacity is. The numerical method established in this study can provide an important reference for the prediction of gas breakthrough pressure on rock-core scale and for related numerical studies. 相似文献
902.
Polarized electronic single crystal spectra of natural Fe2+ ion-bearing oxygen-based minerals, in which ferrous ions enter octahedral sites of different symmetry and distortion (olivine,
cordierite, ortho- and clinopyroxene, amphibole), eightfold sites in garnet (almandine) and clinopyroxene (M2), and tetrahedral
sites in spinel, were studied at temperatures from 300 to ca. 600 K. In the minerals studied, the spin-allowed bands of Fe2+ display rather variable temperature behaviour. In most cases, due to the thermal expansion of the Fe2+-bearing polyhedra, bands shift to lower energies upon increasing temperature, though there are some exceptions to this rule:
in cases of other than sixfold octahedral or close to octahedral coordination, in almandine and spinel the bands shift to
higher energies, which can be explained by an increase in distortions of the Fe2+-bearing polyhedra. Splitting of the excited 5
E
g-level of Fe2+ ions usually, but not always, increases with temperature, reflecting thermally induced increase in distortion of the Fe2+-bearing sites in the minerals studied. Integral intensities of the bands in question do not always obey the general rule,
according to which intensity should increase with temperature, when the 3d
N-centred site is centrosymmetric, or should remain unchanged when the 3d
N site lacks an inversion centre. The experimental results show that the response of the characteristics of absorption bands
such as width, intensity and energy caused by dd transitions of Fe2+ in oxygen-based minerals to increasing temperature is not always uniform and is at variance with expectation. This temperature
dependence cannot be used directly to solve band assignment problems, as earlier proposed in the literature.
Received: 22 December 1999 / Accepted: 30 October 2000 相似文献
903.
河流是连接大陆和海洋两大碳库的桥梁,在全球碳循环中的作用举足轻重.金沙江作为长江的上游段,对区域碳循环及区域化学风化的影响非常重要.于2015年8月8-18日对金沙江下游水-气界面CO_2与CH_4通量特征进行监测与分析.采用顶空平衡法结合薄边界层模型估算法计算表层水体CO_2与CH_4的分压以及水-气界面的交换通量,并分析环境变量与其之间的相关性.研究发现,金沙江下游表层水体p(CO_2)平均值为2724.84±477.18μatm,表层水体p(CH_4)平均值为59.96±6.74μatm;水-气界面CO_2通量平均值为2.24±0.50 mmol/(m2·h),CH_4通量平均值为0.000163±0.00009 mmol/(m2·h),通量与分压趋势基本保持一致.表层水体p(CO_2)与溶解性无机碳浓度、碱度均呈显著正相关,而p(CH_4)与水温、叶绿素a浓度均呈显著正相关,CO_2通量与p(CO_2)、溶解性无机碳浓度、碱度均呈正相关,CH_4通量与p(CH_4)、风速均呈正相关,其他环境因素对通量的影响不明显,仍需进一步研究.金沙江下游水-气界面CH_4扩散通量较低,而CO_2扩散通量在世界主要河流中属于中等水平. 相似文献
904.
Changes of atmospheric CO2 concentration since 1958 are shown to be related to sea surface temperature changes. The largest contribution to changes arises from the Pacific equatorial upwelling region, with the Indian Ocean and Atlantic contributing only small fractions to the variance. It is hypothesized that the observed relationship is related to the nutrients that are brought up by upwelling cold water, with photosynthesis contributing to a lowering of the partial pressure of CO2 in the sea and thus to a greater tendency for a flux from the air to the sea.Possible longer term variations of sea temperature and CO2 are discussed. 相似文献
905.
本文介绍了碱金属硼酸盐的一些基本知识,主要回顾了其中Li2O—B2O3体系的研究历史,讨论了该体系结构与性质的关系并总结了Li2O-B2O3晶态及非晶态物质作为新型功能材料的研究进展。 相似文献
906.
1. Introduction The soil moisture plays an important role in in- fluencing the climate change by altering the surface albedo, soil heat capacity and the heat flux between air and land (Ma et al., 2001). Near-surface soil mois- ture controls the partitioni… 相似文献
907.
908.
Accurate modeling of storage of carbon dioxide (CO2) in heterogeneous aquifers requires experiments of the capillary pressure as function of temperature and pressure. We present a method with which static drainage and imbibition capillary pressures can be measured continuously as a function of saturation at various temperature (T) and pressure (P) conditions. The measurements are carried out at (T, P) conditions of practical interest. Static conditions can be assumed as small injection rates are applied. The capillary pressure curves are obtained for the unconsolidated sand–distilled water–CO2 system. The experimental results show a decrease of drainage and imbibition capillary pressure for increasing CO2 pressures and pronounced dissolution rate effects for gaseous CO2. Significant capillary pressure fluctuations and negative values during imbibition are observed at near critical conditions. The measurement procedure is validated by a numerical model that simulates the experiments. 相似文献
909.
910.
通过CaCl2添加剂对KAlSi3O8-CaSO4-CaCO3体系研究反应温度和反应时间的影响研究,结果表明:随着CaCl2加入量的增多,体系的反应温度下降,反应时间缩短,当CaCl2的加入量为10%时,反应温度可降至1000℃,反应时间降至25min,此时KAlSi3O8的转化率仍可高达83.24%。研究CaCl2的加入对KAlSi3O8-CaSO4-CaCO3反应体系动力学过程的影响,得出反应体系符合金斯特林格动力学方程:FK(G)=1-2/3G-(1-G)2/3=KKt,反应受扩散过程控制,计算出当CaCl2的加入量为10%时,体系的表观活化能可从原来的128.921kJ/mol下降至58.320kJ/mol。 相似文献