全文获取类型
收费全文 | 5272篇 |
免费 | 948篇 |
国内免费 | 1428篇 |
专业分类
测绘学 | 636篇 |
大气科学 | 994篇 |
地球物理 | 1112篇 |
地质学 | 2809篇 |
海洋学 | 914篇 |
天文学 | 302篇 |
综合类 | 381篇 |
自然地理 | 500篇 |
出版年
2024年 | 34篇 |
2023年 | 116篇 |
2022年 | 205篇 |
2021年 | 230篇 |
2020年 | 246篇 |
2019年 | 295篇 |
2018年 | 220篇 |
2017年 | 230篇 |
2016年 | 268篇 |
2015年 | 269篇 |
2014年 | 345篇 |
2013年 | 379篇 |
2012年 | 323篇 |
2011年 | 341篇 |
2010年 | 269篇 |
2009年 | 345篇 |
2008年 | 402篇 |
2007年 | 349篇 |
2006年 | 367篇 |
2005年 | 308篇 |
2004年 | 300篇 |
2003年 | 236篇 |
2002年 | 195篇 |
2001年 | 166篇 |
2000年 | 181篇 |
1999年 | 159篇 |
1998年 | 131篇 |
1997年 | 118篇 |
1996年 | 97篇 |
1995年 | 86篇 |
1994年 | 87篇 |
1993年 | 84篇 |
1992年 | 72篇 |
1991年 | 41篇 |
1990年 | 46篇 |
1989年 | 26篇 |
1988年 | 20篇 |
1987年 | 11篇 |
1986年 | 12篇 |
1985年 | 13篇 |
1984年 | 11篇 |
1983年 | 4篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1954年 | 3篇 |
1877年 | 1篇 |
排序方式: 共有7648条查询结果,搜索用时 15 毫秒
61.
用m-氨基苯甲酸作原料,经溴代、重氮化、还原脱氨、酰氯化和酯化反应等步骤,合成了六种新型的三溴苯甲酸的溴代和非溴代芳酯,即;双(2,4,6-三溴苯甲酸)-2',3',5',6'-四溴-1',4'-苯二酯,2,4,6-三溴苯甲酸-2',3',4',5',6'-五溴苯酯,2,4,6-三溴苯甲酸-2',4',6'-三溴苯酯,2,4,6-三溴苯甲酸-4'-溴苯酯,2,4,6-三溴苯甲酸-4'-甲基苯酯和2,4,6-三溴苯甲酸苯酯.通过对产物中碳、氢、溴元素的定量分析以及红外吸收光谱和氢核磁共振谱的研究,验证了合成产物的结构。 相似文献
62.
本文对深水资料浮标中温度传感器的电路原理作了介绍。传感器中的感温元件,采用两端单片集成温度传感器AD590;整个测温电路仅用一片高精度4×1/2位A/D转换器7135;为了能方便地检验和标定温度值,在电路上还设计了温度显示部分,并设计了闭显的功能,以达到省电的目的。 相似文献
63.
64.
以苯酚和4—溴苯甲酸为原料,合成一种尚未见文献记载的新化合物——4—溴苯甲酸—2,3,4,5,6—五溴苯酯,用无水三氯化铝催化苯酚的全溴化。此产物可望在阻燃剂方面得到应用。 相似文献
65.
Shane M. Ohline Malcolm R. Reid Shamus L.G. Husheer Kim I. Currie Keith A. Hunter 《Marine Chemistry》2007
Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25]. 相似文献
66.
研制了 30 0双向自调导叶透平试验机组 ,安装在 10 0 0活塞式往复流透平试验台上 ,对两种叶轮方案和 6种不同喷咀、扩压器进行了不同活塞行程、不同周期和不同恒定输出电压下性能试验。试验结果表明在喷咀出口角α1=2 1 5°、扩压器入口角α2 =6 5 5°和α1=2 4°、α2 =6 3°组合最佳 ,最高效率达 5 3 3% ,而且在宽广流量系数范围内 ,特别是大流量系数范围内都有较高效率。大大优于常用对称翼透平。将上下游导叶固定 ,变成双向固定导叶透平。用No 1叶轮和 6种导叶出口角组合进行试验。表明最佳导叶出口角为 2 4°~ 30°,最高效率仍达 38 5 % ,比对称翼透平仍高许多 相似文献
67.
In order to investigate the relationships between the change of TCO2, △PCO2 and SST, current, upwelling and biological activities during El Nin(~)o event in the subtropical Pacific, the responses of TCO2 and △PCO2 in surface water in the subtropical Pacific during El Nin(~)o and La Nina have been simulated using a three-dimension carbon cycle model with biota pump. The results of numerical simulations show that TCO2 in sea water increases with reducing of SST during mature phase of El Nin(~)o in the subtropical West Pacific . At the same period , the Kuroshio in this region was weakened , the zonal currents were divergence , the upwelling carried the water with high concentrations of CO2 to the sea surface , so both of TCO2 and △PCO2 in surface water were increased . But TCO2 and △pCO2 were decreased during La Nina period. These simulated results confirmed the observations in 1982/1983 , 1986/1987 ,1991/1995 and 1997/1998 El Nin(~)o events . 相似文献
68.
69.
GPS observations of the ionospheric F2-layer behavior during the 20th November 2003 geomagnetic storm over South Korea 总被引:4,自引:1,他引:3
The ionospheric F2-layer peak density (NmF2) and its height (hmF2) are of great influence on the shape of the ionospheric
electron density profile Ne (h) and may be indicative of other physical processes within the ionosphere, especially those
due to geomagnetic storms. Such parameters are often estimated using models such as the semiempirical international reference
ionosphere (IRI) models or are measured using moderately priced to expensive instrumentation, such as ionosondes or incoherent
scatter radars. Global positioning system (GPS) observations have become a powerful tool for mapping high-resolution ionospheric
structures, which can be used to study the ionospheric response to geomagnetic storms. In this paper, we describe how 3-D
ionospheric electron density profiles were produced from data of the dense permanent Korean GPS network using the tomography
reconstruction technique. These profiles are verified by independent ionosonde data. The responses of GPS-derived parameters
at the ionospheric F2-layer to the 20th November 2003 geomagnetic storm over South Korea are investigated. A fairly large
increase in the electron density at the F2-layer peak (the NmF2) (positive storm) has been observed during this storm, which
is accompanied by a significant uplift in the height of the F2 layer peak (the hmF2). This is confirmed by independent ionosonde
observations. We suggest that the F2-layer peak height uplift and NmF2 increase are mainly associated with a strong eastward
electric field, and are not associated with the increase of the O/N2 ratio obtained from the GUVI instruments aboard the TIMED satellite. It is also inferred that the increase in NmF2 is not
caused by the changes in neutral composition, but is related to other nonchemical effects, such as dynamical changes of vertical
ion motions induced by winds and E × B drifts, tides and waves in the mesosphere/lower thermosphere region, which can be dynamically
coupled upward to generate ionospheric perturbations and oscillations. 相似文献
70.