高压下天然菱铁矿的压缩性和电子结构研究

采用同步辐射光源和金刚石对顶砧(DAC)技术,对天然菱铁矿的压缩性和电子结构进行了原位X射线衍射(XRD)和X射线吸收近边结构谱(XANES)测试研究。在室温下随着压力逐渐升高至50.2 GPa,菱铁矿保持方解石型结构不变,但是逐渐向Na Cl型结构转变;刚性[CO3]2-基团平行于ab-平面定向排列使c轴的压缩性大于a轴。菱铁矿在44.6~47.1 GPa之间发生电子由高自旋态(HS)向低自旋态(LS)的转变,表现为体积塌陷8%。HS菱铁矿的等温状态方程参数为K0=112(5)GPa和K'0=4.6(3)。首次采用XANES技术对菱铁矿中Fe2+的电子结构进行了研究,结果表明:随着压力升高至37.3 GPa,Fe2+的配位和局域对称并未发生明显变化;此后电子结构开始转变,Fe2+的3d轨道分裂能降低,电子跃迁概率增大,呈现LS特性。     

The Role of Organic Matter in the Formation of Siderite from Xuanlong Area,Hebei Province

Based on the analysis of siderite distribution,occurrence,chemical compositionk,structureal characteristics,carbon-oxygen isotopic characteristics and relationship between siderite and hematite,this paper presents a systematic study of siderite in the region studied.suggesting that the siderite in the Xuanlong area genetically resulted from organically reduced primary hematite during the diagenesis.The ferric and ferrous relations directly depend on organic contents.In the presence of organic matter ferrous iron can be converted to ferric iron through or ganic reduction.The above conclusion has also been proved by organic geochemistry.data.     

西昆仑切列克其菱铁矿床地质地球化学特征及其对矿床成因的制约

新疆西昆仑切列克其菱铁矿床位于喀喇昆仑造山带的西北缘,处于我国西部著名的塔什库尔干铁矿成矿带内。近年来,切列克其铁矿的地质找矿取得较大突破,在原矿区以北新发现切北菱铁矿,矿床规模已升级为大型铁矿。鉴于该矿床的显著变化,本文拟对新的切列克其大型菱铁矿床成矿地质特征进行总结,通过大量的野外工作、镜下鉴定、矿床地球化学和稳定同位素研究确定矿床成因,为今后该区域同类型矿床的找矿勘查与地质研究工作提供参考。新的切列克其菱铁矿区共包括4个主矿群和北部隐伏矿体群(I、II、III、IV及Fe1~5),共26条矿体,主要赋存于中下志留统达坂沟群的黑云母石英片岩夹白云母片岩以及大理岩段。主矿体呈似层状、透镜状,总体走向近东西向—北西向,倾向北,倾角在22°~30°之间,矿体长度140~605m,平均厚度1.80~39.92m,全铁品位38.00%~47.52%。菱铁矿石构造多样,有代表原始沉积作用形成的块状、层状、条带状或纹层状构造和后期变质及热液叠加作用形成的假波纹、晶洞、脉状和浸染状构造。矿石最主要的结构是自形—半自形粒状变晶结构。矿石矿物主要为菱铁矿(部分被氧化成赤铁矿),矿物含量可达70%~80%或更高;脉石矿物主要为石英(10%~25%)、白云母(3%~5%)和少量黄铁矿、石墨、电气石、磷灰石等。切列克其铁矿的成矿主要经历了沉积成岩成矿期、区域变质改造期和岩浆热液叠加改造三个时期。通过对矿石的地球化学和稳定同位素分析,反映研究区志留纪为陆棚碎屑滨浅海相沉积环境;矿石样品的Al-Fe-Mn图解、轻稀土明显亏损、正Eu异常(δEu为1.54~2.82)、Ce异常不明显(δCe值为0.90~0.99)等均反映矿床具热水沉积特征;菱铁矿的δ~(18) O、δD同位素反映成矿流体叠加成因特点。综合以上因素和对其形成环境的探讨,研究认为该矿床成因属海相热水沉积型,并有后期热液叠加改造。     

泰国湾西部表层沉积物自生矿物分布及组成

Generation, morphology, and distribution of authigenic minerals directly reflect sedimentary environment and material sources. Surface sediments were collected from the western Gulf of Thailand during 2011–2012, and 159 samples were analyzed to determine detrital minerals. Authigenic minerals, including siderite, pyrite, and glauconite, are abundant whereas secondary minerals, such as chlorite and limonite, are distributed widely in the study area. Siderite has a maximum content of 19.98 g/kg and appears in three types from nearshore to continental shelf, showing the process of forming-maturity-oxidation. In this process, the Mn O content in siderite decreases, but Fe_2O_3 and Mg O content increase. Colorless or transparent siderite pellets are fresh grains generated within a short time and widely distributed throughout the region; high content appears in coastal area where river inputs are discharged. Translucent cemented double pellets appearing light yellow to red are mature grains; high content is observed in the central shelf. Red-brown opaque granular pellets are oxidized grains,which are concentrated in the eastern gulf. Pyrite is mostly distributed in the central continental shelf with an approximately north–south strip. Pyrite are mainly observed in foraminifera shell and distributed in clayey silt sediments, which is similar to that in the Yangtze River mouth and the Yellow Sea. The pyrite in the gulf is deduced from genetic types associated with sulfate reduction and organic matter decomposition. Majority of glauconite are granular with few laminar. Glauconite is concentrated in the northern and southern parts within the boundary of 9.5° to 10.5°N and is affected by river input diffusion. The distribution of glauconite is closely correlated with that of chlorite and plagioclase, indicating that glauconite is possibly derived from altered products of chlorite and plagioclase. The K_2O content of glauconite is low or absent, indicating its short formation time.     

云南安宁禄脿小村锰铁矿矿床成因及找矿标志

昆阳群美党组军哨段中亚段第二层砂质板岩为铁锰矿源层,严格受地层层位控制,具有后期改造特征,属沉积—改造—层控矿床。     

西昆仑切列克其菱铁矿床特征及成矿模式

切列克其铁矿是西昆仑地区典型的海相沉积(改造)型菱铁矿床,是前震旦纪基底经长期风化剥蚀的含铁质碎屑物,迁移至阿克赛钦早古生代(早志留世)陆缘沉积盆地沉淀和成岩,经历二叠纪末至中三叠世末古特提斯洋闭合产生的区域变质作用和侵入的花岗岩热液叠加作用改造形成.     

黄铁矿、菱铁矿、白云石在不同气氛下热行为的研究——QDTA/T/EGD/GC在线联用技术(Ⅶ)

应用差热分析(DTA)/逸气检测(EGD)/气相色谱(GC)在线联同技术及其装置,对黄铁矿、菱铁矿、白云石在N_2、Air、CO_2、Air/CO_2气氛下的热行为进行了研究。依据测得的DTA/EGD/DC曲线所提供的信息,探讨了黄铁矿热氧化分解反应历程;鉴定了菱铁矿中的含硫杂质;考察了白云石在N_2、Air、CO_2气氛下的热行为。实验结果表明,把热分析与高灵敏度的逸气检测/逸气分析的联用技术应用于矿物学研究领域中,将更发挥其潜在的优越性和独特的效用。     

油气化探指标与土壤介质中矿物成分相互关系的研究

在油气藏上方化探指标与土壤介质中的矿物成分的对比分析中,不同地区两者间在相关分析、聚类谱系图等方面存在着差异性.不同开发阶段的油气藏上方,化探指标与矿物成分间相关性存在着很大差异性.在油气藏上方的土壤菱铁矿分析中发现,油气藏(开采晚期的油田除外)边缘与油气藏范围内、外的土壤菱铁矿平均含量存在着差异性,油气藏上方及其外围的土壤菱铁矿与热释烃含量存在着不同的特征.