同位素地球化学、岩石地球化学——密坑山锡矿同位素年代学研究的启示

密坑山锡矿田位于江西省会昌县西南约40km处。该区为一晚中生代破火山，火山岩为上侏罗统鸡笼嶂组流纹质凝灰熔岩及火山碎屑岩，火山口周围环状及放射状断裂发育，火山口中心为浅成相的密坑山似斑状钾长花岗岩中央岩株侵入体所充填。上世纪80年代以来，在该岩体与流纹质凝灰熔岩的内外接触带相继发现了岩背、淘锡坝、苦竹岽、矿背、上湾等一批大、中型锡多金属矿床或矿点，表明这一岩体对成矿具有重要的制约作用。     

The ＂CO2-rich gas vents＂ of Mt. Amiata volcano （Tuscany, Central Italy）： Geochemistry,genetic mechanism and hazard evaluation

Mt. Amiata （Southern Tuscany, Central Italy） is an extinct Quaternary volcano located in an area still marked by high heat-flow that is caused by deep seated （6-10 km） hot masses related to Pliocene magmatic activity. The anomalous geothermal gradient gives rise, within the Mesozoic limestone formation （Tuscan series）, to geothermal systems that fed the Ca-SO4 thermal springs characterizing this area. Besides of thermal fluids, several cold, dry CO2-rich gas emissions seep out on the NE flank of the volcano. These gas vents mostly consist of large sub-circular craters at variable depth and diameter （5-15 m and 10-50 m, respectively）, and represent a serious hazard for the local population, as testified by the several asphyxia casualties that have been repeatedly occurred within these morphological depressions. In this work, the chemical and isotopic compositions of the Mt. Amiata ＂CO2-rich gas vents＂ and the estimation of both the CO2 flux from the soil and the CO2 distribution in air of their surroundings, has been carried out in order to： （1） assess the origin of gases, （2） recognize the mechanism of formation for these gas emissions and their relationship with local tectonics, and （3） to evaluate the CO2 hazard in the high flux emanations. The chemical composition of the gases is largely dominated by CO2 （up to 98 % by vol） and shows relatively high concentrations of N2, CH4 and H2S （up to 1.1%, 0.9% and 3.9 % by vol, respectively）. These features, coupled with the carbon and nitrogen isotopic signatures, suggest that the origin of the main gas compounds may be related to the contribution of deep （i.e., thermometamorphic processes on carbonate formations for CO2） and shallow （i.e. thermal decomposition of organic material for CH4, N2 and H2S） sources.     

Geochemistry of recent hydrothermal systems of Mendeleev Volcano （Kuril Islands） and surrounding waters

On the Kuril Islands there are 85 volcanoes, 39 of which are active. Hot springs and mud pots are wide spread in this area and have significant inputs on the chemical composition of the surrounding surface waters and environment. We present results of trace elements as well as data on H, O, S, and He isotope ratios for hydrothermal systems of the Mendeleev Volcano （Kunashir Island） and surrounding surface waters. Water and gas samples were taken from springs and holes as well as creeks and the Lesnaya River. Among the thermal water types, three main groups can be distinguished. The first group includes the waters, in which SO4^- ion predominant. The water temperature on the surface reaches 97℃, and TDS varies from a few g/L to 7 g/L. These waters are acid to superacid with pH values ranging 0.6 to 2.3. The second group is sodium-chloride waters. A maximum TDS is 14.2 g/L. The waters are neutral or alkaline; pH varies from 6.9 to 8.2. The third group is the sodium-chloride-sulfate-bicarbonate water. The Stolbovskie springs, located in the periphery of the Mendeleev Volcano are representative of this type. The pH of these waters is close to neutral. TDS is 1.9 g/L. They are rather the derivatives of sodium-chloride waters arisen from dilution of them by subsurface waters. The Kuslyi Creek and Lesnaya River are located near the Mendeleev Volcano. The most acid springs discharge into the Kislyi Creek as a result pH of this creek being 2.5, and contents of most elements rather high. For example, the contents of dissolved solids of Si, Fe, Al, Mn, Zn, in waters of the Kislaya Creek are 22.1, 8.1, 6.2, 1.29, and 0.28 mg/L, and correspondently. The water of the Lesnaya River, （Before the Kislyi Creek, pH is about 8 with TDS 102 mg/L, but after the Kuslyi Creek, pH decreases and the concentrations of chemical elements increase. Debit of the Kislayi Creek in summer season is about 370 L/sec. It means that every day only this small creek inputs in the Lesnay River about 706 kg of Si;     

Naturally acidic and metalliferous waters at unmined volcanogenic massive sulfide deposits in the Bonnifield mining district, Alaska Range, east-central Alaska

The Bonnifield district hosts 26 tmmined volcanogenic massive sulfide （VMS） occurrences. Environmental geochemical samples of water and stream sediment were collected at several occurrences, concentrating on the two best-exposed and largest deposits, Red Mountain （RM） and Sheep Creek （SC）. Limited samples were also collected at the poorly exposed WTF deposit. The deposits are Late Devonian to Early Mississippian, and are hosted by felsic metavolcanic and carbonaceous schist members of the Totatlanika Schist or Keevy Peak Fm. Spring and stream waters at RM and SC have pH values commonly 〈3.5 （as low as 2.4 at RM and 2.5 at SC）, high conductivity （up to 11000 μS/cm）, and very high （Is to 100s mg/L） dissolved contents of Al, Cd, Co, Cu, Fe, Ni, and Pb. Waters at RM are characterized by extremely high REE contents （summed REE median 3200 μg/L, n=33）. At both RM and SC, pyrite oxidation and dissolution produce low pH waters that interact with and dissolve bedrock minerals, resulting in acidic, metal-laden, naturally degraded streams that are mostly devoid of aquatic life. Ferricrete is common. In contrast, WTF barely produces a surficial environmental footprint, mostly due to topography and relief. RM and SC are well exposed in the areas of relatively high relief, and both exhibit extensive areas of quartz-sericite-pyrite-alteration. While WTF shares many of the same deposit-and alteration characteristics, it is concealed by tundra in a large, nearly flat area. Surface water at WTF is absent and outcrops are sparse. Even though WTF is roughly the same size as Red Mountain （both around 3 million tonnes） and has similar base- and precious-metal grades, the surficial geochemical manifestation of WTF is minimal. However, exposure through mining of the altered, mineralized rock at WTF potentially could initiate the same processes of pyrite oxidation, acid generation, and mineral dissolution that are observed naturally at RM and SC.     

“地震与火山”公开课后的启示

在波澜起伏的教改浪潮中，我尝试开设了“地震与火山”这堂公开课。在备课过程中查寻整理资料、制作修改课件、设计创立课堂流程，自然化了不少心思，然而作为教师的我，在这一过程中所学到的远不止课程本身或其所涉及到的相关领域知识、能力。几次“模拟演习”师生都能按事先设计好的环节逐一展开，当时我感到自然、流畅、顺利，然而在有众多领导、专家、教师在场的公开课堂上，学生、课堂带给我的却是另外一种东西，那是一种感动、一种启示，甚至是一种震撼。课后我及时与学生交流沟通，我想用字表达一下几个方面的感想与启示。     

东准噶尔纸房地区晚石炭世巴塔玛依内山组陆相火山-沉积体系特征

东准噶尔巴塔玛依内山组是典型陆相火山．沉积体系(盆地)，主体由基性及中酸性火山熔岩组成，火山碎屑岩及火山碎屑沉积岩较少，通过对纸房地区晚石炭世巴塔玛依内山组陆相火山岩的岩石化学、地球化学特征进行系统研究，认为它属于造山期后固结初期，新陆壳裂谷向高原火山岩演化的同岩浆源、同沉积盆地、同火山作用的钙碱系列双峰式火山岩．     

伊宁吐拉苏火山盆地热液活动与金成矿关系

吐拉苏火山盆地中与金成矿有关的热液富含K^＋、Na^＋、F、SO4^2-和N2、O2等，是一种主要来源于岩浆．火山的热液，有大气水参于的次生热液．平均均一温度96～158℃，平均盐度0．26％～1．08％，热液活动深度0．26～0．67km，具有低温、低盐度、在地壳浅部活动的基本特征．热液活动生成围绕金矿体由内向外环状展布的黄英岩化、高级泥化、泥化和绿泥石碳酸盐化4个围岩蚀变带．与其有关的金成矿期分为原生沉积富集和次生热液交代蚀变2期，后者包括毒砂黄铁矿化、面状硅化、脉状硅化和绿泥石碳酸盐化4个成矿阶段．金富集成矿主要与黄英岩化蚀变带和面状硅化、脉状硅化2个成矿阶段密切相关．     

青藏高原唐古拉山口第四纪冰碛层划分及其地质环境意义

在对唐古拉山口现代冰川和古冰川考察研究的基础上，结合定位观测资料和TL、^10B-^26Al-^21Ne及^14C测年数据，对区内第四纪冰川遗迹进行了深入讨论，划分出二次冰期(即中更新世晚期的倒数第二次冰期、晚更新世中一晚期的末次冰期)和二次全新世冰进(即新冰期和小冰期)。提出在早更新世时，由于山体未达到当时冰川发育的雪线高度，所以未发育冰川。但在唐古拉山口地区，截止目前还未找到中更新世早期的倒数第三次冰期的冰川遗迹，由于高原隆升的滞后性和冰川发育的延滞效应及“亚洲干极”的耦合，推测仍只发育局部冰川作用。进一步研究表明，古今雪线由高原边缘向腹地升高，唐古拉山地区高出边缘1500m左右，生动表现了“亚洲干极”的作用；广泛分布的湖群说明羌塘地区是一个大江大河尚未伸入的内流地区，意味着青藏高原是个年青的高原。由于青藏高原的隆升，对高原腹地引起的干旱化过程和水分严重不足，使唐古拉山地区的冰川自倒数第二次冰期以来，冰川规模一次比一次明显地减小。     

宁夏山区建设中的岩土工程问题

近年来 ,随着工业和旅游业的发展 ,在宁夏 ,特别是宁南低山黄土丘陵区及银川西侧的贺兰山区 ,一些不适于建筑的山坡、谷地 ,也成为建筑场地 ,随着也带来一系列与环境保护、岩土工程有密切关系的问题 ,如不慎重对待 ,妥善解决 ,必将产生十分严重的后果 ,阻碍山区建设的进一步发展。     

东海陆缘(闽北段)晚第四纪沉积的硅藻学研究

对东海陆缘 (闽北段 )晚第四纪沉积 4口钻井岩心进行系统的硅藻分析研究,获得丰富的硅藻化石,共发现硅藻 117种和变种,分属于 33个属。根据剖面硅藻组合特征变化,结合最优分割法和对应序分法的计算机运算结果,可以详细划分为 12个硅藻带,自下而上为 :1.Cascinodiscusargus-Cos.wittiomus-Cyclotellastriata硅藻带,2.Cos.blandus-Cyclotellastriata硅藻带,3.Cos.excentricus-Trbliepteychuscocconiformis硅藻带,4.Gomphonema-Cos.blandus-Actnolychusralfsii硅藻带,5.Cos.-Cyclotellastriata-Actinocyclusralfsii硅藻带,6.Cos.-Actinolychusralfsii硅藻带,7.贫乏硅藻带,8.Cos.lineatus-Cos.rothii-Actinolyclusralfsii硅藻带,9.Gomphonema-Cyclotellastriata-Cocconeisplacentulavareuglypta硅藻带,10.Cos.rothii-Cyclotellastriata-Actinolychusralfsi,11.Cymbel laaffinis-Cyclotellastriata-Gomphonema硅藻带,12.Coscinodiscuswittinus-Cyclotellastriata-Epithemiahynd manii硅藻带,建立了该区晚第四纪硅藻组合序列,并探讨其相应的古环境演变。