基于泥沙中碳含量的变化表征黄河调水调沙入海泥沙的扩散范围

主要通过黄河口悬浮物中有机碳和无机碳的含量,表征黄河调水调沙入海的泥沙在黄河口外近海的扩散范围。结果表明:黄河口入海前泥沙中的颗粒无机碳(PIC),颗粒有机碳(POC)具有稳定性,分别为(1.75×0.28)%和(0.51×0.08)%;在悬浮物含量约为30 mg/L时,黄河口临近海区悬浮物中的PIC、POC含量分别出现突跃性降低和升高趋势,叶绿素分析表明,POC含量的升高是由于浮游植物对颗粒有机碳贡献的结果,同时正构烷烃轻重比值ΣC₂₀-/ΣC₂₀+和碳优势指数(CPI)值也分别增加和降低;X衍射发现悬浮物浓度低于30 mg/L时,黄河泥沙在悬浮物中所占比例迅速下降,从而造成悬浮物中PIC突跃性下降;因此,黄河口近海悬浮物含量30 mg/L可以被认为是陆源和海源颗粒物对黄河口近海区悬浮物贡献的有效分界线。调水调沙入海的泥沙在黄河口外近海表层主要扩散到河口以南海域,而底层扩散范围主要集中在河口以北和河口以南海域,这些泥沙最终可能停留在莱州湾中部。     

雾水的D和18O同位素研究进展

凝结水的D、¹⁸O同位素研究目前主要集中在雾水方面,露水和土壤吸附水的相关研究仍属空白。由于形成时的温度较高,大多数雾水的D、¹⁸O同位素较当地雨水富集,但不同类型雾的同位素特征存在差异。平流式海洋雾为单级的蒸发—冷凝封闭循环系统的首次凝结,D、¹⁸O同位素较当地雨水显著富集;热带云雾林中的地形雾与降雨同时发生,且水分源于同一云团,δD、δ¹⁸O值差异较小;内陆辐射雾因部分水汽源于当地水分的再循环,过量氘和δD、δ¹⁸O值高于降雨。目前有少量研究用D、¹⁸O同位素指示雾水对植被、地下水和地表径流的补给作用,但以定性分析为主,基于端元混合模型的定量评价极少。露水和土壤吸附水的稳定同位素研究是干旱区凝结水研究的重要方向;D、¹⁸O同位素与其它同位素或化学指标的结合有助于促进凝结水生态水文效应的研究进展;短间隔、高密度的长期观测和用于稳定同位素分析的凝结水采样器的设计是需要进一步开展的工作。     

塔东地区古城4井上寒武统—中、上奥陶统流体地球化学示踪

通过对塔东地区古城4井上寒武统和中、上奥陶统碳酸盐岩围岩及充填物的碳、氧、锶同位素地球化学和流体包裹体成分的对比研究表明,充填于中、上奥陶统和上寒武统的流体分属于2个不同来源的流体体系。充填于中、上奥陶统灰岩裂缝中方解石脉的w(87Sr)/w(86Sr)介于0.7084~0.7088,它与早奥陶世海水的w(87Sr)/w(86Sr)相近;流体体系为CH4-H2O体系;充填物与围岩间具有明显的碳、氧同位素差异,表明上部流体体系中的流体来自于奥陶系地层本身。上寒武统白云岩裂缝中方解石脉的w(87Sr)/w(86Sr)为0.7138,明显地高于同时代海水的锶同位素值;流体体系为CO2-H2O体系;下部流体体系中的流体为外来富锶流体。上、下流体体系间互不连通暗示着上寒武统地层具有相对较好的保存条件。     

西湖茶园茶叶铅污染铅同位素示踪

通过对西湖茶园的植物和土壤样品进行一系列的调查,以着力寻找茶叶的铅污染源。利用铅同位素技术对西湖茶园的土壤、茶叶和城区的燃煤、大气气溶胶、汽车尾气进行铅同位素示踪研究。研究表明,茶园土壤铅物质的可溶相具同源性和残查态偏于多源性。清洗后的茶叶铅含量显著降低,但其同位素组成不发生明显改变,显示出茶叶中的铅与叶面空气沉降物中的铅同源。不同介质铅同位素对比值平均值呈现表土、大气(气溶胶)、煤的w(²⁰⁶Pb)/w(²⁰⁷Pb)与茶叶趋于相近,汽油低之;表土、大气(气溶胶)、汽油的w(²⁰⁸Pb)/〔w(²⁰⁶Pb)+w(²⁰⁷Pb)〕与茶叶趋于相近,煤略高之。不同区域茶叶铅物质具同源性,与种植的农业地质背景无关。在煤燃烧、气化过程中,Pb进入大气,通过大气沉降或被茶树吸收或附着在茶叶叶面;汽车尾气的排放是茶树铅污染的重要原因之一。     

灌注桩钢筋笼内部的磁异常特征

通过分析有限长直立圆柱体内部的磁异常特征,结合模型桩试验,研究了灌注桩钢筋笼内部的磁异常特征,结果表明在钢筋笼内部钻孔中的磁异常Za 垂直分量总体上呈现"两峰夹一谷"的特征,钢筋笼中部呈宽缓的马鞍形负异常,钢筋笼底端位置对应磁异常从极小值转变为极大值的拐点,相应梯度曲线出现极大值.     

Carbon and oxygen isotopic composition of car- bonate cements of different phases in terrigenous siliciclastic reservoirs and significance for their origin： A case study from sandstones of the Triassic Yanchang Formation, southwestern Ordos Basin, China

Early carbonate cements in the Yanchang Formation sandstones are composed mainly of calcite with relatively heavier carbon isotope （their δ^18O values range from -0.3‰- -0.1‰） and lighter oxygen isotope （their δ^18O values range from -22.1‰- -19.5‰）. Generally, they are closely related to the direct precipitation of oversaturated calcium carbonate from alkaline lake water. This kind of cementation plays an important role in enhancing the anti-compaction ability of sandstones, preserving intragranular volume and providing the mass basis for later disso- lution caused by acidic fluid flow to produce secondary porosity. Ferriferous calcites are characterized by relatively light carbon isotope with δ^13C values ranging from -8.02‰ to -3.23‰, and lighter oxygen isotope with δ^18O values ranging from -22.9‰ to -19.7‰, which is obviously related to the decarboxylation of organic matter during the late period of early diagenesis to the early period of late diagenesis. As the mid-late diagenetic products, ferriferous cal- cites in the study area are considered as the characteristic authigenic minerals for indicating large-scaled hydrocarbon influx and migration within the clastic reservoir. The late ankerite is relatively heavy in carbon isotope with δ^13C values ranging from -1.92‰ to -0.84‰, and shows a wide range of variations in oxygen isotopic composition, with δ^18O values ranging from -20.5‰ to -12.6‰. They are believed to have nothing to do with decarboxylation, but the previously formed marine carbonate rock fragments may serve as the chief carbon source for their precipitation, and the alkaline diagenetic environment at the mid-late stage would promote this process.     

Environmental Redox Changes of the Ancient Sea in the Yangtze Area during the Ordo-Silurian Transition

Extensive organic-matter （OM） rich facies （black shales） occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections （Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province） straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon （TOC）, pyrite sulphur, and different species of Fe, including dithionite-extractable Fe （FED）, pyrite Fe （FeP）, HCl-extractable Fe （FeH）, and total Fe （FeT）, in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe （FeHR = FeD ＋ FeP） and FeT, and the FeP/（FeP ＋ FeH） ratio, known as the degree of pyritization （DOP）. In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios （0.20-0.77; avg. 0.45）, high DOP values （0.21-0.72; avg. 0.54）, and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios （0.10-0.35; avg. 0.21）, low DOP values （0.11- 0.40; avg. 0.28）, and SIC values are clustering on the normal marine value （SIC = 0.36）. The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios （0.32-0.49; avg. 0.41）, high DOP values （0.46-0.68; avg. 0.53） and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters     

Isotopes and Geochronology of the Meixian-type Pb-Zn-(Ag)Deposits,Central Fujian Rift,South China:Implications for Geological Events

Central Fujian Rift is another new and important volcanogenic massive sulfide Pb-Zn polymetallic metallogenetic belt. In order to find out the material genesis and mineralization period of Meixian-type Pb-Zn-Ag deposits, S and Pb isotope analysis and isotope geochronology of ores and wall rocks for five major deposits are discussed. It is concluded that the composition of sulfur isotope from sulfide ore vary slightly in different deposits and the mean value is close to zero with the 834S ranging from -3.5‰ to ＋5.6‰ averaging at ＋2.0‰, which indicates that the sulfur might originate from magma or possibly erupted directly from volcano or was leached from ore-hosted volcanic rock. The lead from ores in most deposits displays radioactive genesis character （206pb/204pb〉18.140, 207Pb/204pb〉15.584, 208pb/204pb〉38.569） and lead isotope values of ores are higher than those of wall rocks, which indicates that the lead was likely leached from the ore-hosted volcanic rocks. Based on isotope data, two significant Pb-Zn metallogenesis are delineated, which are Mid- and Late-Proterozoic sedimentary exhalative metailogenesis （The single zircon U-Pb, Sm-Nd isochronal and Ar-Ar dating ages of ore- hosted wall rocks are calculated to be among 933-1788 Ma.） and Yanshanian magmatic hydrothermal superimposed and alternated metallogenesis （intrusive SHRIMP zircon U-Pb and Rb-Sr isochronal ages between 127-154 Ma）.     

川西坳陷中段天然气碳同位素特征及其成因类型

川西坳陷中段天然气的组份以烃类气体为主,占气体总体积的98.1%～99.7%;非烃气体以CO,2和N2为主,其含量分别占气体的0.12%～1.32%和0.25%～1.54%;烃类气体中以甲烷占绝对优势,平均含量为95.83%;重烃含量较低,平均为3.21%;干燥系数(C1/C,1-5>)平均为0.97,整体上属典型的干气.川西坳陷中段的所有样品δ13C,2都大于-25.8‰,属于典型的煤型气范畴,天然气的δ13C,1δ'13C,2δ13C,3,呈明显的正序排列,显示出天然气为典型的有机成因.甲烷碳同位素组成,反映了其母质演化程度已处于成熟～高成熟阶段,且以高成熟阶段为主.     

内蒙古兴安盟杜尔基岩体特征研究

内蒙古兴安盟杜尔基岩体位于大兴安岭中南段,岩性主要为中—细粒二长花岗（斑）岩、中—粗粒二长花岗岩、细粒二长花岗岩。岩石化学分析结果属于碱性岩系列,具有高硅、高钾、富碱、过铝、贫铁、镁、钙特征。稀土元素总量平均值为112．43μg／g,球粒陨石标准化曲线整体平缓右倾,具有Eu负异常;微量元素蛛网图解表现为“W”型形态．具有明显的Sr、Ba、Ti负异常,反映了强烈的分离结晶作用存在。4个样品K-Ar全岩法测年结果为100．15-120．29Ma,说明岩体形成于早白垩世。反映杜尔基地区在早自垩世可能处于相对稳定的拉张环境。