青藏高原影响亚洲夏季气候研究的最新进展

文中回顾了近 10a来吴国雄等在青藏高原影响亚洲夏季气候研究方面的最新进展。通过分析东西风交界面的演变证明 ,由于青藏高原的春季加热 ,亚洲季风区对流层低层冬季盛行偏东风转变为夏季偏西南风最早发生在孟加拉湾东部 ,与其相伴随的激烈对流降水出现在其东面。因此孟加拉湾东部至中印半岛西部是亚洲季风最早爆发的地区。同时也指出盛夏伊朗高原和青藏高原加热所激发的同相环流嵌套在欧亚大陆尺度的热力环流中 ,从而加强了东亚的夏季风 ,加剧了中西亚的干旱 ;并通过其所激发的波动对夏季东亚的气候格局产生重要影响。文中还比较了夏季南亚高压的伊朗模态和青藏模态性质的异同及其对亚洲夏季降水异常分布的不同影响。     

Hydrothermal Mineralization on the Mesoproterozoic Passive Continental Margins of China： A Case Study of the Langshan-Zha＇ertaishan Belt, Inner Mongolia, China

Most ore-forming characteristics of the Langshan-Zha‘ertaishan hydrothermal exhalation belt, which consists of the Dongshengmiao, Huogeqi, Tanyaokou and Jiashengpan large-superlarge Zn-Pb-Cu-Fe sulfide deposits, are most similar to those of Mesoproterozoic SEDEX-type provinces of the world. The characteristics include: (1) All deposits of this type in the belt occur in third-order fault-basins in the Langshan-Zha‘ertaishan aulacogen along the northern margin of the North China Platform; (2) these deposits with all their orebodies hosted in the Mesoproterozoic impure dolomite-marble and carbonaceous phyllite (or schists) have an apparent stratabound nature; ores display laminated and banded structures, showing clear depositional features; (3) there is some evidence of syn-sedimentary faulting, which to a certain extent accounts for the temporal and spatial distribution and the size of the orebodies in all deposits and the formation of intrabed conglomerates and breccias; (4) they show lateral and vertical zonation of sulfides; (5) The Cu/(Pb Zn Cu) ratio of the large and thick Pb Zn Cu orebodies gradually decreases from bottom to top; and (6) barite is interbedded with pyrites and sometimes with sphalerite. However, some characteristics such as the Co/Ni radio of the pyrites, the volcanism, for example, of the Langshan-Zha‘ertalshan metallogenic belt, are different from those of the typical SEDEX deposits of the world. The meta-basic volcanic rock in Huogeqi, the sodic bimodal volcanic rocks in the Dongshengmiao and potassic bimodal-volcanic rocks with blastoporphyfitic and blasto-glomeroporphyritic texture as well as blasto-amygdaloidal structure in the Tanyaokou deposits have been discovered in the only ore-bearing second formation of the Langshan Group in the past 10 years. The metallogeny of some deposits hosted in the Langshan Group is closely related to syn-sedimentary volcanism based on the following facts: most of the lead isotopes in sphalerite, galena, pyrite, pyrrhotite and chalcopyrite plot on both sides of the line for the mantle or between the lines for the mantle and lower crust in the lead isotope composition diagram; cobalt content of some pyrites samples is much higher than the nickel content (Co/Ni= 11.91-12.19). Some volcanic blocks and debris have been picked out from some pyritic and pyrrhotitic ores. All Zn-Pb-Cu-Fe sulfide orebodies in these deposits occur in the strata overlying metamorphic volcanic rocks in the only ore-bearing second formation. In the Jiashengpan deposit that lacks syn-sedimentary volcanic rocks in the host succession only Pb and Zn ores occur without Cu ore, but in the Dongshengmiao, Tanyaokou and Huogeqi deposits with syn-sedimentary volcanic rocks in the host succession Cu ores occur. This indicates a relatively higher ore-forming temperature. The process of synsedimentary volcanic eruption directly supplied some ore-forming elements, and resulted in secular geothermal anomaly favorable for the circulation of a submarine convective hydrothermal system, which accounts for the precipitation of deep mineralizing fluids exhaling into anoxidic basins along the syn-sedimentary fault system in the Langshan-Zha‘ertai rift. The Dongshengmiao, Tanyaokou, and Huogeqi deposits hosted in the Langshan Group appear to be a transitional type of mineral deposit between SEDEX and VMS-types but with a bias towards SEDEX, while the Jiashengpan deposit hosted in the Zha‘ertai Group is of a characteristic SEDEX type. This evidence, together with other new discoveries of Mesoproterozoic volcanic rocks and the features of lithogeny and metallogeny of the Bayun Obo deposit in the neighborhood emphasize the diversity, complexity and uniqueness of the Mesoproterozoic Langshan-Zha‘ertal-Bayun Obo ore belt.     

析取克立格法及其应用的研究

非线性现象普遍存在于许多自然科学的研究之中，线性地质统计仅限于有效数据的线性组合；而某些非线性方法不容易处理，如条件期望的前提条件苛刻，计算复杂耗费大；析取克立格法（DK）介于两者中，利用二元概率分布函数进行估计，更有效、准确且易实现，并能很好地估计 Z（ x）的任意函数，解决可回采储量估计等现实问题。介绍了DK方法的基本理论和方法及其应用，并给出了计算实例。     

洛川黄土剖面中矿物固定态铵的分布

对洛川黄土中的固定铵进行了初步分析。结果表明,在所测定的黄土古土壤层中,固定铵态氮含量在130-1之间变化。黄土中的固定铵态氮含量明显低于古土壤。13万a以来洛川黄土剖面中固定铵的分布呈～210现三次大的低高值的振荡特征,即末次间冰期S1古土壤中固定铵态氮含量最高,其次为冰后期的S0古土壤层,末次冰期形成的马兰黄土中固定铵态氮含量最低;在马兰黄土中同样体现出三次小的低高值的波动特征。黄土与μm组分的分布具有相似性,这些特征反映了洛川黄土中固定铵态氮的含量变化与气互层的古土壤中固定态铵的分布与黄土高原区气候的冷暖变化有较好的一致性,并且13万a以来洛川黄土剖面中固定铵的分布与磁化率和<2候条件有紧密的联系,揭示了黄土中固定铵的变化在一定程度上能指示黄土高原区古气候的演变。     

加卸载响应比（LURR）、矩／能量加速释放（AM／ER）、态矢量：岩石试件破坏前兆的实验研究

为了验证大地震发生前或者非均匀脆性介质宏观破坏前加卸载响应比和能量加速释放等前兆现象，本文进行了三轴应力(压缩)条件下大尺度岩石破坏声发射实验。实验采用4组岩石试件，并且分为单调加载和循环加载两种方式。实验结果证明了脆性材料宏观破坏前加卸载响应比升高和能量加速释放这两种前兆现象。本文提出了一种描述岩石试件损伤演化的新的物理量——态矢量。     

Water soluble components of PM10 Chongqing, China

The concentrations of water soluble ions (Na⁺, NH₄ ⁺, K⁺, Mg²⁺, Ca²⁺, NO₃ ^-, Cl^-, and SO ₄ ^2- ) in PM₁₀ samples collected on cellulose filters by a medium-volume cascade impactor were determined, which were obtained from three kinds of areas in Chongqing: industrial area (Jiulongpo district), commercial and residential area (Jiangbei district) and background area (Jinyun Mountain in the Beibei district). The results showed that except for the background site, the annual average values of PM₁₀ are 23% – 61% higher than the national air quality standard (GradeII) (0.1 mg/m³), even that the value of the control site is still 20% higher than American standard (0.05 mg/m³). This implied that serious pollution of fine particles occurred in Chongqing. Nine kinds of soluble ions in water of PM₁₀ were analyzed by ion chromatography (IC) and the annual average concentrations follow the order of [SO ₄ ^2- ] > [NO³ _-] > [Cl^-] > [F^-], and [Ca²⁺] > [NH₄ ⁺] > [K⁺] > [Na⁺] > [Mg²⁺]. Their values were different in these areas: the industrial area > the commercial and living area > the control area. As for NH_{4 +}, K⁺, Ca²⁺, NO₃ ^- and SO ₄ ^2- , their seasonal average concentrations show a similar variation trend: the values in spring and fall were higher than those in summer and winter. The seasonal average concentrations of [Cl^-], [F^-], [Na⁺] and [Mg²⁺] are much lower than those of other ions. However, the concentrations of [Na⁺] changed more greatly in different seasons than those of the other three ions. Correlation coefficients showed that the three areas have been polluted by coal smoke and dust to different extents, while some local resources of pollution should be taken into consideration as well.     

Rb2Ca[B4O5(OH)4]2·8H2O溶解及相转化过程的研究

利用IR光谱和Raman光谱等实验手段,对25℃时Rb2Ca[B4O5(OH)4]2·8H2O的溶解及相转化过程进行了初步探索,结果表明,Rb2Ca[B4O5(OH)4]2·8H2O溶于水后,硼在溶液中主要以B(OH)3和[B(OH)4]-的形式存在,残留固相由开始的无定形水合三硼酸钙,最终部分转变为Ca2[B3O3(OH)5]2·8H2O晶体。     

珠江三角洲地区重大短时强降水的基本流型与环境参量特征

为了了解珠江三角洲(简称珠三角)地区重大短时强降水(小时雨强≥50 mm)发生的环境特征,利用珠三角地区稠密自动气象站资料、探空资料、卫星资料等分析研究了近7年(2007—2013年)68个重大短时强降水事件的环境流型、T-lnp图形态和关键物理参数,结果表明珠三角地区重大短时强降水天气流型主要有台风型、西南季风型、北部湾低压型、冷(式)切变线型和热带云团型等5种;不同类型、不同季节出现的频率不同。台风型、西南季风型和北部湾低压型的大多数过程T-lnp图温度廓线和湿绝热线很接近,整层水汽含量丰富,对流有效位能(CAPE)大致呈"瘦弱"的狭长形形态;冷(式)切变线型温湿廓线呈上干下湿分布,CAPE大致呈较"胖"的狭长形;热带云团型温度廓线和湿绝热线很接近,CAPE形态较"胖"。850~500 hPa间温差△T_(85)都较小,一般在21~23℃,大气层结接近于湿中性层结,呈现弱的条件不稳定层结,表明大多数过程中有利于重大短时强降水发生的环境条件的关键点不是强对流预报中常关注的"高空冷空气的侵入",而是低层暖湿气流的输送;地面露点一般在23~25℃,暖云厚度在4100 m以上;大多数重大短时强降水发生前大气可降水量都在57 mm以上,其中台风型最大,其次是西南季风型、北部湾低压型、热带云团型,冷(式)切变线型最小,台风型、西南季风型、北部湾低压型CAPE一般小于1500 J·kg~1,属于比较温和的CAPE值,冷(式)切变线型、热带云团型平均CAPE≥1700 J·kg~(-1);对于所有类型对流抑制能(CIN)≤50 J·kg~1;除热带云团型外,大多数过程出现了低空急流;五种流型配置下,台风型、西南季风型大多处在弱到中等的0~6 km深层垂直风切变环境中,北部湾低压型和热带云团型处在弱的0~6 km垂直风切变环境中;冷(式)切变线型大多数过程处在中等强度的0~6 km垂直风切变环境中。可以将流型配置方法(分型)、重大短时强降水对应的关键环境参数以及根据箱线图展示的参数范围设定适宜的阈值的方法相结合,为珠三角地区显著强降水预报的改进提供有价值的参考。     

高频地波雷达海杂波背景下的船只目标检测研究进展

针对海杂波对高频地波雷达目标检测的干扰问题,分目标处于海杂波谱区之内和之外两种情况综述了海杂波背景下的目标检测方法。对于海杂波内目标检测的难题,介绍了一种基于现场海态同步观测信息的检测新思路以及初步验证结果。对国内外相关研究进展的归纳总结和新思路的提出,为提出更加有效的海杂波干扰下的目标检测方法提供了重要的参考。     

水和水蒸气辅助粗晶三水铝石转化为勃姆石的机制研究

在165℃、175℃、185℃和195℃的温度条件下,对水热处理前和处理后的粗晶三水铝石样品分别进行了XRD分析和SEM表征,研究了粗晶三水铝石在水蒸气和热水中转变成勃姆石的相变过程。结果表明,水热条件下粗晶三水铝石转化成勃姆石的过程受控于溶解-再沉淀机制,而并非是通常认为的固体状态下的转变;相对于在热水中,水蒸气环境可以加速三水铝石向勃姆石的转化;所形成的勃姆石的粒径（4~7 μm）明显比前驱体三水铝石的粒径（120~200 μm）要小得多,表明可以利用粗晶三水铝石生产微晶勃姆石。在转化过程中,勃姆石微晶首先生长在三水铝石的晶体表面上,通过控制反应温度和反应时间,可形成壳层为勃姆石、壳下为三水铝石的具有双层结构的铝的氢氧化物颗粒,也有可能形成具有中空结构的勃姆石集合体颗粒。