硫氰酸盐光度法测定地质岩石矿物中的三氧化钨

试样经Na2O2熔融,在3～4mol/L的HCl介质中,以TiCl3为还原剂,将W 6还原为W 5,并与SCN-作用生成稳定的黄色络合物,借此进行光度测定,该络合物采用721分光光度计在430nm处测定,有最大吸收,此方法灵敏度高,重线性好,适用于地质样品中ω(WO3)/10-2=0.03～5.0的测定。     

地质样品中痕量钯的测定

一、方法提要 钯在地球化学样品中的含量低,且存在“粒径效应”,分析时为了使其具有代表性,一般都要求最小取样量在10．0g以上。试样经盐酸加过氧化氢进行分解后,加热除去过量的过氧过氢。过滤,最后试液体积100ml,试液酸度10％,用负载了三正辛胺的泡塑吸附。泡塑经灰化后光谱法测量。方法检出限可达0．5ng／g。     

有机质对海底沉积物中粘土矿物X射线衍射分析结果的影响

X射线衍射法广泛应用于分析粘土矿物的含量和结晶特征,由于粘土矿物易与有机质结合形成有机-粘土复合体,是否去除有机质对分析结果有很大影响,实验结果表明影响最大的是伊-蒙混层矿物(含蒙脱石)和伊利石的含量,为得到可靠实验数据,必须重视对样品的前处理工作,对不同批次样品应该保持一致的处理程序。     

环境样品中甲基汞的检测方法综述

综述了常用的环境样品中甲基汞的检测方法和检测步骤,认为在实际的甲基汞检测过程中,选择或评价所选用检测方法的原则通常是,在确保检测限的基础上,首选考虑检测结果的精确度如何,而快捷方便、经济实惠的检测技术也是现实运用中的实际需要。作为定量检测,GC分别与AAS、AES、AFS的联用是目前较常用的技术,而与ICP-MS或ID-ICPMS的联用,在今后的实际检测中将得到更广泛的运用。生物传感器检测到的汞一般是生物可利用的汞,降低其检测限并将其作为对污染水体与沉积物检测的重要方法,也是今后研究的重点。总之,在人类对环境安全和身体健康日益重视的今天,发展高灵敏度、高准确度、快速方便和低成本的检测技术是未来甲基汞检测的重要发展方向。     

“大洋一号”船首次成功实现海底深孔钻探

9月28日～10月上旬,“大洋一号”船圆满完成了南海海试第一航段调查任务。其间,在我国东沙海域1740m海底成功获取深孔岩心样品,实现了中国大洋人海底深孔钻探的梦想,并创下了15．7m的深孔记录。据悉,本次深钻试验在国内是首次,填补了我国深钻领域的空白。     

挪威近海Storegga滑坡侧翼麻点的成因及烟囱构造

1 Storegga滑坡崖地质背景 挪威的陆缘形态以Storegga滑坡崖为标志,该滑坡崖是由一系列巨大的全新世陡坡崩塌形成的.14C测年证实,最近一次崩塌出现在约7.2 ka以前.     

情洒地矿 岁月如歌——黑龙江省第六地质勘察院五十年发展纪实

光阴似箭,岁月如梭。黑龙江省第六地质勘察院已经走过了五十年的风雨历程。半个世纪以来,一代又一代六院人,攀陡崖、钻深山、涉险河,用坚实的脚步踏遍龙江广阔大地;一代又一代六院人,跑路线、定岩性、采样品,用汗水和智慧为国家探寻地下的宝藏。他们把激情洒在了原野深山,把忠诚写在了天边云霞,唤醒了沉睡已久的无尽宝藏,铸造了黑龙江省第六地质勘察院的不朽丰碑。     

Application of matter-element model in soil nutrient evaluation of ecological fragile region

On the basis of the soil environment investigation in Da'an City, Jilin Province, China, 40 soil samples from main land use types were obtained and tested by standard method. Soil organic matter (SOM), total N (TN), total P (TP), total K (TK), available N (AN), available P (AP) and available K (AK) were chosen as the evaluation factors. A regional soil nutrient evaluation model was developed based on the matter-element model. The results show that the soil samples with nutrient grade Ⅱ-Ⅴ respectively account for 10%, 30%, 32.5% and 27.5%, and those with grade Ⅳ and Ⅴ account for 60% in all samples. The relationship between soil nutrients and land types indicates that the nutrients of farmland are relatively good, with 41.7% of soil samples with the nutrient grade Ⅳ and Ⅴ. The nutrients of saline-alkali land and sandy land are the worst, with 100% of soil samples with the nutrient grade Ⅳ and Ⅴ. And the ratios of soil samples grade Ⅳ and Ⅴ in grassland and wasteland are respectively 62.5 % and 54.55%. Generally speaking, the soil nutrients status in Da'an City is poor, 60% of soil samples are in poor and extremely poor conditions, indicating that the soil has been severely eroded. Being a relatively superior evaluation method with more accurate resuits and spatial distribution consistency, matter-element analysis is more suitable for regional soil nutrient evaluation than previous models.     

ICP-MS测定生物样品中的微量金属元素

采用SP-60型恒压消解罐消解生物样品,用ICP-MS测定8种金属元素(Mn、Zn、Pb、La、Ce、Mo、Cr和Fe)的质量分数。依据分析结果,比较了消解程序的效果。结果表明,由10.0 mLHNO3对生物样品具有很好的消解能力,各元素的测定值与推荐值相符。     

Spatial variability of soil nutrients in Punta Fort William,Greenwich Island,maritime Antarctic

This study aims to report baseline soil nutrients, specifically the organic carbon, nitrogen and phosphorus profile, in soil samples collected from Puntta Fort William on Greenwich Island in maritime Antarctic. Samples were collected along two transect lines during the early summer of 2008. Ward＇s method of hierarchical agglomerative clustering was employed to group the sampling points based on their physico-chemical properties. In this context, the soil samples can be grouped into three major clus- ters： （1） Samples with intensive biological activities, （2） samples from the area recently exposed by glacial retreat and （3） samples from barren and dried areas. Nutrient contents in Punta Fort William are driven by the intensity of biological activities as well as melt water from the Qnito glacier.