高效液相色谱法测定奥沙利铂注射液中奥沙利铂的含量和有关物质

建立以高效液相色谱法测定奥沙利铂注射液中的奥沙利铂有关物质和含量的方法,以碳十八烷基硅烷键合硅胶为填充剂,规格250 mm×4.6 mm,粒径5 μm,以水-甲醇(90∶10)为流动相,流动相用0.45 μm的膜过滤,紫外检测波长为250 nm.奥沙利铂在50～1 600 μg/ml的浓度范围内,峰面积与浓度呈线性关系,线性曲线方程为A=3 650.9 C+17.095(r=0.9999),最低检测限为1.2 ng.加样平均回收率为99.4%(RSD=0.81%,n=9).本方法简便、灵敏、准确,可用于奥沙利铂注射液中的有关物质和含量的控制.     

被动源海底地震仪数据预处理技术构建与应用

被动源海底地震仪(OBS)探测是海洋深部结构研究的重要方法之一.受投放区洋流、海底地形崎岖,以及海底温压环境等多种因素影响,OBS数据预处理面临时钟漂移,姿态及水平方位角偏差等问题.本文基于国产OBS硬件结构特点与其观测数据特性,针对仪器姿态校正、时间校正和水平方位角校正三个关键环节构建技术解决方案.通过硬件架构特征构建仪器姿态校正方案;结合仪器记录的石英晶振特点和背景噪声互相关方法提出时间校正技术;基于最小化P波切向分量能量和P波主成分分析两个技术方法进行水平方位角校正.上述预处理技术体系在苏拉威西海域被动源OBS数据预处理中取得了良好的应用效果,综合背景噪声水平与地震信号的时频分析结果,表明该预处理技术能有效提高被动源OBS观测数据质量,为进一步的科学研究奠定坚实基础.     

Color-Redshift Relations and Photometric Redshift Estimations of Quasars in Large Sky Surveys

With a recently constructed composite quasar spectrum and the X2 minimization technique, we describe a general method for estimating the photometric redshifts of a large sample of quasars by deriving theoretical color-redshift relations and comparing the theoretical colors with the observed ones. We estimated the photometric redshifts from the 5-band SDSS photometric data of 18678 quasars in the first major data release of SDSS and compared them with their spectroscopic redshifts. The difference is less than 0.1 for 47% of the quasars and less than 0.2 for 68%. Based on the calculation of the theoretical color-color diagrams of stars, galaxies and quasars both on the SDSS system and on the BATC system, we expect that we would be able to select candidates of high redshift quasars more efficaciously with the latter than with the former, provided the BATC survey can detect objects with magnitudes fainter than 21.     

煤层瓦斯含量井下直接测定的应用研究

瓦斯灾害是煤矿生产中威胁最大的自然灾害之一,而瓦斯含量测定是防治瓦斯灾害事故的重要基础.由于间接法测定煤层瓦斯含量工程量大、耗时长,已不能满足煤矿生产的需要,自2008年采用瓦斯含量井下直接测定技术.根据直接测定与间接法测定结果的对比发现,直接法测定用时短、操作简便、布点密度高,且误差在10％以内,瓦斯含量值与K1值有较好的正相关关系,采用此法预测煤层区域突出危险性是可行的.     

原子荧光光谱法直接连续测定化探样品中的As Sb Bi Hg

研究了还原性介质中原子荧光光谱法直接连续测定化探样品中Ａｓ、Ｓｂ、Ｂｉ、Ｈｇ的方法。按拟定的条件进行测定,各元素的检出限分别为Ａｓ２．９×１０－９、Ｓｂ１．３×１０－１０、Ｂｉ１．８×１０－１０、Ｈｇ５×１０－１１。应用于区域化探扫面工作中,效果良好。     

沈阳地震台大震速报震级差分析

利用沈阳台测算震级与国家台网速报标准震级进行比较,寻找存在震级差的原因,分析得出,台站测算震级存在误差的原因主要有震中距,方位角,地震震级等。     

江苏地区渗流方位角变化特征分析

利用谐波振幅和峰谷值2种方法,计算江苏地电台站渗流方位角,并尝试利用渗流方位角进行映震分析,结果表明：①使用2种方法计算的渗流方位角相差不大,由此所得地震对应关系应基本可靠;②高邮地电台渗流方位角与高邮-宝应M_S 4.9地震对应关系较好。因此,对江苏地区开展渗流方位角变化特征分析具有一定意义。     

遥测地震台网记录限幅时速报震级的估算

以遥测地震台网大量的观测资料为基础，拟合了限幅时间t的对数与近震震级ML的线性回归关系，结果显示二者有很好的相关性，相关系数为0．967，标准误差为0．2121。检验证实结果是可靠的。得出当台网记录限幅时，采用这种方法快速估算震级进行速报是可行的结论。     

浙江省测震观测台网井下地震计方位角检测与校正

选取浙江省测震台网景宁、北仑、南麂岛地震台井下地震计观测数据,采用地震数据波形相关性分析法,与地表地震计同步观测数据进行相关性分析,检测并校正井下地震计方位角,结果发现,3个地震台井下地震计方位角实际偏差分别为82.2°、-22.8°、32.2°。分析认为,井下地震计安装易受线缆应力影响,导致方位角与实际偏差过大,应在应力释放完成后固定地震计,并架设地表地震计进行数据相关性分析,以确定方位角可靠性。     

Geochemistry of Ore Fluids and Rb-Sr Isotopic Dating for the Wulong Gold Deposit in Liaoning, China

On the basis of detailed geological studies of the Wulong gold deposit, three metallogenic stages can be identified. With quartz fluid inclusions as an object of study, the authors investigated phase characteristics, compositional variations, temperature and pressure changes, fluid evolution, Pb isotope tracing and Rb-Sr isotopic dating of fluid inclusions entrapped in the above three metallogenic stages. The results show that Na+ is decreased obviously with metallogenic evolution, while K+ and other cations and gas compositions (H2, CO, CH4 and CO2) are increased slightly, and that the temperature and salinity vary in a pulsating manner along with the metallogenic evolution. Inverse calculation of hydrogen and oxygen isotopes indicate that at the first metallogenic stage the fluids were magmatic water, at the second stage they were dominated by magmatic water with a minor amount of meteoric water involved, and at the third stage, i.e., the final stage of metallogenesis, the fluids were composed complete