赣东北鹅湖岭组的再认识

在分析赣东北鹅湖岭组及有关地层的地质特征、地层划分现状及产生分岐的原因的基础上,提出以岩性、岩相为划分依据,将鹅湖岭组与喷发相相对应,将其下界、上界分别置于沉积喷发相与喷发相、喷发相与喷发沉积相的相变界面上。从而将北京地质学院指定的打鼓顶组建组剖面上的"打鼓顶组"并入鹅湖岭组;将赣东北其它地区的鹅湖岭组下界由安山岩层顶界处上移至安山岩层之上灰绿色砂岩层的顶界处,将铅山一上饶一带鹅湖岭组上界下移至原鹅湖岭组上部的底界处。     

大别杂岩中混合岩的矿物空间分布研究

介绍了矿物空间分布研究的基本原理及两种统计方法(接触频数法和线切法)。作者对混合岩矿物空间分布的研究表明:(1)前人提出的统计方法存在方法上的缺陷和应用上的局限性,作者推导出矿物接触类型的概率公式;(2)部分浅色体中矿物显示聚集分布的特征,而绝大部分的浅色体中矿物具有分散分布的特点。结合质量平衡和地球化学研究认为:大别杂岩中主体混合岩成因机制是重熔和交代作用。     

早期矿业发展与地质学的诞生

石头是人类由蒙昧走向智慧的启蒙，彩石和矿物颜料开启了人类对美的认识和追求。人类在使用矿物岩石中相继出现的武器、农耕时代、陶器、金属冶炼、人类聚落和城邦，标志着人类智慧的爆发和文明根基的建立。遍布全球的规模性采掘和矿业活动为早期人类社会的发展奠定了工业和经济基础，给人类认识矿物岩石和探索地球的奥秘打开了大门。东西方先哲们最早观察和思索天地万物、物质组成和变化、探索石头和金属的形成，炼丹术和炼金术、早期博物学、早期医学对金属、矿物和岩石的进一步探索与实践，孕育了现代矿物学和地质学。中世纪矿业的繁荣带动了地质科学研究的复兴，矿床学和矿物学的确立、化石研究与地层层序的确立、岩石成因的水火之争、山脉成因的垂向升降和水平挤压之争导致了地质学的诞生和确立。     

中国南方离子吸附型稀土矿床成矿类型及其母岩控矿因素探讨

传统认为中国南方的离子吸附型稀土矿床可划分为以“足洞式”为代表的重稀土型和以“河岭式”(或“花山式”)为代表的轻稀土型两种矿化类型。然而，近年来发现的许多矿床(如清溪、寨背和馒头山等)的赋矿风化壳中出现了轻稀土矿与重稀土矿并存现象，表现出特殊的“上轻下重”双层矿体结构。这指示了除重稀土型和轻稀土型之外，还存在着轻重稀土共生型的过渡类型。本研究通过对三种不同成矿类型的若干典型矿床系统对比，指出成矿类型的多样性与母岩性质密切相关，尤其是母岩的稀土元素地球化学和稀土载体矿物属性是制约成矿类型变化的关键因素。统计数据表明，从重稀土型→轻重稀土共生型→轻稀土型，成矿母岩的全岩稀土总量变化不大(ΣREY: 200×10-6~450×10-6→200×10-6~500×10-6→200×10-6~800×10-6)，但轻重稀土配分值出现较显著的区间性差异(ΣLREE/ΣHREY: 02~1→1~5→2~10)。与之同时，母岩中能为离子相稀土提供物源且具有重稀土配分属性的稀土副矿物类型和数量明显减少，这与全岩稀土元素地球化学特征中重稀土分量占比的降低趋势也互相匹配。该结果指示，以往认为重稀土配分母岩形成重稀土矿床、轻稀土配分母岩形成轻稀土矿床的传统观点需要外延，即一部分具有低度轻稀土配分属性(1＜ΣLREE/ΣHREY＜5)且含有丰富易风化稀土副矿物的母岩还可能形成轻重稀土共生型矿床，该认识可为今后离子吸附型稀土矿床勘查工作提供新的找矿依据。     

重视和加强岩矿物性的测量研究

本文从物探科学技术的进步,勘查任务的发展变化、物探方法应用范畴的扩大和物性勘探等几个方面,论述了岩石和矿物物理性质测量、研究的重要性,指出：物性工作不可能毕其功于一役,并提出了五点建议：１．深入研究各类矿藏及其围岩（直至地面）物性的空间变化规律,为选择、研究合适的物探方法,提高物探效果,进一步探讨“直接”找矿问题,提供依据;２．这项工作可专门进行,但最好尽可能利用为其他目的而设计的钻井进行;３．物     

井下记录的PP和SS震相

本文在系统分析静海台井下地震记录图的基础上,发现并解决了具有一定实际和理论意义的两个问题:其一是证明了最初误认为是干扰的“双脉冲”图形实际上均是微地震。从而指出研究静海周围地区的地震活动性应考虑微震活动问题。其二确认静海周围地区微震波形的4个主要震相是P、PP、S和SS,并对地面反射波PP和SS能够观测到的条件作了初步分析,其结果进一步说明井下地震记录较之地面记录更为“逼真”,复杂和丰富。     

短周期仪器记录在远震分析中的应用

地震泼由多种频率成份组成,在其传播过程中。由于地球介质的滤波作用,随着传播距离的增大。高频成份逐渐被衰减。周期越大的成份传播越远。因此,在地震观测上,不同频带的地震仪用于观测不同震中距范围的地震,使仪器较好地响应,就我国台网而言,短周期仪用于地方震、近震的监测,中长周期仪和长周期仪用于远震,极远震的监测,其中长周期仪偏重于记录极远震。但作者在实际分析工作中注意到,短周期仪的记录应用于远震,极远震的分析,显示出独特的作用,充分挖掘和利用短仪资料,将会更加丰富远震、极远震的震相资料。本文以高台地震台的资料为依据,从震中距和震级角度,与中长仪和长仪作比较,对短仪记录远震、极远震的震相及特征作了统计分析与初步探讨,并对新疆地区“影区”地震S波的记录、日本地区地震_PPcP等震相的出现提出了现象的存在,给出了相应的观测结果,以待步一步研究。     

Catalytic ozonation of phenol in water with natural brucite and magnesia

Catalytic ozonation has attracted much attention in treatment of wastewater for its mild conditions. Phenol and its ramifications are common components in a wide variety of wastewaters including those from coal conversion processes, coking plants, petroleum refineries and several chemical industries. In this paper, natural brucite and magnesia have been successfully used in catalytic ozonation of phenol. And the mechanisms of catalysis were also investigated. From Figs. 1 and 2, it can be found that both brucite and magnesia have remarkable catalysis on degradation of phenol and removal of Chemical Oxygen Demand （COD）. The pH of solutions on the process of ozonation alone, catalytic ozonation with brucites and with magnesia were 6.35-2.76, 10.18-8.52 and 10.58-10.83, respectively. It can be concluded that alkali environment plays a critical role for catalytic ozonation of phenol. We also found that the alkaline minerals reacted on the surface with oxalic acid and other low molecular-weight acids which are intermediate products in ozonation, but those intermediate products could be mineralized into carbon dioxide completely with enough ozonation time.     

Hydrogeochemical controls on surface and groundwater chemistry in naturally acidic, porphyry-related mineralized areas, southern Rocky Mountains

In southern Rocky Mountains, catchments characterized by acidic, metalliferous waters that are relatively unaffected by human activity usually occur within areas that have active or historical mining activity. The US Geological Survey has utilized these mineralized but unmined catchments to constrain geochemical processes that control the surface- and ground-water chemistry associated with near surface acid weathering as well as to estimate premining conditions. Study areas include the upper Animas River watershed, Lake City, Mt. Emmons, and Montezuma in Colorado and Questa in New Mexico. Although host-rock lithologies range from Precambrian gneisses to Cretaceous sedimentary units to Tertiary volcanic complexes, mineralization is Tertiary in age and associated with intermediate to felsic composition, porphyritic plutons. Pyrite is ubiquitous. Variability of metal concentrations in water is caused by two main factors： mineralogy and hydrology. Parameters that potentially affect water chemistry include： host-rock lithology, intensity of hydrothermal alteration, sulfide mineralogy and chemistry, gangue mineralogy, length of flow path, precipitation, evaporation, and redox conditions. Springs and headwater streams have pH values as low as 2.5, sulfate up to 3700 mg/L and high dissolved metal concentrations （for example： Al up to 170 mg/L; Fe up to 250 mg/L; Cu up to 3.5 mg/L and Zn up to 14 mg/L）. With the exception of evaporative waters, the lowest pH values and highest Fe and Al concentrations occur in water draining the most intense hydrothermally altered areas consisting of the mineral assemblage quartz-sericite-pyrite. Stream beds tend to be coated with iron floc, and some reaches are underlain by ferricrete. When iron-rich ground water interacts with oxygenated waters in the stream or hyporheic zone, ferrous iron is oxidized to ferric iron, which is less soluble, leading to the precipitation of iron oxyhydroxides.     

Naturally acidic and metalliferous waters at unmined volcanogenic massive sulfide deposits in the Bonnifield mining district, Alaska Range, east-central Alaska

The Bonnifield district hosts 26 tmmined volcanogenic massive sulfide （VMS） occurrences. Environmental geochemical samples of water and stream sediment were collected at several occurrences, concentrating on the two best-exposed and largest deposits, Red Mountain （RM） and Sheep Creek （SC）. Limited samples were also collected at the poorly exposed WTF deposit. The deposits are Late Devonian to Early Mississippian, and are hosted by felsic metavolcanic and carbonaceous schist members of the Totatlanika Schist or Keevy Peak Fm. Spring and stream waters at RM and SC have pH values commonly 〈3.5 （as low as 2.4 at RM and 2.5 at SC）, high conductivity （up to 11000 μS/cm）, and very high （Is to 100s mg/L） dissolved contents of Al, Cd, Co, Cu, Fe, Ni, and Pb. Waters at RM are characterized by extremely high REE contents （summed REE median 3200 μg/L, n=33）. At both RM and SC, pyrite oxidation and dissolution produce low pH waters that interact with and dissolve bedrock minerals, resulting in acidic, metal-laden, naturally degraded streams that are mostly devoid of aquatic life. Ferricrete is common. In contrast, WTF barely produces a surficial environmental footprint, mostly due to topography and relief. RM and SC are well exposed in the areas of relatively high relief, and both exhibit extensive areas of quartz-sericite-pyrite-alteration. While WTF shares many of the same deposit-and alteration characteristics, it is concealed by tundra in a large, nearly flat area. Surface water at WTF is absent and outcrops are sparse. Even though WTF is roughly the same size as Red Mountain （both around 3 million tonnes） and has similar base- and precious-metal grades, the surficial geochemical manifestation of WTF is minimal. However, exposure through mining of the altered, mineralized rock at WTF potentially could initiate the same processes of pyrite oxidation, acid generation, and mineral dissolution that are observed naturally at RM and SC.