Structural and magnetic properties of Co2Al4Si5O18 and Mn2Al4Si5O18 cordierite

The crystal structures, lattice dynamics and magnetic properties of synthetic Co-cordierite, Co₂Al₄Si₅O₁₈, and Mn-cordierite, Mn₂Al₄Si₅O₁₈ have been studied by neutron powder diffraction, infrared spectroscopy and magnetisation measurements. Due to different synthesis conditions, the Co-cordierite used here crystallised in the hexagonal α-cordierite structure with a disordered Si/Al distribution in the framework, while for the Mn-cordierite the orthorhombic β-structure has been determined. The experimentally determined paramagnetic moments, _exp (Mn) = 5.47(6) _B and _exp (Co) = 3.88(4) _B , are in good agreement with theoretical predictions for octahedrally coordinated Mn²⁺ and Co²⁺, respectively. In both compounds there is no magnetic long-range order down to at least 1.5 K. However, the onset of an anti-ferromagnetic short-range correlation of magnetic moments along [001] has been observed for Mn-cordierite by magnetisation and neutron diffraction measurements. This short-range magnetic correlation becomes evident from diffuse scattering observed at 2 K. The diffuse scattering has been interpreted in terms of a Blech-Averbach function. Received: 30 June 1998 / Revised, accepted: 3 March 1999     

Microanalysis of Fe3+/ΣFe in oxide and silicate minerals by investigation of electron energy-loss near-edge structures (ELNES) at the Fe M 2,3 edge

The Fe M _2,3-edge spectra of solid solutions of garnets (almandine-skiagite Fe₃(Al_1–xFe_x)₂[SiO₄]₃ and andradite-skiagite (Fe_1–xCa_x)₃Fe₂[SiO₄]₃), pyroxenes (acmite-hedenbergite (Ca_1–xNa_x)(Fe²⁺ _1−xFe³⁺ _x)Si₂O₆), and spinels (magnetite-hercynite Fe(Al_1–xFe_x)₂O₄) have been measured using the technique of parallel electron energy-loss spectroscopy (EELS) conducted in a transmission electron microscope (TEM). The Fe M _2,3 electron energy-loss near-edge structures (ELNES) of the minerals exhibit a characteristic peak located at 4.2 eV and 2.2 eV for trivalent and divalent iron, respectively, prior to the main maximum at about 57 eV. The intensity and energy of the pre-edge feature varies depending on Fe³⁺/ΣFe. We demonstrate a new quantitative method to extract the ferrous/ferric ratio in minerals. A systematic relationship between Fe³⁺/ΣFe and the integral intensity ratio of the main maximum and the pre-edge peak of the Fe M _2,3 edge is observed. Since the partial cross sections of the Fe M _2,3 edges are some orders of magnitude higher than those of the Fe L _2,3 edges, the Fe M _2,3 edges are interesting for valence-specific imaging of Fe. The possibility of iron valence-specific imaging is illustrated by Fe M _2,3-ELNES investigations with high lateral resolution from a sample of ilmenite containing hematite exsolution lamellae that shows different edge shapes consistent with variations in the Fe³⁺/ΣFe ratio over distances on the order of 100 nm. Received: 14 April 1998 / Revised, accepted: 8 March 1999     

Facies architecture of an isolated carbonate platform: tracing the cycles of the Latemàr (Middle Triassic, northern Italy)

The 720-m-thick succession of the Middle Triassic Latemàr Massif (Dolomites, Italy) was used to reconstruct the lagoonal facies architecture of a small atoll-like carbonate platform. Facies analysis of the lagoonal sediments yields a bathymetric interpretation of the lateral facies variations, which reflect a syndepositional palaeorelief. Based on tracing of lagoonal flooding surfaces, the metre-scale shallowing-upward cycles are interpreted to be of allocyclic origin. Short-term sea-level changes led to subaerial exposure of wide parts of the marginal zone, resulting in the development of a tepee belt of varying width. Occasional emergence of the entire lagoon produced lagoon-wide decimetre-thick red exposure horizons. The supratidal tepee belt in the backreef area represented the zone of maximum elevation, which circumscribed the sub- to peritidal lagoonal interior during most of the platform's development. This tepee rim, the subtidal reef and a sub- to peritidal transition zone in between stabilized the platform margin. The asymmetric width of facies belts within individual metre-scale cycles was caused by redistribution processes that reflect palaeowinds and storm paths from the present-day south and west. The overall succession shows stratigraphic changes on a scale of tens of metres from a basal subtidal unit, overlain by three tepee-rich intervals, separated by tepee-poor units composed of subtidal to peritidal facies. This stacking pattern reflects two third-order sequences during the late Anisian to early middle Ladinian.     

Global temperature and monsoon activity

In this paper an attempt has been made to search a new parameter for the prediction of the Indian summer monsoon rainfall. For this purpose the relationship of the global surface-air temperature of four standard seasons viz., Winter (December-January-February), Spring (March-April-May), Summer (June-July-August), Autumn (September-October-November) with the Indian summer monsoon rainfall has been carried out. The same analysis is also carried out with surface-air temperature anomalies within the tropical belt (30°S to 30°N) and Indian summer monsoon rainfall. For the present study data for 30 years period from 1958 to 1988 have been used. The analysis reveals that there is a strong inverse relationship between the monsoon activity and the tropical belt temperature.     

矿物粉尘表面活性位及其变化分析

本文通过酸碱蚀,强机械力和极性分子等表面作用,利用红外吸收光谱手段分析了７放物粉尘的表面基团裸露,转化过程,总结了矿物粉尘表面存在的基团类型及其表面活性位的分布及在不同环境条件下的转化,对讨论粉尘生物活性及矿物表面／细胞物理化学作用过程有重要意义。     

Adhesion of foulings on surface energy of silicone rubber coatings

INTRODUCTIONBiologicalfoulingonthehullsofshipsandothersubmergedmarinestructurescausesgreatha~s.Inadditiontodecreasingship'sspeed,andincreasingitsfuelconsumption,biologicalfoulingalsoincreasestheweightofnavigationalbuoys,interfereswithoperatingequipmentandsounddevices,clogsseawaterpipingsystems,adverselyaffectsheat-exchangerperformance,andpromotescorrosionofmetalsurface(HuangandCat,1984).UPtothepresent,antifoulingpaintshaveachievedtheireffectivenessbyreleasingattheirsurfacebiocides,allcom…     

Annual and Seasonal Variations of the Sea Surface Heat Fluxes in the East Asian Marginal Seas

Based on the twice-daily marine atmospheric variables which were derived mostly from the weather maps for 18 years period from 1978 to 1995, the surface heat flux over the East Asian marginal seas was calculated at 0.5°×0.5° grid points twice a day. The annual mean distribution of the net heat flux shows that the maximum heat loss occurs in the central part of the Yellow Sea, along the Kuroshio axis and along the west coast of the northern Japanese islands. The area off Vladivostok turned out to be a heat-losing region, however, on the average, the amount of heat loss is minimum over the study area and the estuary of the Yangtze River also appears as a region of the minimum heat loss. The seasonal variations of heat flux show that the period of heat gain is longest in the Yellow Sea, and the maximum heat gain occurs in June. The maximum heat loss occurs in January over the study area, except the Yellow Sea where the heat loss is maximum in December. The annual mean value of the net heat flux in the East/Japan Sea is −108 W/m² which is about twice the value of Hirose et al. (1996) or about 30% higher than Kato and Asai (1983). For the Yellow Sea, it is about −89 W/m² and it becomes −75 W/m² in the East China Sea. This increase in values of the net heat flux comes mostly from the turbulent fluxes which are strongly dependent on the wind speed, which fluctuates largely during the winter season. This revised version was published online in August 2006 with corrections to the Cover Date.     

长岛轮渡码头装卸工艺设计

以长岛港轮渡码头装卸工艺设计为例,介绍轮渡码头装卸工艺设计的步骤和内容。     

水深对超浅吃水拖轮系柱拖力的影响

超浅吃水拖轮在浅海对钻井平台进行拖带和井位定位时,必须了解超浅吃水拖轮浅水系柱拖力特性,才能充分利用海潮条件和自身能力完成钻井平台的拖带和定位任务。