磺化层柱状有机膦酸锆的合成及催化反应研究

在氢氟酸溶液中,混合亚磷酸、4,4’-联苯二膦酸和锆离子反应生成4,4’-联苯二膦酸锆／亚磷酸锆（简称MCZP）,改变有机酸和亚磷酸的比例,可以合成具有相同组分但结构不同的一系列化合物。通过磺化反应,在苯环上接上磺酸基团后,它具有类似强酸性阳离子交换树脂特性．该文首次对这类化合物催化酯化、醚化等典型的酸催化有机反应进行了研究,结果表明其催化转化率高、催化剂可重复使用和再生,是一种很有发展前途的新型固体酸催化剂．     

亚南极冰川雪冰内MSA的季节变化(英)

Methanesulphonate was investigated as a potential contributor to the sulphur budget based on the analysis on Antarctic snow/ice from Coffins Ice Cap, King George Island (62°10' S, 58°50,W). The anion was found to be present at a mean concentration of 0. 17 μeq. L-1 with a maximum of 0.73 μeq. L-1. A distinct seasonal variation exists in the top 10 m of the core, equivalent to more than two years of deposition. Dating resulted from δ18O profile suggests that the principal peaks of methanesulphonate are associated with snow deposited in autumn and secondary peaks in spring. The seasonal patterns of methanesulphonate in the subantarctic snow displays a phase difference from that observed in marine air from low and middle latitudes.     

Accelerator mass spectrometry radiocarbon dating of 1994 Lake Winnipeg cores

Conventional radiocarbon dating of Lake Winnipeg core samples has produced erroneously old ages due to the incorporation of pre-Quaternary carbon derived from carbonaceous rocks, soils and sediments in the watershed, as well as a hard-water effect resulting from leaching of calcareous rocks and soils. To circumvent these problems and develop a reliable chronology for the Lake Winnipeg core series, a total of 64 samples from the Lake Winnipeg core series were processed to isolate well preserved macrofossils suitable for Accelerator Mass Spectrometry (AMS) radiocarbon dating. Here we report six radiocarbon ages derived from plant macrofossils and ostracodes, and reconstruct aspects of the depositional environment of each sample based on the associated macrofossil assemblage.     

The evolution characteristics of positive and negative earthquakes before strong quakes in Kanto area and the Hyugo earthquake in Japan

ＴｈｅｅｖｏｌｕｔｉｏｎｃｈａｒａｃｔｅｒｉｓｔｉｃｓｏｆｐｏｓｉｔｉｖｅａｎｄｎｅｇａｔｉｖｅｅａｒｔｈｑｕａｋｅｓｂｅｆｏｒｅｓｔｒｏｎｇｑｕａｋｅｓｉｎＫａｎｔｏａｒｅａａｎｄｔｈｅＨｙｕｇｏｅａｒｔｈｑｕａｋｅｉｎＪａｐａｎＹＵＣＡＮＧＷ...     

穿过张家口—渤海地震带西缘的折射剖面所揭示的地壳上地幔构造与速度结构

近期完成的北北东向的繁峙～太仆寺旗宽角反射／折射剖面,由山西断隆进入内蒙地轴,它穿过了山西地震带的大同～阳高震区和北西西向张家口～渤海地震带的西北缘。其主要目的是探测研究张～渤地震带及其两侧壳幔构造与速度结构的差异及其与地震活动的相关性。结果表明：张～渤地震带壳内界面及莫霍面较其两侧有１．０～２．０ｋｍ的不同程度的上隆;在阳原～张家口之间地壳结构纵向与横向非均匀性明显,上地壳和下地壳上部有局部的速度逆转,下地壳下部的低速层由山西断隆一直延伸至内蒙地轴,上地幔顶部的速度梯度明显增大;在阳原、怀安和张北附近分别存在着延伸至莫霍面的地壳深断裂带;在内蒙地轴一系列壳内界面不明显。     

On the use of microtremor recordings in seismic microzonation

Experimental methods involving microtremor recordings are useful for determining site effects in regions of moderate seismic activity where ground motion records are few, and in urban or industrial contexts where the noise level is high. The aim of this study is to establish a microzonation by using the Nogoshi–Nakamura method,[1, 2] a simple experimental technique based on microtremor recordings. Since the physical phenomena underlying the method are only partially understood, the spectral responses obtained cannot be used alone. We, therefore, complete our experimental results by comparing them with the solutions of a one-dimensional numerical simulation (SHAKE91).[3, 4] The experimental programme was carried out on a plain near the Rhone Delta (South of France). H/V spectral ratios were calculated at 137 noise measurement points. In addition, we were able to compute the numerical transfer functions from soil columns defined by geotechnical characteristics inside the studied region. A comparison of the results obtained by the experimental and numerical methods showed that the fundamental frequencies are in good agreement, but that the amplitudes obtained by the two techniques are sometimes different. The analysis of H/V spectral ratios enabled us to establish maps to characterize the region: a resonance frequency map and maps of amplification levels as a function of frequency range, leading to a seismic microzonation for the whole of the region.     

中国数字地震台网数据管理中心日常工作软件的升级和应用

文中阐述了中国数字地震台网数据管理中心（ＣＤＳＮ ＤＭＣ）日常工作软件的升级和升级后新软件的主要功能,并结合新软件的主要命令及运行实例,对升级后软件的实际应用作了简要叙述。     

TFe/TiO_2比值在攀枝花层状辉长岩体钒钛磁铁矿矿床勘探中的应用

攀枝花钒钛磁铁矿床是我国特大型晚期岩浆分凝型矿床。本文首次用ＴＦｅ／ＴｉＯ２比值对矿带、矿层、火成堆积旋回进行了详细划分,同时对断层位置、性质及矿床成因进行了判定,并提出在层状辉长岩体中,当ＴＦｅ／ＴｉＯ２比值小于２∶１的部位是寻找独立钛铁矿矿床最佳地段     

Flow of groundwater with variable density and viscosity, Atikokan Research Area, Canada

 Flow of groundwater with variable density and viscosity was simulated at the Atikokan Research Area (ARA) in northwestern Ontario, Canada. An empirical viscosity–concentration equation was modified to include total-dissolved-solids (TDS) data from the ARA. The resulting equation was used successfully to estimate reasonably accurate viscosity values over the expected range of temperature and concentration, in comparison with experimental values derived for sodium chloride solutions. A three-dimensional finite-element code, MOTIF, developed by Atomic Energy of Canada Limited, was used in the simulations. The inclusion of the effects of depth-increasing temperature and TDS-dependent fluid-density distribution, while maintaining only a temperature-dependent viscosity relationship in a simulation, resulted in a more penetrative flow against expected buoyancy effects (i.e., the physics of the system was not honored). Accounting for concentration in the viscosity equation caused water to be less penetrative and more in accordance with the expected physics of the system. A conclusion is that fluid concentration should be considered simultaneously in calculating the density and viscosity of a fluid during modeling of variable-density flow in areas underlain by fluids with high TDS. Results of simulations suggest that both flow directions and magnitudes should be employed simultaneously during the calibration of a model. Large-scale groundwater movement in the ARA may be analyzed with carefully selected vertical no-flow boundaries. By incorporating the geothermal temperature gradient, groundwater recharge increases by 12%; thus, this gradient plays a significant role in groundwater flow at the ARA. Variability in the fluid concentration at the ARA neither decreases nor increases recharge into the groundwater system. The hypothesis that an isolated continuous regional flow system may exist at depth in the ARA is not supported by these simulations. Received, September 1996 Revised, September 1997, February 1998 Accepted, February 1998     

A method of searching for radial velocity anomalies in the lower mantle using interfering signals

Radial velocity anomalies in the lower mantle that give rise to triplications in the travel-time curve for short-periodP waves will produce arrivals havingdT/d values that differe by roughly 0.2–0.5 s/deg. The first two arrivals associated with such triplications will be separated by less than one second over a distance range of 4°–10° they may not, therefore, be separable visually on single seismograms, so that their presence can only be inferred from some measurable property that depends on their mutual interference. If there are lateral variations in the regions of anomalous velocity gradients, the interfering signals will also have different azimuths of arrival. Using two synthetic wavelets we have investigated the effect of interference on bothdT/d and azimuth measurements at the Yellowknife Array. We found that if the interfering pulses have a dominant frequencyv, there is a range of time separations (0.30/v0.55/v) over which the measureddT/d and azimuth values may fluctuate by much more than the differences indT/d and azimuth between the interfering signals. We have evaluated the following empirically defined functions for three different primary signals, and for three different relative amplitudes of the interfering signals:f (t), the drift function, which expresses how the measured slownesses,p, and azimuths, , differ from the slownesses and azimuths of the primary wavelets; f(), the range function, which describes the behaviour of the upper and lower bounds ofp and as a function of the difference in arrival times of the signals, andf , studied the properties of these functions, and have outlined how these properties provide criteria based on the numerical and statistical characteristics of the arrival vectors, and on the waveform of the signal that will enable small radial velocity anomalies to be more clearly delineated.Contribution No. 863 from the Earth Physics Branch.