Anthropogenic trace metals in an ice core at Vestfonna,Svalbard, Norway

1　IntroductionAnicecoreobtainedfrom polarglaciersoricesheetsisoneofthemostimportantarchivestoreconstructpaleoclimaticandpaleoatmosphericcondition .Informationonpale o environmentcanbeextractedfromicecoresaschemicaland/orphysicalsignals.Amongthechemicalsignals,heavymetalsarenotedassignalsofterrestrialenvironmentalchangeandanthropogenicpollution (e.g .Murozumietal.1 969;NgandPatterson 1 981 ;Hongetal.1 994) .SinceconcentrationsofmostofthemetalsinpolarsnowincentralGreen landareatorbelowthepptl…     

MS 1603.6+2600: an accretion disc corona source?

We have observed the eclipsing low-mass X-ray binary MS 1603.6+2600 with Chandra for 7 ks. The X-ray spectrum is well fit with a single absorbed power law with an index of ∼2. We find a clear sinusoidal modulation in the X-ray light curve with a period of  1.7 ± 0.2 h  , consistent with the period of 1.85 h found before. However, no (partial) eclipses were found. We argue that if the X-ray flare observed in earlier X-ray observations was a type I X-ray burst, then the source can only be an accretion disc corona source at a distance of ∼11–24 kpc (implying a height above the Galactic disc of ∼8–17 kpc). It has also been proposed in the literature that MS 1603.76+2600 is a dipper at ∼75 kpc. We argue that, in this dipper scenario, the observed optical properties of MS 1603.6+2600 are difficult to reconcile with the optical properties one would expect on the basis of comparisons with other high-inclination, low-mass X-ray binaries, unless the X-ray flare was not a type I X-ray burst. In that case, the source can be a nearby soft X-ray transient accreting at a quiescent rate, as was proposed by Hakala et al., or a high-inclination source at ∼15–20 kpc.     

Magnetic susceptibility variations of the Edicaran cap carbonates in the Yangtze platform and their implications for paleoclimate

1 INTRODUCTION One of the most intriguing phenomena in the late Neoproterozoic (~750 to 543 Ma) is the globa occurrence of thin carbonates that directly overlie glacial deposits in almost every continent (Kennedy 1996; Hoffman et al., 1998; Hoffman and Schrag 2002; Brasier and Shields, 2000; James et al., 2001 Jiang et al., 2003; Nogueira et al., 2003). These “cap carbonates”, commonly several to tens of meters thick, have attracted enormous interests because o their unusually negati…     

Sedimentary evolution of a Late Pleistocene temperate red algal reef (Coralligène) on Rhodes,Greece: correlation with global sea‐level fluctuations

Autochthonous red algal structures known as coralligène de plateau occur in the modern warm‐temperate Mediterranean Sea at water depths from 20 to 120 m, but fossil counterparts are not so well‐known. This study describes, from an uplifted coastal section at Plimiri on the island of Rhodes, a 450 m long by 10 m thick Late Pleistocene red algal reef (Coralligène Facies), interpreted as being a coralligène de plateau, and its associated deposits. The Coralligène Facies, constructed mainly by Lithophyllum and Titanoderma, sits unconformably upon the Plio‐Pleistocene Rhodes Formation and is overlain by a Maerl Facies (2 m), a Mixed Siliciclastic‐Carbonate Facies (0·2 m) and an Aeolian Sand Facies (2·5 m). The three calcareous facies, of Heterozoan character, are correlated with established members in the Lindos Acropolis Formation in the north of the island, while the aeolian facies is assigned to the new Plimiri Aeolianite Formation. The palaeoenvironmental and genetic‐stratigraphic interpretations of these mixed siliciclastic‐carbonate temperate water deposits involved consideration of certain characteristics associated with siliciclastic shelf and tropical carbonate shelf models, such as vertical grain‐size trends and the stratigraphic position of zooxanthellate coral growths. Integration of these results with electron spin resonance dates of bivalve shells indicates that the Coralligène Facies was deposited during Marine Isotope Stage 6 to 5e transgressive event (ca 135 to 120 ka), in water depths of 20 to 50 m, and the overlying Maerl Facies was deposited during regression from Marine Isotope Stage 5e to 5d (ca 120 to 110 ka), at water depths of 25 to 40 m. The capping Aeolian Sand Facies, involving dual terrestrial subunits, is interpreted as having formed during each of the glacial intervals Marine Isotope Stages 4 (71 to 59 ka) and 2 (24 to 12 ka), with soil formation during the subsequent interglacial periods of Marine Isotope Stages 3 and 1, respectively. Accumulation rates of about 0·7 mm year^?1 are estimated for the Coralligène Facies and minimum accumulation rates of 0·2 mm year^?1 are estimated for the Maerl Facies. The existence of older red algal reefs in the Plimiri region during at least Marine Isotope Stages 7 (245 to 186 ka) and 9 (339 to 303 ka) is inferred from the occurrence of reworked coralligène‐type lithoclasts in the basal part of the section and from the electron spin resonance ages of transported bivalve shells.     

Possible chemical structures and biological precursors of different vitrinites in coal measure in Northwest China

Chemical structure of Jurassic vitrinites isolated from the coals in basins in NW China have been checked using solid state ¹³C NMR and flash pyrolysis-GC/MS. Study shows some Jurassic collodetrinites are rich in aliphatic products in pyrolysates, consisting with the high amount of methylene carbon in ¹³C NMR spectra. In contrast, pyrolysates of Jurassic collotelinites are rich in phenols and alkylbenzenes. Also one Pennsylvanian and one Permian vitrinite selected from the Ordos basin, NW China have been checked for comparison. The proportion of aliphatics is low in pyrolysates, and aliphatic carbon peak in ¹³C NMR spectrum of Permian vitrinite is mostly composed of gas-prone carbons compared with collodetrinites in those Jurassic basins. But both pyrolysis and ¹³C NMR data shows the Pennsylvanian vitrinite is not only gas-prone but also oil-prone. Relatively high proportion of long chain aliphatic structure of some Jurassic vitrinite in Junggar, Turpan-Hami basins may be due to the contribution of liptodetrinites, which may be included during the formation of vitrinites. And it seems that suberinite is the most possible precursor of long chain aliphatics in the structure of Jurassic collodetrinite.     

鄂尔多斯盆地西峰地区长8砂岩微观非均质性的实验分析

通过真实砂岩微观模型实验,客观地分析了鄂尔多斯盆地西峰地区长8砂岩的微观非均质性特征,发现该区长8储层为致密型砂岩,直观地显示出长8砂岩储层具有很强的微观非均质性,砂岩的成岩作用和孔隙结构是影响鄂尔多斯盆地西峰地区长8砂岩储层微观非均质性的主要原因。在低渗透砂岩中,引起砂岩产生强烈的非均质性,而这些砂岩则形成长8砂岩储层的高渗带。     

Probing molecular-level transformations of dissolved organic matter: insights on photochemical degradation and protozoan modification of DOM from electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry

Molecular-level characterization of natural organic matter (NOM) has been elusive due to the inherent complexity of natural organic mixtures and to the fact that individual components are often polar and macromolecular. Electrospray ionization (ESI) is a “soft” ionization technique that ionizes polar compounds from aqueous solution prior to injection into a mass spectrometer. The highest resolution and mass accuracy of compounds within NOM have been achieved when ESI is combined with an ultrahigh-resolution mass spectrometer such as the Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS). With this technique, individual molecules within a variety of natural organic mixtures can be detected and their elemental composition can be determined. At low mass-to-charge (m/z) ratio, the resolution is high enough to assign exact molecular formulas allowing specific components of these mixtures to be identified. In addition to molecular identification, we can now use ESI FT-ICR MS to examine molecular-level changes in different organic mixtures as a function of relevant geo-processes, such as microbial alterations and photochemistry. Here we present the results from the application of ESI FT-ICR MS to two geochemical questions: (1) the effect of photoirradiation on the molecular composition of fulvic acids and (2) the role of protozoan grazers in the modification of DOM in aquatic systems.     

四川汶川大地震的构造分析

2008年5月12日在汶川映秀(北纬31.0°,东经103.4°)发生8级大地震,而后发生万余次余震,其最大震级为6.4级.此次地震属主震-余震型地震.通过构造分析认为.汶川大地震是构造地震,主要受龙门山断裂带的强烈活动控制.它是一种板内地震,其动力来源来自印度板块与欧亚板块的碰撞.而成都平原处于稳定地块中,尽管离震中较近,然受地震的影响有限,是比较安全的.     

汶川地震山地灾害遥感快速提取及其分布特点分析

针对泥石流滑坡灾害体特有的物质组成与活动特点,通过比较分析其在不同遥感影像的光谱特征差异,选择ETM+影像作为主要数据源,提取湿度指数与绿度指数,利用ETM+的穗帽变换、影像差值增强、密度分割和掩膜技术建立了泥石流滑坡山地灾害快速提取模型,并用于汶川地震.通过灾害体的提取,分析了本次地震山地次生灾害的分布规律,利用空间叠加进行了成因的分析.本次地震山地灾害具有如下特点:(1)沿主要地表破裂带分布;(2)山地灾害主要出现在8度-9度地震烈度区,随着烈度的降低,山地灾害的总面积也相应的减少;(3)山地灾害主要发生在海拔高度1000-2500m的地带;(4)主要发生在坡度20°-50°之间的边坡上;(5)地震及余震期间以崩塌滑坡滚石为主,后期以泥石流滑坡为主;(6)具有河流左右两岸呈不对称分布等特点.结果表明,利用ETM+影像建立基于湿度指数与绿度指数的快速提取模型,对于大规模泥石流滑坡提取效果较好,进行大区域山地灾害的遥感快速提取是可行的.     

"5.12"汶川大地震震中区映秀镇地震灾情及次生地质灾害遥感初步调查

"5.12"四川汶川8级大地震发生后,中国国土资源航空物探遥感中心立即采用"赛斯纳"高空遥感飞机,携带高清晰彩色数码相机及先进的POS系统,迅速获取了重灾区的航摄图像数据。本文以震中附近的映秀镇地区为例,简要介绍了以该高质量航摄数据为基础,采用数字滑坡技术,快速进行震后重灾区灾情及次生地质灾害遥感调查的成果。