Hydraulics of runoff and loess loam deposition

On many more or less loamy soils, rill erosion is reported to start on slopes that are equal to or steeper than 2–3°; critical Froude numbers for the start of rill wash on these slopes vary between 2·0 and 3·0. This explains why colluvial deposition often occurs on slopes below 2–3°, when water spreads out at the downslope extremities of the rills. The critical hydraulic conditions for loess loam deposition were tested in the laboratory for slopes of 0·5° and 2°, applying unit-discharges (q) up to 10 cm²/s. It appeared from these experiments that for afterflow, without raindrop impact, deposition starts for critical load concentrations (c_cr) varying between several g/1 and about 60 g/l. Under rain c_cr amounts to a minimum value of 100–125 g/l and it increases when the runoff film becomes thinner. Nevertheless, deposition in pluvial runoff is also possible, as was the case during the Weichselian, according to data from quarries in Belgium and in The Netherlands. A modified Kalinske equation is proposed for c_cr prediction, with the introduction of a typical empirical coefficient C_r and considering such factors as shear stress and mean particle size. Massive sedimentation may occur when it stops raining and afterflow starts, since c_cr values are then much lower. It is shown from the Shields' diagram that loamy suspensions are more sensitive to sedimentation than sands in clear water.     

用滤膜法进行稀土氧化物原料组分的X射线荧光光谱分析

本文叙述了用沉淀抽滤法制备薄试样,X射线荧光光谱法测定混合稀土氧化物原料组分的分析方法。本法定量下限为0.01％—0.17％,方法精度为0.85％—14.9％。对几种类型的原料分析结果表明,本法与ICP-AES法结果基本相符。方法简便快速,可用于混合稀土氧化物原料的成分分析。     

Temporal and spatial variations in the geochemistry of major and minor particulate and selected dissolved elements of Thermaikos Gulf, Northwestern Aegean Sea

The objectives of this study were to examine both spatial and temporal changes of particulate major elements and minor metals, as well as dissolved Mn and Cd, in the waters of Thermaikos Gulf. Collections of water and suspended particulate matter (SPM), as depth profiles (5–8 depths), were undertaken at 10 principal stations, essentially on a N–S traverse of the western side of the Gulf.One of the principal aims of the study was to observe if there was any change in the patterning of the elements between the three occupations of the stations: (a) in September 2001, immediately before the commencement of trawling; (b) in October 2001, whilst fishing was active; and (c) in winter/early spring conditions (February 2002), when fishing was still active, but after a change of river/atmospheric conditions.Bottom (20 m) waters were dominated by sediment resuspension; this was identified by concentration changes in the aluminosilicate elements (e.g. Al, Ti, K, Fe) of the SPM. A two- to three-fold increase occurred between September and October, caused probably by trawling; this was sustained at the offshore stations, in February. During February, the western inshore stations showed little sediment resuspension, caused by extreme winter cooling and the sinking of water. Consequently, a N–S density discontinuity existed at all water depths, which prevented the thermohaline cyclonic circulation from penetrating into the western seaboard of the Gulf. The distribution of dissolved and particulate Mn in the lower waters was due to redox cycling of the element at the benthic boundary; this was more intense in the north, where the organic supply was higher.Biogenic element concentrations and Ca/Al, Si/Al ratios showed no evidence that trawling activity promoted higher biological production. Strong correlations of Co, Cr, Ni and V, with Al and K, showed that these elements were associated strongly with detrital aluminosilicates. However, the variable association of Cd, Pb and Zn, with K (and Al), especially in the upper waters, implied an anthropogenic source derived from the rivers and the city of Thessaloniki. Examination of the Kd's of Cd showed a two-order of magnitude decrease with depth, caused by resuspension and possible advection of relatively unpolluted sediments, into the western Gulf.