Petrochronology of oxidized granulites from southern Peru

Sapphirine–quartz granulites from the Cocachacra region of the Arequipa Massif in southern Peru record early Neoproterozoic ultrahigh‐temperature metamorphism. Phase equilibrium modelling and zircon petrochronology are used to quantify timing and pressure–temperature (P–T) conditions of metamorphism. Modelling of three magnetite‐bearing sapphirine–quartz samples indicates peak temperatures of >950°C at ~0.7 GPa and a clockwise P–T evolution. Elevated concentrations of Al in orthopyroxene are also consistent with ultrahigh‐temperature conditions. Neoblastic zircon records ages of c. 1.0–0.9 Ga that are interpreted to record protracted ultrahigh‐temperature metamorphism. Th/U ratios of zircon of up to 100 reflect U‐depleted whole‐rock compositions. Concentrations of heavy rare earth elements in zircon do not show systematic trends with U–Pb age but do correlate with variable whole‐rock compositions. Very large positive Ce anomalies in zircon from two samples probably relate to strongly oxidizing conditions during neoblastic zircon crystallization. Low concentrations of Ti‐in‐zircon (<10 ppm) are interpreted to result from reduced titania activities due to the strongly oxidized nature of the granulites and the sequestration of titanium‐rich minerals away from the reaction volume. Whole‐rock compositions and oxidation state have a strong influence on the trace element composition of metamorphic zircon, which has implications for interpreting the geological significance of ages retrieved from zircon in oxidized metamorphic rocks.     

鄂尔多斯地块构造演化的古地磁学研究

鄂尔多斯地块与中朝地台其它地区相同时代地层的古地磁结果基本一致表明:晚二叠世以来,中朝地台经历了从低纬度(19°左右)向中纬度的北移过程,并伴有50°左右的逆时针旋转;晚二叠世—中三叠世地台北移10°(1000km)左右,而方位基本未变;中三叠世—中侏罗世主要发生50°左右的逆时针旋转,而北向位移不明显,这一旋转可能与杨子地台和中朝地台碰撞拼合有关,或者说是印支运动在该地区的反应,中侏罗世—早白垩世地块已基本和现代位置一致     

Microbially mediated carbonates in the Holocene deposits from Sarliève, a small ancient lake of the French Massif Central, testify to the evolution of a restricted environment

Both the mineralogy and facies of lacustrine bio‐induced carbonates are controlled largely by hydrological factors that are highly dependent upon climatic influence. As such they are useful tools in characterizing ancient lake environments. In this way, the study of the sedimentary record from the small ancient Sarliève Lake (Limagne, Massif Central, France) aims to reconstruct the hydrological evolution during the Holocene, using petrographical, mineralogical and geochemical analyses. The fine‐grained marls, mainly calcitic, display numerous layers rich in pristine Ca‐dolomite, with small amounts of aragonite, which are clearly autochthonous. As these minerals are rather unusual in the temperate climatic context of western Europe, the question arises about their forming conditions, and therefore that of the lacustrine environment. Ca‐dolomite prevails at the base of the sequence as a massive dolomicrite layer and, in the middle part, it builds up most of the numerous laminae closely associated with organic matter. Scanning electron microscope observations reveal the abundance of tiny crystals (tens to hundreds of nanometres) mainly organized as microspheres looking like cocci or bacilli. Such a facies is interpreted as resulting from the fossilization of benthic microbial communities by dolomite precipitation following organic matter consumption and extracellular polymeric substance degradation. These microbial dolomites were precipitated in a saline environment, as a consequence of excess evaporation from the system, as is also suggested by their positive ?¹⁸O values. The facies sequence expresses the following evolution: (i) saline pan, i.e. endorheic stage with a perennial lowstand in lake level (Boreal to early Atlantic periods); (ii) large fluctuations in lake level with sporadic freshening of the system (Atlantic); (iii) open lake stage (sub‐boreal); and (iv) anthropogenic drainage (sub‐Atlantic).     

Crustal structure at the easternmost termination of the Variscan belt based on CELEBRATION 2000 and ALP 2002 data

The eastern margin of the Variscan belt in Europe comprises plate boundaries between continental blocks and terranes formed during different tectonic events. The crustal structure of that complicated area was studied using the data of the international refraction experiments CELEBRATION 2000 and ALP 2002. The seismic data were acquired along SW–NE oriented refraction and wide-angle reflection profiles CEL10 and ALP04 starting in the Eastern Alps, passing through the Moravo-Silesian zone of the Bohemian Massif and the Fore-Sudetic Monocline, and terminating in the TESZ in Poland. The data were interpreted by seismic tomographic inversion and by 2-D trial-and-error forward modelling of the P waves. Velocity models determine different types of the crust–mantle transition, reflecting variable crustal thickness and delimiting contacts of tectonic units in depth. In the Alpine area, few km thick LVZ with the Vp of 5.1 km s^− 1 dipping to the SW and outcropping at the surface represents the Molasse and Helvetic Flysch sediments overthrust by the Northern Calcareous Alps with higher velocities. In the Bohemian Massif, lower velocities in the range of 5.0–5.6 km s^− 1 down to a depth of 5 km might represent the SE termination of the Elbe Fault Zone. The Fore-Sudetic Monocline and the TESZ are covered by sediments with the velocities in the range of 3.6–5.5 km s^− 1 to the maximum depth of 15 km beneath the Mid-Polish Trough. The Moho in the Eastern Alps is dipping to the SW reaching the depth of 43–45 km. The lower crust at the eastern margin of the Bohemian Massif is characterized by elevated velocities and high Vp gradient, which seems to be a characteristic feature of the Moravo-Silesian. Slightly different properties in the Moravian and Silesian units might be attributed to varying distances of the profile from the Moldanubian Thrust front as well as a different type of contact of the Brunia with the Moldanubian and its northern root sector. The Moho beneath the Fore-Sudetic Monocline is the most pronounced and is interpreted as the first-order discontinuity at a depth of 30 km.     

鄂尔多斯盆地西峰地区长8砂岩微观非均质性的实验分析

通过真实砂岩微观模型实验,客观地分析了鄂尔多斯盆地西峰地区长8砂岩的微观非均质性特征,发现该区长8储层为致密型砂岩,直观地显示出长8砂岩储层具有很强的微观非均质性,砂岩的成岩作用和孔隙结构是影响鄂尔多斯盆地西峰地区长8砂岩储层微观非均质性的主要原因。在低渗透砂岩中,引起砂岩产生强烈的非均质性,而这些砂岩则形成长8砂岩储层的高渗带。     

镇泾地区延长组河流相砂体分布与圈闭形成的关系研究

鄂尔多斯盆地镇泾地区侏罗系地层以三角洲-湖泊沉积体系为主,研究区范围内主要发育主河道和部分分流河道砂体。研究区构造平缓,主要为单斜地层、在东南部存在大型鼻状构造。通过对主要储层段(长6、8油层组)砂体分布及与构造之间关系进行研究,分析砂体走向与构造线方向的关系认为在构造单斜地区,当两者相交时(交角β≠0)是形成圈闭的关键因素之一,在大型鼻状构造地区因构造线的弯曲与河道砂体组合可以形成圈闭。根据研究区砂体分布和构造线组合出4种地层-岩性及岩性圈闭。利用构造图与砂体分布图对主要储层段存在的圈闭确定出长6、8油层组10个层圈闭。     

Carbon and oxygen isotopic composition of car- bonate cements of different phases in terrigenous siliciclastic reservoirs and significance for their origin： A case study from sandstones of the Triassic Yanchang Formation, southwestern Ordos Basin, China

Early carbonate cements in the Yanchang Formation sandstones are composed mainly of calcite with relatively heavier carbon isotope （their δ^18O values range from -0.3‰- -0.1‰） and lighter oxygen isotope （their δ^18O values range from -22.1‰- -19.5‰）. Generally, they are closely related to the direct precipitation of oversaturated calcium carbonate from alkaline lake water. This kind of cementation plays an important role in enhancing the anti-compaction ability of sandstones, preserving intragranular volume and providing the mass basis for later disso- lution caused by acidic fluid flow to produce secondary porosity. Ferriferous calcites are characterized by relatively light carbon isotope with δ^13C values ranging from -8.02‰ to -3.23‰, and lighter oxygen isotope with δ^18O values ranging from -22.9‰ to -19.7‰, which is obviously related to the decarboxylation of organic matter during the late period of early diagenesis to the early period of late diagenesis. As the mid-late diagenetic products, ferriferous cal- cites in the study area are considered as the characteristic authigenic minerals for indicating large-scaled hydrocarbon influx and migration within the clastic reservoir. The late ankerite is relatively heavy in carbon isotope with δ^13C values ranging from -1.92‰ to -0.84‰, and shows a wide range of variations in oxygen isotopic composition, with δ^18O values ranging from -20.5‰ to -12.6‰. They are believed to have nothing to do with decarboxylation, but the previously formed marine carbonate rock fragments may serve as the chief carbon source for their precipitation, and the alkaline diagenetic environment at the mid-late stage would promote this process.     

The characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin

The Central Gas Field is a famous large-sized gas field in the Ordos Basin of China. However, identification of main gas sources of the Ordovician reservoirs in this gas field remains puzzling. On the basis of a lot of geochemical data and geological research on natural gases, the characteristics and sources of natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin were studied. The results indicated that natural gases from Ordovician weathered crust reservoirs in the Central Gas Field in the Ordos Basin have similar chemical and isotopic compositions to highly mature and over-mature dry gases. Both coal-derived gases and oil-type gases coexist in the Central Gas Field in the Ordos Basin. The former was derived mainly from Carboniferous-Permian coal measures and the latter from Lower Paleozoic marine carbonates. It is suggested that coal-derived gases occur in the eastern part of the Central Gas Field while oil-type gases may be produced mainly in the northern, western and southern parts of the Central Gas Field in the Ordos Basin.     

鄂尔多斯地块早白垩世构造-热事件:杭锦旗玄武岩的Ar-Ar年代学证据

在鄂尔多斯地块北部杭锦旗黑石头沟,于下白垩统砂岩之上发现了一层玄武岩。其SiO2(46.93%)较低而碱含量(K2O+Na2O=6.21%)较高,组合指数σ=8.0,含标准矿物Ne,属于碱性橄榄玄武岩。Ar-Ar激光阶段加热定年结果表明,该玄武岩具有126.2±0.4Ma的Ar-Ar年龄。年龄数据表明杭锦旗黑石头沟玄武岩形成于早白垩世,反映鄂尔多斯地块在早白垩世发生了一次构造-岩浆-热事件,这与华北、乃至整个中国东部在早白垩世发生了较普遍的构造-岩浆-热事件具有一致性。这次构造-岩浆-热事件可能引起深部流体自地下深部上涌及在地块内部运移,为各种成矿元素的迁移、沉淀、富集和成矿创造了合适条件。     

New age constraints on emplacement of the Cévenol granitoids, South French Massif Central

During the development of the Variscan orogeny, large amounts of granitic melt were produced, giving rise to the intrusion of granitoids at different structural levels. Despite numerous studies, ages available from previous work on the Cévennes granites remain largely imprecise. In order to better constrain the age and emplacement mode of these granites, we have combined U–Pb dating on monazites and zircons and ⁴⁰Ar/³⁹Ar dating on biotites with petrological observations, major element chemical analysis and SEM zircon imaging on five samples from the Aigoual–St Guiral–Liron and Mont Lozère granitic massifs. The results revealed that granitic intrusions and cooling in Southern Cévennes occurred in a short time span at ∼306 Ma after the main episode of regional metamorphism. Petrological and chemical data suggest that they result from a mixing between mantle-derived basic magmas (lamprophyres) and lower crust acid magmas. At a regional scale the production of these melts occurred at the end of crustal thickening induced by nappe stacking, at the same time as the late anatectic events recorded further north in the Velay dome and the granulite facies metamorphism recorded in metasedimentary granulite enclaves brought up by Tertiary volcanoes of the Velay area (Bournac).