Possible chemical structures and biological precursors of different vitrinites in coal measure in Northwest China

Chemical structure of Jurassic vitrinites isolated from the coals in basins in NW China have been checked using solid state ¹³C NMR and flash pyrolysis-GC/MS. Study shows some Jurassic collodetrinites are rich in aliphatic products in pyrolysates, consisting with the high amount of methylene carbon in ¹³C NMR spectra. In contrast, pyrolysates of Jurassic collotelinites are rich in phenols and alkylbenzenes. Also one Pennsylvanian and one Permian vitrinite selected from the Ordos basin, NW China have been checked for comparison. The proportion of aliphatics is low in pyrolysates, and aliphatic carbon peak in ¹³C NMR spectrum of Permian vitrinite is mostly composed of gas-prone carbons compared with collodetrinites in those Jurassic basins. But both pyrolysis and ¹³C NMR data shows the Pennsylvanian vitrinite is not only gas-prone but also oil-prone. Relatively high proportion of long chain aliphatic structure of some Jurassic vitrinite in Junggar, Turpan-Hami basins may be due to the contribution of liptodetrinites, which may be included during the formation of vitrinites. And it seems that suberinite is the most possible precursor of long chain aliphatics in the structure of Jurassic collodetrinite.     

Comparison of source rock geochemistry of selected rocks from the Schei Point group and Ringnes formation, Sverdrup basin, arctic Canada

Organic-rich from the Schei Point group (middle to late Triassic in age) and the Ringnes formation (late Jurassic) from the Sverdrup basin of the Canadian arctic archipelago have been geochemically evaluated for source rock characterization. Most samples from the Schei Point group are organic-rich (> 2% TOC and are considered as immature to mature oil-prone source rocks [kerogen types I, I–II (IIA) and II (IIA)]. These kerogen types contain abundant AOM1, AOM2 and alginite (Tasmanales, Nostocopsis, Leiosphaeridia, acritarch and dinoflagellate) with variable amounts of vitrinite, inertinite and exinite. Samples from the Ringnes formation contain dominant vitrinite and inertinite with partially oxidized AOM2, alginite and exinite forming mostly immature to mature condensate- and gas-prone source rocks [kerogen type II–III (IIB), III and a few II (IIA)]. Schei Point samples contain higher bitumen extract, saturate hydrocarbons and saturate/ aromatic ratio than the Ringnes samples. Triterpane and sterane (dominant C₃₀) distribution patterns and stable carbon isotope of bitumen and kerogen suggest that the analyzed samples from the Schei Point group are at the onset of oil generation and contain a mixture of sapropelic (algal) and minor terrestrial humic organic matter. Sterane carbon number distributions in the Ringnes formation also suggest a mixed algal and terrestrial organic matter type. There are some variations in hopane carbon number distributions, but these are apparently a function of thermal maturity rather than significant genetic differences among samples. Pyrolysis-gas chromatography/mass spectrometry of the two samples with similar maturity shows that the Schei Point sample generates three times more pyrolyzate than the Ringnes sample. Both samples have a dominant aliphatic character, although the Ringnes sample contains phenol and an aromaticity that is higher than that of the Schei Point sample.     

汶川大地震(MS 8.0)同震变形作用及其与地质灾害的关系

2008年5月12日发生于四川盆地西部龙门山断裂带的汶川大地震（MS 8.0）波及半个亚洲,震撼整个中国。本文通过地震后的实地调查,对发育在龙门山断裂带上的同震地表破裂带的分布、产状、继承性复活与变形特征,以及同震变形与地震地质灾害的关系等进行了初步总结,分析表明这次汶川大地震(MS 8.0)沿北川-映秀逆冲断裂和安县-灌县逆冲断裂同时发生地表破裂,前者产生以高角度逆冲兼右旋走滑为特征的地表破裂带长约275 km,后者产生以缓倾角逆冲作用为特征的地表破裂带长约80 km。汶川大地震的同震地表破裂带分布具有分段性特征,并与地表破坏程度的分带性有着一定的内在联系,详细研究表明,同震地表破裂带的产状直接影响地表破坏程度和地震地质灾害的强度,汶川大地震（MS 8.0）沿呈高角度陡倾的北川-映秀逆冲断裂发育的同震地表变形所产生的地表破坏程度和地震地质灾害的强度比沿缓倾角的安县-灌县逆冲断裂要强。从各种类型的地震断裂来看,具有垂直运动的逆冲型地震断裂所造成的地表破坏程度和地质灾害强度比具水平运动的走滑型地震断裂要强。因此,汶川大地震发生的破裂过程和同震地表变形与地震地质灾害的关系值得深入研究。     

A Compilation of Silicon,Rare Earth Element and Twenty‐One other Trace Element Concentrations in the Natural River Water Reference Material SLRS‐5 (NRC‐CNRC)

The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given.     

汶川MS 8.0地震地表破裂带

2008年5月12日14时28分4秒,四川省汶川县发生MS8.0大地震。发震断裂为龙门山断裂带中的映秀-北川断裂。该次地震的地表破裂可分成2条,分别出现在龙门山断裂带中的映秀-北川断裂、彭县-灌县断裂上,前者破裂长度约200km,后者破裂长度约80km。本次地震的最大垂直和右旋水平同震位移出现在都江堰市虹口乡附近的映秀-北川断裂上,分别为(5±0.2)m和(4.8±0.2)m。破裂带南段出露的地表断层产状为N32°E/NW∠76°,其上的侧伏角为S75°～80°W,反映了该次地震在南段以逆冲运动为主,兼有少量的右旋走滑分量     

鄂尔多斯盆地吴堡地区长6段浊积特征及其石油地质意义

在介绍鄂尔多斯盆地吴堡地区延长组长6段沉积特征的基础上,探讨了该储层物性特征、浊积岩特征、浊积岩分布规律及其对油藏的影响,明确了浊流沉积的石油地质意义.结果表明:鄂尔多斯盆地吴堡地区长6段以发育长石砂岩为主,填隙物成分有方解石、绿泥石、白云母以及少量的石英加大、长石加大等,砂岩储集层孔隙结构具有很强的非均质性;吴堡地区长6期湖盆沉降趋于稳定,是三角洲的高建设时期;多水系、多物源的三角洲前缘沉积为深湖浊积扇沉积提供了充足的物质基础;在吴堡地区东北部三角洲前缘水下分流河道前端发育深湖浊积扇沉积,可区分出中心微相和边缘微相两个沉积微相带,其中浊积扇中心微相以细砂岩、粉砂岩与暗色泥岩呈砂泥互层;从平面上看,浊积岩砂体非均质性在侧向上逐渐变弱,砂体底部发育厚度较大、成熟度较高的暗色湖相沉积的烃源岩,深湖相的暗色泥岩含有丰富的烃源岩,而浊积岩砂体是由深湖相的暗色泥岩构成,孔渗物性好的区域易于形成良好的上倾尖灭的透镜状岩性油藏.     

2017-08-09新疆精河Ms6.6地震附近区域相对应变的变化分析

2017年精河M_S6.6地震震前,尼勒克、巴伦台和小泉沟台钻孔应变仪记录到显著的应变变化,经现场落实确认,异常是可靠的。根据这3个台的记录资料计算相对应变的变化,结果表明,地震前最大（小）主应变大小和方向分别出现明显加速和急剧偏转变化。此外还发现,相对应变场异常期间主方向与震源机制解P轴方位较为一致。     

CG-6型重力仪零漂特性研究

对中国地震局地震研究所最新引进的4台CG-6型相对重力仪的零漂特性进行测试研究,结果表明,4台重力仪的静态零漂率、混合零漂率和动态零漂率均小于8 μGal/h,满足厂家给出的技术指标。在较长观测时间内,各台仪器的零漂均存在不同程度的非线性特征,因此在进行较长时间的野外观测以及后续数据处理中,不宜将零漂率作为常数进行解算和零漂改正。     

Genetic algorithm for fitting a mixed Bingham distribution to 3D orientations: a tool for the statistical and paleostress analyses of fracture orientations

The clustering of fracture orientations is important for tectonic studies and for geotechnical engineering. In this study, a real‐coded genetic algorithm was adopted to fitting a mixed Bingham distribution to orientation data by maximizing the log‐likelihood function of the distribution. The maximization is a difficult problem, because the function has multimodality and singularity. It was found that the algorithm was effective for this problem. Given the orientations of dilational fractures, the present method determines not only the stress axes and stress ratio of each of the fracture groups but also the maximum non‐dimensionalized fluid pressure at the time of their formation. In addition, the software calculates the 95 % error ellipses of the concentration axes. The present method found that the orientations of ore veins of the Akenobe Mine, SW Japan, should be partitioned into three clusters. It is shown that two of the groups had distinctive Zn and Sn contents, and that the ore fluids had overpressures only slightly greater than the minimum principal stress at the time of the deposition of Zn‐ and Sn‐rich veins.     

钛-氨三乙酸-对氯苯基荧光酮-CTMAB四元配合物的分光光度法研究

本文研究Ti(Ⅳ)-氨三乙酸(NTA)-对氯苯基荧光酮(p-ClPF)-CTMAB四元配合物的显色条件。结果表明,在pH5.8—6.6形成了摩尔比为Ti(Ⅳ):NTA:p-ClPF:CTMAB=1:1:3:3的四元配合物,借此反应测定钛,灵敏度高,其ε_(573nm)=2.1×10~5L·mol~(-1)·cm~(-1)。Ti(Ⅳ)浓度在0—1.4μg/10ml范围服从比耳定律。已用本法直接测定了岩矿和铝合金中的Ti,结果满意。