The petroleum generation potential and effective oil window of humic coals related to coal composition and age

A worldwide data set of more than 500 humic coals from the major coal-forming geological periods has been used to analyse the evolution in the remaining (Hydrogen Index, HI) and total (Quality Index, QI) generation potentials with increasing thermal maturity and the ‘effective oil window’ (‘oil expulsion window’). All samples describe HI and QI bands that are broad at low maturities and that gradually narrow with increasing maturity. The oil generation potential is completely exhausted at a vitrinite reflectance of 2.0–2.2%R_o or T_max of 500–510 °C. The initial large variation in the generation potential is related to the original depositional conditions, particularly the degree of marine influence and the formation of hydrogen-enriched vitrinite, as suggested by increased sulphur and hydrogen contents. During initial thermal maturation the HI increases to a maximum value, HI_max. Similarly, QI increases to a maximum value, QI_max. This increase in HI and QI is related to the formation of an additional generation potential in the coal structure. The decline in QI with further maturation is indicating onset of initial oil expulsion, which precedes efficient expulsion. Liquid petroleum generation from humic coals is thus a complex, three-phase process: (i) onset of petroleum generation, (ii) petroleum build-up in the coal, and (iii) initial oil expulsion followed by efficient oil expulsion (corresponding to the effective oil window). Efficient oil expulsion is indicated by a decline in the Bitumen Index (BI) when plotted against vitrinite reflectance or T_max. This means that in humic coals the vitrinite reflectance or T_max values at which onset of petroleum generation occurs cannot be used to establish the start of the effective oil window. The start of the effective oil window occurs within the vitrinite reflectance range 0.85–1.05%R_o or T_max range 440–455 °C and the oil window extends to 1.5–2.0%R_o or 470–510 °C. For general use, an effective oil window is proposed to occur from 0.85 to 1.7%R_o or from 440 to 490 °C. Specific ranges for HI_max and the effective oil window can be defined for Cenozoic, Jurassic, Permian, and Carboniferous coals. Cenozoic coals reach the highest HI_max values (220–370 mg HC/g TOC), and for the most oil-prone Cenozoic coals the effective oil window may possibly range from 0.65 to 2.0%R_o or 430 to 510 °C. In contrast, the most oil-prone Jurassic, Permian and Carboniferous coals reach the expulsion threshold at a vitrinite reflectance of 0.85–0.9%R_o or T_max of 440–445 °C.     

Hydrogeology of thermal waters in Viterbo area, central Italy

A conceptual hydrogeological model of the Viterbo thermal area (central Italy) has been developed. Though numerous studies have been conducted on its geological, geochemical and geothermal features, there is no generalized picture defining the origin and yield of the hydrothermal system. These latter aspects have therefore become the objectives of this research, which is based on new hydrogeological and geochemical investigations. The geological setting results in the coexistence of overlapped interacting aquifers. The shallow volcanic aquifer, characterized by fresh waters, is fed from the area around the Cimini Mountains and is limited at its base by the semiconfining marly-calcareous-arenaceous complex and low-permeability clays. To the west of Viterbo, vertical upflows of thermal waters of the sulphate-chloride-alkaline-earth type with higher gas contents, are due to the locally uplifted carbonate reservoir, the reduced thickness of the semiconfining layer and the high local geothermal gradient. The hot waters (30–60°C) are the result of deep circulation within the carbonate rocks (0.5–1.8 km) and have the same recharge area as the volcanic aquifer. The upward flow in the Viterbo thermal area is at least 0.1 m³/s. This flow feeds springs and deep wells, also recharging the volcanic aquifer from below.     

Temperature dependence of large-scale water-retention curves: a case study

A local-scale model for temperature-dependence of water-retention curves may be applicable to large scales. Consideration of this temperature dependence is important for modeling unsaturated flow and transport in the subsurface in numerous cases. Although significant progress has been made in understanding and modeling this temperature effect, almost all the previous studies have been limited to small scales (on the order of several centimeters). Numerical experiments were used to investigate the possibility of extending a local-scale model for the temperature-dependence of water retention curves to large scales (on the order of meters). Temperature effects on large-scale hydraulic properties are of interest in many practical applications. Numerical experiment results indicate that the local-scale model can indeed be applicable to large-scale problems for special porous media with high air entry values. A typical porous medium of this kind is the porous tuff matrix in the unsaturated zone of Yucca Mountain, Nevada, the proposed geologic disposal site for national high-level nuclear wastes. Whether this finding can approximately hold for general cases needs to be investigated in future studies.     

Control of dust emissions by geomorphic conditions, wind environments and land use in northern China: An examination based on dust storm frequency from 1960 to 2003

The degree to which dust emissions are controlled by geomorphic conditions, wind environments and land use was investigated using the dust storm frequency (DSF) and data from more than 300 meteorological stations throughout northern China. Our analysis showed that most dust emissions originated in gobi deserts that developed in piedmont alluvial fans of the Kunlun, Qilian and Helan mountains. Dust emissions are low from other gobi desert regions, such as the northern Gurbantunggut and eastern Taklimakan, where high vegetation coverage restrained dust emissions or where dust-size particles are not abundant after a long period of strong wind erosion. Sandy deserts with relatively high vegetation coverage or an extensive cover by mobile sands are not a major dust source. Although the highest dust emissions did not appear in regions with the highest wind energy, DSF trends in each region from 1960 to 2003 were closely related to local wind activity. DSF was low in regions with high levels of human activity, where the mean DSF from 1960 to 2003 did not exceed 4 days/year; even from the 1960s to the early 1970s, the period with the greatest DSF, frequency did not exceed 8 days/year, which indicates that extensive land use did not contribute to DSF. The low DSF in these areas might result from the fact that although land use could produce abundant fine soil fractions, vegetation coverage and soil moisture remained higher than in the gobi deserts of arid China, thereby decreasing dust-storm occurrence.     

Verification of the motion fields over Southeast Asia by the Florida State University (FSU) superensemble forecast

The Florida State University (FSU) multimodel superensemble forecast is evaluated against several other operational weather models for the Southeast Asia region. The superensemble technique has demonstrated its exceptional skills in forecasting precipitation, motion and mass fields compared to either individual global operational or ensemble mean forecasts. The motion field investigation for the season of 2001 reveals that the superensemble forecasts are closer to the observed data compared to the other global member operational models through its low systematic errors at the 850 hPa level. The FSU multimodel superensemble forecasts exhibit the lowest root mean square errors (RSMEs), the highest correlation against the best observed data and the lowest systematic errors compared to the other operational model members. These forecasts have the potential to provide better daily weather predictions over the Southeast Asia region, particularly during the early northeast monsoon that often causes heavy rainfall in the equatorial part of the Southeast Asia region.     

四川省康定县滑坡灾害发育特征与形成条件

康定县地处四川盆地西缘山地及青藏高原过渡地带。县域内地势险峻,地形切割强烈,地层与地质构造复杂,新构造运动强烈,地震活动频繁。加之降水充沛,致使山地灾害十分发育,其中滑坡灾害占山地灾害的38.32%。通过搜集资料及现场调查,概述了该县县域内滑坡灾害的分布;从行政区划、自然地理及灾害规模等3方面统计分析了滑坡灾害的发育现状;从地形地貌、地层岩性、地质构造、降雨、地震活动、人类工程活动等方面总结了滑坡灾害的形成条件,并提出防治对策与措施,力求有效地预防与减少滑坡灾害的发生。     

新疆雷暴天气过程分型

对新疆39a雷暴天气资料的普查，得到367次雷暴天气过程，归结出4种天气形势，雷暴天气由冷锋和中尺度高压造成。     

三峡库区滑坡治理工程设计中推力荷载计算方法初探

随着三峡水利工程的逐步实施，淹没区移民及新城镇建设等人类工程活动的加剧，以滑坡为主的环境地质问题日益突出。本文从稳定系数、安全系数入手，对铁道、公路等部门常用的设计计算原理进行了研究，并由此类比分析研究了三峡区回水后或库水位正常运行条件下，滑坡治理工程设计计算方法。     

Ground‐shaking mapping for a scenario earthquake considering effects of geological conditions: a case study for the 1995 Hyogo‐ken Nanbu,Japan earthquake

In order to examine the applicability of ground‐shaking mapping techniques to a near‐field earthquake, a peak ground velocity map of the 1995 Hyogo‐ken Nanbu, Japan earthquake computed from seismic zoning methods that consider the effects of geological conditions is compared with the actual observed intensity map. When computing the ground‐shaking map, the site amplification at each site is calculated in terms of the average shear‐wave velocity of the ground estimated from the corresponding geomorphological conditions. This map shows a relatively good agreement with the observed intensity map. However, the computations provide smaller values for certain disastrous areas of the earthquake, where the effects on ground motion of a deep, irregular underground structure have been reported. The effect of such structures on site response is examined implementing 2D FEM analyses, thereby being also incorporated into the method. Results considering the effect of the irregular underground structure show better agreement with the observed intensity map. Copyright © 2002 John Wiley & Sons, Ltd.     

攀西地区独立银矿的成矿地质条件及找矿前景

四川攀西地区具有特定的地质条件，区域地球化学特征、有利的成矿环境和已发现的银矿床点，都证明区内具有很好的成矿地质条件，寻找大型独立银矿很有前景。主攻内生型和沉积变质型银矿床是今后工作的重点。